GB1326014A - Catalystic carbonylation process - Google Patents

Catalystic carbonylation process

Info

Publication number
GB1326014A
GB1326014A GB1326014DA GB1326014A GB 1326014 A GB1326014 A GB 1326014A GB 1326014D A GB1326014D A GB 1326014DA GB 1326014 A GB1326014 A GB 1326014A
Authority
GB
United Kingdom
Prior art keywords
july
alcohols
esters
produced
carboxylic acids
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Johnson Matthey PLC
Original Assignee
Johnson Matthey PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johnson Matthey PLC filed Critical Johnson Matthey PLC
Publication of GB1326014A publication Critical patent/GB1326014A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1326014 Carboxylic acids and esters JOHNSON MATTHEY & CO Ltd 6 July 1970 [14 July 1969] 15294/73 Divided out of 1326012 Heading C2C Carboxylic acids or esters are produced by the carboxylation of alcohols with CO using as catalyst a composition prepared by adding a stabilizing donor ligand to a solution contain ing a strong acid and any of M 2 <SP>4+</SP>, M 2 (O 2 CR)<SP>n+</SP> 4-n , M 2 (OCSR)<SP>n+</SP> 4-n and M 2 (S 2 CR)<SP>n+</SP> 4-n , wherein n is 1, 2, 3 or 4, R is alkyl or aryl and may be substituted and M is a transition metal. Preferably, a halogen promoter is present. Stabilizing donor ligands are defined as organic isocyanides; other organic compounds, other than alcohols, having in the molecule an atom of an element of Group VB or VIB in a valency state such that it possesses a lone pair of electrons; or a stannous or germanium II halide. In the example acetic acid is produced by the carbonylation of methanol having dissolved therein Rh 2 (O 2 CCH 3 ) 2 , HBF 4 , P(C 6 H 5 ) 3 and CH 3 I.
GB1326014D 1969-07-14 1969-07-14 Catalystic carbonylation process Expired GB1326014A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1529473 1969-07-14

Publications (1)

Publication Number Publication Date
GB1326014A true GB1326014A (en) 1973-08-08

Family

ID=10056521

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1326014D Expired GB1326014A (en) 1969-07-14 1969-07-14 Catalystic carbonylation process

Country Status (1)

Country Link
GB (1) GB1326014A (en)

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2431481A1 (en) * 1978-07-19 1980-02-15 Uop Inc Carbonylation of alkanol to alkanoic acid and ester - using heterogeneous phthalocyanine catalyst with alkyl halide promoter
EP0055618A1 (en) * 1980-12-29 1982-07-07 Monsanto Company Carbonylation process employing a catalyst stabilised in soluble form
EP0079592A2 (en) * 1981-11-12 1983-05-25 Union Carbide Corporation Catalyst stabilization
EP0081152A1 (en) * 1981-12-04 1983-06-15 Hoechst Aktiengesellschaft Process for preparing acetic-anhydride and/or acetic-acid and/or ethylidene diacetate
US4433166A (en) * 1980-12-29 1984-02-21 Monsanto Company Process for stabilizing carbonylation catalyst in soluble form
US4433165A (en) * 1980-12-29 1984-02-21 Monsanto Company Process for stabilizing carbonylation catalyst in soluble form
EP0114703A1 (en) * 1983-01-25 1984-08-01 Shell Internationale Researchmaatschappij B.V. Process for the preparation of carboxylic acids and/or esters
WO1985003703A1 (en) * 1984-02-16 1985-08-29 Bp Chemicals Limited Carbonylation process improvement
US4563309A (en) * 1984-08-16 1986-01-07 Union Carbide Corporation Production of carboxylic anhydrides from methyl carboxlyates using rhodium complex catalysts
EP0172365A1 (en) * 1984-08-21 1986-02-26 Hüls Aktiengesellschaft Process for the preparation of phenylacetic acid and of its derivatives by catalytic rearrangement of benzyl formate and its derivatives
US4733006A (en) * 1980-12-29 1988-03-22 Monsanto Company Carbonylation process with an alkali metal acetate as catalyst stabilizer
US4918222A (en) * 1984-07-27 1990-04-17 Texaco Inc. Process for synthesis of N-acetylglycine
US4927967A (en) * 1984-07-20 1990-05-22 Union Carbide Chemicals And Plastics Company Inc. Production of carboxylic acids from organic formate esters using rhodium complex catalysts
US4990654A (en) * 1984-08-16 1991-02-05 Union Carbide Chemicals And Plastics Company Inc. Production of acetate esters from alcohols using rhodium complex catalysts
US5026907A (en) * 1984-08-16 1991-06-25 Union Carbide Chemicals And Plastics Technology Corporation Production of carboxylic acids from alcohols using rhodium complex catalysts and organic ester source
US5817869A (en) * 1995-10-03 1998-10-06 Quantum Chemical Corporation Use of pentavalent Group VA oxides in acetic acid processing
US6031129A (en) * 1995-10-03 2000-02-29 Quantum Chemical Corporation Use of pentavalent group VA oxides in acetic acid processing
WO2006064178A1 (en) * 2004-12-17 2006-06-22 Bp Chemicals Limited Process and catalyst for the manuafacture of acetic acid

