GB1305211A - - Google Patents
Info
- Publication number
- GB1305211A GB1305211A GB46870A GB46870A GB1305211A GB 1305211 A GB1305211 A GB 1305211A GB 46870 A GB46870 A GB 46870A GB 46870 A GB46870 A GB 46870A GB 1305211 A GB1305211 A GB 1305211A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polyester
- acid
- per cent
- derivative
- glycol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
Abstract
1305211 Linear polyterephthalates MONSANTO CO 5 Jan 1970 [7 Jan 1969 13 May 1969] 468/70 Heading C3R A thermally stable, disperse dyeable, synthetic linear condensation polyester comprises at least 85% by wt. of the polyester of terephthalic acid and a glycol, modified with from 0À25-3À0 mole per cent based on the moles of the repeating units of the polyester, of an additive comprising compounds of the formula R-O(G-O) x -H, where R is a C 8-20 alkyl group, G is an ethylene, propylene or butylene radical or a mixture thereof, and X is 8-20 and is # number of carbon atoms in R. The polyester may be further modified with up to 0À73 mole per cent, based on the amount of dicarboxylic acid or ester-forming derivative thereof, of a chain-branching agent which is preferably a tri- or tetra-fanctional aromatic carboxylic acid derivative, e.g. trimesic acid, trimethyl trimerate, tetramethylpyromellitate, or a polyol, e.g. R(OH) n (R=C 3-6 , n=3-6), R 1 -(CH 2 OH) 3 (R 1 =C 2-6 ) or C 6 H 3 [(CH 2 ) n OH] 3 (n = 1-6). The polyester is preferably prepared by polycondensing terephthalic acid or esterforming derivative, a glycol, and from 0À25- 3À0 mole/per cent, based on the weight of acid or ester-forming derivative of mixtures of alkoxy poly-(oxyalkylene) glycols RO(GO) x H. Preferred glycols for esterification are HO(CH 2 ) n OH (n=2-10) particularly ethylene glycol, and acids that may be present in addition to terephthalic acid include isophthalic acid, p,p<SP>1</SP> - dicarboxybiphenyl, p,p<SP>1</SP> - dicarboxydiphenylsulphone, p,p<SP>1</SP> - dicarboxydiphenylmethane, and halides, esters, half-esters, ammonium and amine salts thereof. The polyesters may be melt-spun to form filaments or films, and the invention further comprises filaments characterized by having (a) the inherent capability of resisting fusion when heated in the presence of air to at least 175 C. for at least 10 min, and (b) an inherent disperse dye uptake of at least 2% when dyed with Latyl Brilliant Blue 2G dye (C.I. Disperse Blue 61) for 2 hr. at 98À89 C. with a 4% dye bath having a liquor-filament ratio of 40:1; percentages being based on the wt. of filament. Specification 847,090 is referred to. Reference has been directed by the Comptroller to Specification 847,090.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US78952869A | 1969-01-07 | 1969-01-07 | |
US82409269A | 1969-05-13 | 1969-05-13 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1305211A true GB1305211A (en) | 1973-01-31 |
Family
ID=27120926
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB46870A Expired GB1305211A (en) | 1969-01-07 | 1970-01-05 |
Country Status (10)
Country | Link |
---|---|
JP (2) | JPS4832435B1 (en) |
BE (1) | BE744138A (en) |
CA (1) | CA935949A (en) |
CH (1) | CH528559A (en) |
DE (1) | DE2000547C3 (en) |
FR (1) | FR2037034A1 (en) |
GB (1) | GB1305211A (en) |
IL (1) | IL33666A (en) |
LU (1) | LU60152A1 (en) |
NL (1) | NL7000178A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
USRE34329E (en) * | 1988-11-04 | 1993-08-03 | Petrolite Corporation | Overprint aqueous varnish |
USRE34647E (en) * | 1988-11-04 | 1994-06-28 | Petrolite Corporation | Overprint aqueous varnish |
US5376170A (en) * | 1988-11-04 | 1994-12-27 | Petrolite Corporation | Additive dispersions containing ethoxylated alcohols |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5010569U (en) * | 1973-05-24 | 1975-02-03 | ||
JPS50132445U (en) * | 1973-11-30 | 1975-10-31 | ||
JPS53161968U (en) * | 1977-05-23 | 1978-12-19 | ||
JPS61125973U (en) * | 1985-01-25 | 1986-08-07 |
-
1970
- 1970-01-05 GB GB46870A patent/GB1305211A/en not_active Expired
- 1970-01-05 IL IL33666A patent/IL33666A/en unknown
- 1970-01-06 CA CA071504A patent/CA935949A/en not_active Expired
- 1970-01-07 BE BE744138D patent/BE744138A/en unknown
- 1970-01-07 LU LU60152D patent/LU60152A1/xx unknown
- 1970-01-07 FR FR7000367A patent/FR2037034A1/fr not_active Withdrawn
- 1970-01-07 JP JP45002462A patent/JPS4832435B1/ja active Pending
- 1970-01-07 NL NL7000178A patent/NL7000178A/xx unknown
- 1970-01-07 DE DE2000547A patent/DE2000547C3/en not_active Expired
- 1970-01-07 CH CH13270A patent/CH528559A/en not_active IP Right Cessation
-
1972
- 1972-10-13 JP JP47102614A patent/JPS5239097B1/ja active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
USRE34329E (en) * | 1988-11-04 | 1993-08-03 | Petrolite Corporation | Overprint aqueous varnish |
USRE34647E (en) * | 1988-11-04 | 1994-06-28 | Petrolite Corporation | Overprint aqueous varnish |
USRE34792E (en) * | 1988-11-04 | 1994-11-22 | Petrolite Corporation | Additive composition for water-based inks |
US5376170A (en) * | 1988-11-04 | 1994-12-27 | Petrolite Corporation | Additive dispersions containing ethoxylated alcohols |
Also Published As
Publication number | Publication date |
---|---|
CA935949A (en) | 1973-10-23 |
DE2000547C3 (en) | 1980-07-03 |
JPS5239097B1 (en) | 1977-10-03 |
BE744138A (en) | 1970-07-07 |
LU60152A1 (en) | 1970-07-09 |
CH528559A (en) | 1972-09-30 |
IL33666A0 (en) | 1970-03-22 |
DE2000547A1 (en) | 1970-07-23 |
NL7000178A (en) | 1970-07-09 |
FR2037034A1 (en) | 1970-12-31 |
IL33666A (en) | 1974-03-14 |
JPS4832435B1 (en) | 1973-10-05 |
DE2000547B2 (en) | 1979-10-25 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PCNP | Patent ceased through non-payment of renewal fee |