GB1304038A - - Google Patents

Info

Publication number
GB1304038A
GB1304038A GB1970570A GB1304038DA GB1304038A GB 1304038 A GB1304038 A GB 1304038A GB 1970570 A GB1970570 A GB 1970570A GB 1304038D A GB1304038D A GB 1304038DA GB 1304038 A GB1304038 A GB 1304038A
Authority
GB
United Kingdom
Prior art keywords
coo
alcl
oipr
oet
alet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1970570A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Publication of GB1304038A publication Critical patent/GB1304038A/en
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/14—Monomers containing five or more carbon atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

1304038 Butadiene-alphaolefin alternating copolymerization catalyst MARUZEN PETROCHEMICAL CO Ltd 24 April 1970 [25 April 1969 13 May 1969 19 June 1969 3 July 1969 15 Aug 1969 10 Sept 1969 25 Sept 1969 30 Sept 1969 (2) 9 Oct 1969 31 Oct 1969 (2) 4 Dec 1969 17 March 1970] 19705/70 Heading C3P Butadiene and a C 3-6 alpha-olefin or styrene are copolymerized, to form an alternating copolymer, in the presence of a catalyst comprizing (a) an organoaluminium compound, (b) a compound containing a V-halogen bond, (c) a compound containing a MO hydrocarbyl or MO haloether linkage, where M is an atom whose electronegativity is lower than 2À2, and optionally (a) a halogen, halide, or metal or metalloid oxide. Conventional Zeigler alternating copolymerization techniques are employed. In examples, the olefin is propylene, styrene, butene-1, pentene-1, 4-methyl pentene-1 or hexene-1, while the catalyst components are (a) Al(iBu) 3 , AlEt 3 , or AlEt 2 Cl; (b) VOCl 3 or VOCl 4 ; (c) Al(OiPr) 3 , AlCl(OiPr) 2 , NaOEt, B(OPn) 3 , Ti(OBu) 4 , P(OPh) 3 , AlCl 3 -propylene oxide reaction product, Al(iOPr) 3 -H 2 O, AlEt 3 -iPrOH or EtOH-H 2 O, Ti(OiPr) 4 -H 2 O, B(OEt) 3 -H 2 O, P(OnBu) 3 -H 2 O, OV(OEt) 3 -H 2 O, Al 2 O(CH 3 COO) 4 -OV(CH 3 COO) 2 -, Zn(CH 3 COO) 2 -Zr(CH 3 COO) 4 -, Mn(CH 3 COO) 2 -, Pb(CH 3 COO) 2 - Al(OiPr) 3 , Cd(CH 3 COO) 2 -P(OPh) 3 , OV(CH 3 COO) 2 -Si(OEt) 4 , Ti(OBu) 4 -Cu(CH 3 COO) 2 , (CaOOC.CH 3 ) 2 -Ti(OBu) 4 , Co(CH 3 .COO) 2 -B(OPh) 3 or Al(O-s-Bu) 3 , NaOEt; and (d) TiCl 4 , SnCl 4 , +BuCl, AlCl(iOPr) 2 , I 2 , AlCl 3 , CuCl, ZnCl 2 , MgCl 2 , SbCl 5 , MnCl 2 , PCl 5 , AlEtCl 2 , MgO, ZnO, Al 2 O 3 , silicaalumina, B 2 O 3 , TiO 2 , zeolites, V 2 O 5 , CoBr 2 , ZnI 2 , BF 3 .OEt 2 , or AlCl 3 .Et 2 O.
GB1970570A 1970-04-24 1970-04-24 Expired GB1304038A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE2020168A DE2020168C3 (en) 1970-04-24 1970-04-24 Process for the preparation of an alternating copolymer by copolymerization of butadiene - (1,3) with an α-olefin of the general formula CH ↓ 2 ↓ = CHR, in which R is a normal or branched alkyl group with 1 to 4 carbon atoms or with styrene
GB1970570 1970-04-24

Publications (1)

Publication Number Publication Date
GB1304038A true GB1304038A (en) 1973-01-24

Family

ID=25759019

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1970570A Expired GB1304038A (en) 1970-04-24 1970-04-24

Country Status (2)

Country Link
DE (1) DE2020168C3 (en)
GB (1) GB1304038A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112279964A (en) * 2020-10-29 2021-01-29 遂川海州树脂有限公司 Method for preparing modified m-pentadiene petroleum resin by using composite catalyst

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55110107A (en) * 1979-02-19 1980-08-25 Maruzen Sekiyu Kagaku Kk Bulk alternating copolymerization of propylene and butadiene

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1361801A (en) * 1962-07-12 1964-05-22 Montedison Spa New olefin copolymers and process for their preparation
GB982708A (en) * 1963-01-23 1965-02-10 British Petroleum Co Copolymers
US3457186A (en) * 1964-09-30 1969-07-22 Columbian Carbon Homogeneous iron coordination catalysts

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112279964A (en) * 2020-10-29 2021-01-29 遂川海州树脂有限公司 Method for preparing modified m-pentadiene petroleum resin by using composite catalyst

Also Published As

Publication number Publication date
DE2020168C3 (en) 1981-04-23
DE2020168A1 (en) 1970-11-12
DE2020168B2 (en) 1980-09-11

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee