GB1331084A - Process for the photocatalytic oxidation of hydrocarbons - Google Patents
Process for the photocatalytic oxidation of hydrocarbonsInfo
- Publication number
- GB1331084A GB1331084A GB4406370A GB4406370A GB1331084A GB 1331084 A GB1331084 A GB 1331084A GB 4406370 A GB4406370 A GB 4406370A GB 4406370 A GB4406370 A GB 4406370A GB 1331084 A GB1331084 A GB 1331084A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oxide
- catalyst
- alcoholates
- sept
- wavelengths
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229930195733 hydrocarbon Natural products 0.000 title abstract 4
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 2
- 230000003647 oxidation Effects 0.000 title abstract 2
- 238000007254 oxidation reaction Methods 0.000 title abstract 2
- 230000001699 photocatalysis Effects 0.000 title 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 239000007789 gas Substances 0.000 abstract 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- STNJBCKSHOAVAJ-UHFFFAOYSA-N Methacrolein Chemical compound CC(=C)C=O STNJBCKSHOAVAJ-UHFFFAOYSA-N 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910004298 SiO 2 Inorganic materials 0.000 abstract 1
- 150000001805 chlorine compounds Chemical class 0.000 abstract 1
- 238000005367 electrostatic precipitation Methods 0.000 abstract 1
- 230000007062 hydrolysis Effects 0.000 abstract 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 230000001678 irradiating effect Effects 0.000 abstract 1
- 239000001282 iso-butane Substances 0.000 abstract 1
- 229910044991 metal oxide Inorganic materials 0.000 abstract 1
- 150000004706 metal oxides Chemical class 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 239000001294 propane Substances 0.000 abstract 1
- 230000005855 radiation Effects 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
- 238000001228 spectrum Methods 0.000 abstract 1
- 238000005979 thermal decomposition reaction Methods 0.000 abstract 1
- 238000007669 thermal treatment Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/36—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in compounds containing six-membered aromatic rings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
- B01J19/122—Incoherent waves
- B01J19/123—Ultraviolet light
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions decreasing the number of carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S204/00—Chemistry: electrical and wave energy
- Y10S204/902—Production of desired compound by wave energy in presence of a chemically designated nonreactant chemical treating agent, excluding water, chloroform, carbon tetrachloride, methylene chloride or benzene
- Y10S204/903—Inorganic chemical treating agent
- Y10S204/904—Metal treating agent
- Y10S204/905—Heavy metal agent
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR6931280A FR2058540A5 (enExample) | 1969-09-15 | 1969-09-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1331084A true GB1331084A (en) | 1973-09-19 |
Family
ID=9040066
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4406370A Expired GB1331084A (en) | 1969-09-15 | 1970-09-15 | Process for the photocatalytic oxidation of hydrocarbons |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3781194A (enExample) |
| JP (1) | JPS546524B1 (enExample) |
| DE (1) | DE2045562A1 (enExample) |
| FR (1) | FR2058540A5 (enExample) |
| GB (1) | GB1331084A (enExample) |
| NL (1) | NL7013639A (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5736055A (en) * | 1995-05-16 | 1998-04-07 | Photo-Catalytics, Inc. | Cartridge for photocatalytic purification of fluids |
| RU2130332C1 (ru) * | 1997-06-24 | 1999-05-20 | Центральное конструкторское бюро машиностроения | Способ переработки тетрафторэтилена с регламентированным содержанием изотопа 13c в двуокись углерода |
| RU2144421C1 (ru) * | 1998-03-10 | 2000-01-20 | Государственное предприятие Научно-исследовательский институт электрофизической аппаратуры имени Д.В.Ефремова | Способ получения высокообогащенного изотопа 13c |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NZ183162A (en) * | 1976-02-06 | 1979-03-16 | Ici Ltd | Photochemcial oxidation |