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2431481A1 (en) * 1978-07-19 1980-02-15 Uop Inc Carbonylation of alkanol to alkanoic acid and ester - using heterogeneous phthalocyanine catalyst with alkyl halide promoter
EP0055618A1 (en) * 1980-12-29 1982-07-07 Monsanto Company Carbonylation process employing a catalyst stabilised in soluble form
US4733006A (en) * 1980-12-29 1988-03-22 Monsanto Company Carbonylation process with an alkali metal acetate as catalyst stabilizer
US4433166A (en) * 1980-12-29 1984-02-21 Monsanto Company Process for stabilizing carbonylation catalyst in soluble form
US4433165A (en) * 1980-12-29 1984-02-21 Monsanto Company Process for stabilizing carbonylation catalyst in soluble form
EP0079592A2 (en) * 1981-11-12 1983-05-25 Union Carbide Corporation Catalyst stabilization
EP0079592A3 (en) * 1981-11-12 1983-07-06 Union Carbide Corporation Catalyst stabilization
EP0081152A1 (en) * 1981-12-04 1983-06-15 Hoechst Aktiengesellschaft Process for preparing acetic-anhydride and/or acetic-acid and/or ethylidene diacetate
EP0114703A1 (en) * 1983-01-25 1984-08-01 Shell Internationale Researchmaatschappij B.V. Process for the preparation of carboxylic acids and/or esters
WO1985003703A1 (en) * 1984-02-16 1985-08-29 Bp Chemicals Limited Carbonylation process improvement
EP0153834A1 (en) * 1984-02-16 1985-09-04 BP Chemicals Limited Carbonylation process improvement
US4927967A (en) * 1984-07-20 1990-05-22 Union Carbide Chemicals And Plastics Company Inc. Production of carboxylic acids from organic formate esters using rhodium complex catalysts
US4918222A (en) * 1984-07-27 1990-04-17 Texaco Inc. Process for synthesis of N-acetylglycine
US4563309A (en) * 1984-08-16 1986-01-07 Union Carbide Corporation Production of carboxylic anhydrides from methyl carboxlyates using rhodium complex catalysts
US4990654A (en) * 1984-08-16 1991-02-05 Union Carbide Chemicals And Plastics Company Inc. Production of acetate esters from alcohols using rhodium complex catalysts
US5026907A (en) * 1984-08-16 1991-06-25 Union Carbide Chemicals And Plastics Technology Corporation Production of carboxylic acids from alcohols using rhodium complex catalysts and organic ester source
EP0172365A1 (en) * 1984-08-21 1986-02-26 Hüls Aktiengesellschaft Process for the preparation of phenylacetic acid and of its derivatives by catalytic rearrangement of benzyl formate and its derivatives
US5817869A (en) * 1995-10-03 1998-10-06 Quantum Chemical Corporation Use of pentavalent Group VA oxides in acetic acid processing
US6031129A (en) * 1995-10-03 2000-02-29 Quantum Chemical Corporation Use of pentavalent group VA oxides in acetic acid processing
WO2006064178A1 (en) * 2004-12-17 2006-06-22 Bp Chemicals Limited Process and catalyst for the manuafacture of acetic acid
US7977272B2 (en) 2004-12-17 2011-07-12 Bp Chemicals Limited Process and catalyst for the manufacture of acetic acid

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Legal Events

Date Code Title Description
PS Patent sealed
PE20 Patent expired after termination of 20 years