GB1335872A - Olefinic terpolymer compositions - Google Patents

Olefinic terpolymer compositions

Info

Publication number
GB1335872A
GB1335872A GB173971A GB173971A GB1335872A GB 1335872 A GB1335872 A GB 1335872A GB 173971 A GB173971 A GB 173971A GB 173971 A GB173971 A GB 173971A GB 1335872 A GB1335872 A GB 1335872A
Authority
GB
United Kingdom
Prior art keywords
guanidine
rubber
ethylene
butadiene rubber
propylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB173971A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Montedison SpA
Original Assignee
Montedison SpA
Montecatini Edison SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montedison SpA, Montecatini Edison SpA filed Critical Montedison SpA
Publication of GB1335872A publication Critical patent/GB1335872A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/10Layered products comprising a layer of natural or synthetic rubber next to a fibrous or filamentary layer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B25/042Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of natural rubber or synthetic rubber
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/12Layered products comprising a layer of natural or synthetic rubber comprising natural rubber
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/16Layered products comprising a layer of natural or synthetic rubber comprising polydienes homopolymers or poly-halodienes homopolymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/06Sulfur
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/17Amines; Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/29Compounds containing one or more carbon-to-nitrogen double bonds
    • C08K5/31Guanidine; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2312/00Crosslinking
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

1335872 Vulcanizing elastomer compositions MONTECATINI EDISON SpA 13 Jan 1971 [14 Jan 1970] 1739/71 Heading C3P [Also in Division B5] Compositions comprising an ethylene/α-olefin/ polyene elastomer and a highly unsaturated rubber are vulcanized with at least 2À5 parts by weight of sulphur per 100 parts by weight of elastomers and an aryl guanidine compound as sole accelerator in a ratio of gram atoms of sulphur to moles of guanidine compound of at least 3 : 1, optionally together with zinc oxide, carbon black, stearic acids, fillers, plasticizers and/or stabilizers. The olefin copolymer elastomer may be derived from ethylene, propylene and hexadiene-1,4,2-methylhexadiene-1,5, cyclooctadiene, dicyclooctadiene, dicyclopentadiene, 6-methyl-4,7,8,9-tetrahydroindene or 5-ethylidene-2-norbornene. The highly unsaturated rubber may be natural rubber, polybutadiene, polychloroprene, polyisoprene, styrene/butadiene rubber or acrylonitrile/butadiene rubber. The accelerator may be di-o-tolyl guanidine, o-tolyl diguanidine, diphenyl guanidine or triphenyl guanidine. In examples mixtures of (1 and 2) ethylene/propylene/methyl tetrahydroindene terpolymers with natural rubber; and mixtures of ethylene/propylene/ ethylidene norbornene terpolymers with (3, 4, 7 and 8) natural rubber, (5) styrene/butadiene rubber and (6) acrylonitrile/butadiene rubber: are compounded with carbon black, zinc oxide, stearic acid and phenyl #-naphthylamine and covulcanized with sulphur and di-o-tolyl guanidine or diphenyl guanidine.
GB173971A 1970-01-14 1971-01-13 Olefinic terpolymer compositions Expired GB1335872A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT1933270 1970-01-14

Publications (1)

Publication Number Publication Date
GB1335872A true GB1335872A (en) 1973-10-31

Family

ID=11156809

Family Applications (1)

Application Number Title Priority Date Filing Date
GB173971A Expired GB1335872A (en) 1970-01-14 1971-01-13 Olefinic terpolymer compositions

Country Status (6)

Country Link
BE (1) BE761530A (en)
DE (1) DE2101184C3 (en)
ES (1) ES387200A1 (en)
FR (1) FR2075540A5 (en)
GB (1) GB1335872A (en)
NL (1) NL167712C (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AR204831A1 (en) * 1973-05-08 1976-03-05 Du Pont SUITABLE CURABLE BLENDS TO BE USED IN VULCANIZABLE COMPOSITIONS VULCANIZABLE COMPOSITIONS AND VULCANIZED PRODUCTS
CA1078679A (en) * 1975-09-15 1980-06-03 Arthur A. Blaskiewicz Epdm copolymer rubber-highly unsaturated rubber (filled) blends
US4708992A (en) * 1984-12-14 1987-11-24 Sumitomo Chemical Company, Limited Rubber compositions

Also Published As

Publication number Publication date
FR2075540A5 (en) 1971-10-08
DE2101184A1 (en) 1972-08-03
NL7100314A (en) 1971-07-16
BE761530A (en) 1971-07-13
DE2101184C3 (en) 1980-01-17
ES387200A1 (en) 1973-12-16
NL167712B (en) 1981-08-17
NL167712C (en) 1982-01-18
DE2101184B2 (en) 1979-05-23

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Legal Events

Date Code Title Description
PS Patent sealed
PE20 Patent expired after termination of 20 years