| US4655891A (en) * | 1984-08-22 | 1987-04-07 | The Standard Oil Company | Process for the photochemical dehydrogenation of alcohols with semiconductor powder suspensions |
| US4571290A (en) * | 1984-08-22 | 1986-02-18 | The Standard Oil Company (Ohio) | Process for the selective oxidation of olefins with photochemical illumination of semiconductor powder suspensions |
| US5045288A (en) * | 1989-09-15 | 1991-09-03 | Arizona Board Of Regents, A Body Corporate Acting On Behalf Of Arizona State University | Gas-solid photocatalytic oxidation of environmental pollutants |
| GB9102766D0 (en) * | 1991-02-09 | 1991-03-27 | Tioxide Group Services Ltd | Destruction process |
| AU2390395A (en) * | 1994-04-18 | 1995-11-10 | Yosry A. Attia | Aerogel materials and system for the capture and separation of gases and vapors with aerogel materials |
| US5604339A (en) * | 1995-03-14 | 1997-02-18 | University Of Central Florida | Method of photocatalytic destruction of harmful volatile compounds at emitting surfaces |
| US6248218B1 (en) | 1999-03-25 | 2001-06-19 | Clovis A. Linkous | Closed cycle photocatalytic process for decomposition of hydrogen sulfide to its constituent elements |
| US7220391B1 (en) | 1999-03-25 | 2007-05-22 | University Of Central Florida Research Foundation, Inc. | UV photochemical option for closed cycle decomposition of hydrogen sulfide |
| US6179971B1 (en) | 1999-04-30 | 2001-01-30 | Kse, Inc. | Two stage process and catalyst for photocatalytic conversion of contaminants |
| US6179972B1 (en) | 1999-06-02 | 2001-01-30 | Kse, Inc. | Two stage process and apparatus for photocatalytic and catalytic conversion of contaminants |
| US6777374B2 (en) | 2000-07-18 | 2004-08-17 | The United States Of America As Represented By The Environmental Protection Agency | Process for photo-induced selective oxidation of organic chemicals to alcohols, ketones and aldehydes using flame deposited nano-structured photocatalyst |
| EP1403357A3 (en) * | 2002-09-27 | 2004-12-29 | Osada Giken Co., Ltd. | Method for decomposing organic substance |
| WO2014126647A1 (en) * | 2013-02-15 | 2014-08-21 | Empire Technology Development Llc | Photocatalytic degradation of sugar |
| DE102019125125A1 (de) * | 2019-09-18 | 2021-03-18 | Maximilian Blomeier | Reaktormodul und Oxidationsreaktor |
| CN117720067A (zh) * | 2024-01-29 | 2024-03-19 | 四川大学 | 一种苄基化合物光化学制备h2的方法 |
-
1969
- 1969-09-15 FR FR6931280A patent/FR2058540A5/fr not_active Expired
-
1970
- 1970-09-15 GB GB4406370A patent/GB1331084A/en not_active Expired
- 1970-09-15 US US00072341A patent/US3781194A/en not_active Expired - Lifetime
- 1970-09-15 NL NL7013639A patent/NL7013639A/xx unknown
- 1970-09-15 DE DE19702045562 patent/DE2045562A1/de active Pending
- 1970-09-16 JP JP8119770A patent/JPS546524B1/ja active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5736055A (en) * | 1995-05-16 | 1998-04-07 | Photo-Catalytics, Inc. | Cartridge for photocatalytic purification of fluids |
| EP0866773A4 (en) * | 1995-05-16 | 1998-12-30 | Photo Catalytics Inc | CARTRIDGE FOR PHOTOCATALYTIC CLEANING OF LIQUIDS |
| RU2130332C1 (ru) * | 1997-06-24 | 1999-05-20 | Центральное конструкторское бюро машиностроения | Способ переработки тетрафторэтилена с регламентированным содержанием изотопа 13c в двуокись углерода |
| RU2144421C1 (ru) * | 1998-03-10 | 2000-01-20 | Государственное предприятие Научно-исследовательский институт электрофизической аппаратуры имени Д.В.Ефремова | Способ получения высокообогащенного изотопа 13c |
Also Published As
| Publication number | Publication date |
|---|---|
| US3781194A (en) | 1973-12-25 |
| JPS546524B1 (enExample) | 1979-03-29 |
| DE2045562A1 (de) | 1971-03-25 |
| FR2058540A5 (enExample) | 1971-05-28 |
| NL7013639A (enExample) | 1971-03-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |