GB1287793A - Process for the preparation of 2-hydroxy-3-substituted cyclopent-2-en-1-ones and intermediates therefore - Google Patents
Process for the preparation of 2-hydroxy-3-substituted cyclopent-2-en-1-ones and intermediates thereforeInfo
- Publication number
- GB1287793A GB1287793A GB8917/71A GB891771A GB1287793A GB 1287793 A GB1287793 A GB 1287793A GB 8917/71 A GB8917/71 A GB 8917/71A GB 891771 A GB891771 A GB 891771A GB 1287793 A GB1287793 A GB 1287793A
- Authority
- GB
- United Kingdom
- Prior art keywords
- formula
- compounds
- preparation
- alkali metal
- hydroxy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0061—Essential oils; Perfumes compounds containing a six-membered aromatic ring not condensed with another ring
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
- A23L27/20—Synthetic spices, flavouring agents or condiments
- A23L27/203—Alicyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/42—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by hydrolysis
- C07C45/43—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by hydrolysis of >CX2 groups, X being halogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0026—Essential oils; Perfumes compounds containing an alicyclic ring not condensed with another ring
- C11B9/003—Essential oils; Perfumes compounds containing an alicyclic ring not condensed with another ring the ring containing less than six carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Nutrition Science (AREA)
- Health & Medical Sciences (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Seasonings (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Confectionery (AREA)
- Cereal-Derived Products (AREA)
- Distillation Of Fermentation Liquor, Processing Of Alcohols, Vinegar And Beer (AREA)
- Dairy Products (AREA)
Abstract
1287793 2 - Hydroxy - 3 - alkylcyclopent - 2- on-1-ones and intermediates therefor PFIZER Inc 31 Oct 1969 [10 Feb 1969 28 April 1969] 8917/71 Divided out of 1287792 Heading C2C The invention comprises compounds of the formula wherein both Xs are either Br or C1, lower alkoxy contains from 1 to 5 C atoms, and R is C 1 to C 6 alkyl, benzyl or substituted benzyl. They may be obtained by treating an alkali metal salt of 2 - carbo - (C 1 -C 5 ) - alkoxycyclopentan - 1- one with a (C 1 -C 6 ) alkyl halide or benzyl halide in the absence or presence of an alkali metal iodide and chlorinating or brominating the resulting compound by treating it with elemental Br 2 or Cl 2 , or sulphuryl chloride or bromide, The invention also comprises the preparation of compounds of the formula by hydrolysis of a compound of Formula II. Examples are given for the preparation of compounds of Formulµ I and II. The compounds of Formula I are useful as food additives. The alkali metal salt of 2-carbo-(C 1 -C 5 ) alkoxy-cyclopentan-1-one may be obtained by adding a dialkyladipate to a slurry of a base in an anhydrous inert solvent and distilling the mixture.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US79811369A | 1969-02-10 | 1969-02-10 | |
US82001369A | 1969-04-28 | 1969-04-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1287793A true GB1287793A (en) | 1972-09-06 |
Family
ID=27121960
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB8917/71A Expired GB1287793A (en) | 1969-02-10 | 1969-10-31 | Process for the preparation of 2-hydroxy-3-substituted cyclopent-2-en-1-ones and intermediates therefore |
GB53633/69A Expired GB1287792A (en) | 1969-02-10 | 1969-10-31 | 2-hydroxy-3-lower alkyl-cyclopent-2-en-1-one preparation, including intermediates therefor |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB53633/69A Expired GB1287792A (en) | 1969-02-10 | 1969-10-31 | 2-hydroxy-3-lower alkyl-cyclopent-2-en-1-one preparation, including intermediates therefor |
Country Status (7)
Country | Link |
---|---|
JP (1) | JPS5037264B1 (en) |
BE (1) | BE745666A (en) |
CH (1) | CH515869A (en) |
DE (1) | DE2005160C3 (en) |
FR (1) | FR2032835A5 (en) |
GB (2) | GB1287793A (en) |
IT (1) | IT1004006B (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3264304D1 (en) * | 1981-11-27 | 1985-07-25 | Firmenich & Cie | Use of 2-hydroxy-3,4,4-trimethyl-cyclopent-2-ene-1-one as odorant ingredient |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB979295A (en) * | 1960-11-28 | 1965-01-01 | Shell Res Ltd | The preparation of cyclic diketones |
-
1969
- 1969-10-31 GB GB8917/71A patent/GB1287793A/en not_active Expired
- 1969-10-31 GB GB53633/69A patent/GB1287792A/en not_active Expired
-
1970
- 1970-02-05 DE DE2005160A patent/DE2005160C3/en not_active Expired
- 1970-02-09 BE BE745666D patent/BE745666A/en not_active IP Right Cessation
- 1970-02-09 IT IT48425/70A patent/IT1004006B/en active
- 1970-02-10 FR FR7004624A patent/FR2032835A5/fr not_active Expired
- 1970-02-10 CH CH188670A patent/CH515869A/en not_active IP Right Cessation
-
1973
- 1973-11-30 JP JP48133617A patent/JPS5037264B1/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
DE2005160A1 (en) | 1970-09-03 |
DE2005160C3 (en) | 1981-10-01 |
FR2032835A5 (en) | 1970-11-27 |
IT1004006B (en) | 1976-07-10 |
CH515869A (en) | 1971-11-30 |
DE2005160B2 (en) | 1981-02-19 |
JPS5037264B1 (en) | 1975-12-01 |
GB1287792A (en) | 1972-09-06 |
BE745666A (en) | 1970-08-10 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PE20 | Patent expired after termination of 20 years |