GB1277988A - Low noise level semiconductor device and method of manufacturing same - Google Patents
Low noise level semiconductor device and method of manufacturing sameInfo
- Publication number
- GB1277988A GB1277988A GB04771/70A GB1477170A GB1277988A GB 1277988 A GB1277988 A GB 1277988A GB 04771/70 A GB04771/70 A GB 04771/70A GB 1477170 A GB1477170 A GB 1477170A GB 1277988 A GB1277988 A GB 1277988A
- Authority
- GB
- United Kingdom
- Prior art keywords
- layer
- dislocation density
- emitter region
- nitrogen
- ethyl silicate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004065 semiconductor Substances 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 6
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical group CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 abstract 3
- 238000009792 diffusion process Methods 0.000 abstract 3
- 229910052757 nitrogen Inorganic materials 0.000 abstract 3
- 229910004298 SiO 2 Inorganic materials 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 238000005979 thermal decomposition reaction Methods 0.000 abstract 2
- 229910052718 tin Inorganic materials 0.000 abstract 2
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 abstract 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 229910006404 SnO 2 Inorganic materials 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- 239000012159 carrier gas Substances 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 239000012535 impurity Substances 0.000 abstract 1
- 230000007935 neutral effect Effects 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- WRECIMRULFAWHA-UHFFFAOYSA-N trimethyl borate Chemical compound COB(OC)OC WRECIMRULFAWHA-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
- H01L29/12—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
- H01L29/16—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only elements of Group IV of the Periodic System
- H01L29/167—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only elements of Group IV of the Periodic System further characterised by the doping material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02109—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
- H01L21/02112—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer
- H01L21/02123—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon
- H01L21/02126—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon the material containing Si, O, and at least one of H, N, C, F, or other non-metal elements, e.g. SiOC, SiOC:H or SiONC
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02225—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer
- H01L21/0226—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process
- H01L21/02263—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase
- H01L21/02271—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/22—Diffusion of impurity materials, e.g. doping materials, electrode materials, into or out of a semiconductor body, or between semiconductor regions; Interactions between two or more impurities; Redistribution of impurities
- H01L21/225—Diffusion of impurity materials, e.g. doping materials, electrode materials, into or out of a semiconductor body, or between semiconductor regions; Interactions between two or more impurities; Redistribution of impurities using diffusion into or out of a solid from or into a solid phase, e.g. a doped oxide layer
- H01L21/2251—Diffusion into or out of group IV semiconductors
- H01L21/2254—Diffusion into or out of group IV semiconductors from or through or into an applied layer, e.g. photoresist, nitrides
- H01L21/2255—Diffusion into or out of group IV semiconductors from or through or into an applied layer, e.g. photoresist, nitrides the applied layer comprising oxides only, e.g. P2O5, PSG, H3BO3, doped oxides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
- H01L29/06—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
- H01L29/08—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions with semiconductor regions connected to an electrode carrying current to be rectified, amplified or switched and such electrode being part of a semiconductor device which comprises three or more electrodes
- H01L29/0804—Emitter regions of bipolar transistors
Abstract
1277988 Semi-conductor devices MATSUSHITA ELECTRONICS CORP. 26 March 1970 [28 March 1969 (3)] 14771/70 Heading H1K The noise level in a Si transistor is reduced by providing a dislocation density in the emitter region of less than 10<SP>5</SP> cm.<SP>-2</SP>, and preferably also by arranging the surface concentration of conductivity-determining impurities in the emitter region to be in the range 1 Î 10<SP>19</SP>-5 x 10<SP>20</SP> atoms/cm.<SP>3</SP>. Three embodiments are described, each comprising a planar Si transistor having a B-doped base region diffused either from a B layer deposited from BBr 3 or from a SiO 2 - B 2 O 3 layer deposited by thermal decomposition of ethyl silicate and trimethyl borate. The emitter region may be formed by diffusion of P from a SiO 2 -P 2 O 5 layer containing 1-30% by wt. of P 2 O 5 , e.g. formed by thermal decomposition of the mixed vapours of ethyl silicate and trimethyl phosphate, and cooling the Si body slowly to produce the required low dislocation density. Dislocation density may also be reduced by including in the emitter region an electrically neutral element such as Sn or Ge. This may be achieved by incorporating SnO 2 into the mixed oxide layer which serves as the emitter diffusion source, the layer being sintered at 800 C. in oxygen before diffusion takes place at 1050 C. in nitrogen. The layer may be deposited from a carrier gas comprising nitrogen and oxygen, the nitrogen having been passed over solutions of ethyl silicate, trimethyl phosphate and tin tetranormalbutyl. In this case a phosphorus surface concentration of as high as 7 x 10<SP>20</SP> atoms/cm.<SP>3</SP> may be tolerated while maintaining the dislocation density below the required limit.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2402769A JPS5116311B1 (en) | 1969-03-28 | 1969-03-28 | |
JP2402969 | 1969-03-28 | ||
JP2402869A JPS5122347B1 (en) | 1969-03-28 | 1969-03-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1277988A true GB1277988A (en) | 1972-06-14 |
Family
ID=27284487
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB04771/70A Expired GB1277988A (en) | 1969-03-28 | 1970-03-26 | Low noise level semiconductor device and method of manufacturing same |
Country Status (3)
Country | Link |
---|---|
DE (1) | DE2014903B2 (en) |
FR (1) | FR2037280B1 (en) |
GB (1) | GB1277988A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0176409A2 (en) * | 1984-09-06 | 1986-04-02 | Fairchild Semiconductor Corporation | Cmos circuit having a reduced tendency to latch |
US4728998A (en) * | 1984-09-06 | 1988-03-01 | Fairchild Semiconductor Corporation | CMOS circuit having a reduced tendency to latch |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2189876A1 (en) * | 1972-06-23 | 1974-01-25 | Anvar | Radiation resistant silicon wafers - and solar cells made therefrom for use in space |
GB2049643B (en) * | 1979-05-30 | 1983-07-20 | Siemens Ag | Process for the production of silicon having semiconducting proprties |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3346428A (en) * | 1964-02-27 | 1967-10-10 | Matsushita Electronics Corp | Method of making semiconductor devices by double diffusion |
-
1970
- 1970-03-26 GB GB04771/70A patent/GB1277988A/en not_active Expired
- 1970-03-26 DE DE19702014903 patent/DE2014903B2/en not_active Withdrawn
- 1970-03-27 FR FR7011131A patent/FR2037280B1/fr not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0176409A2 (en) * | 1984-09-06 | 1986-04-02 | Fairchild Semiconductor Corporation | Cmos circuit having a reduced tendency to latch |
EP0176409A3 (en) * | 1984-09-06 | 1987-05-06 | Fairchild Camera & Instrument Corporation | Cmos circuit having a reduced tendency to latch |
US4728998A (en) * | 1984-09-06 | 1988-03-01 | Fairchild Semiconductor Corporation | CMOS circuit having a reduced tendency to latch |
Also Published As
Publication number | Publication date |
---|---|
FR2037280B1 (en) | 1974-10-11 |
FR2037280A1 (en) | 1970-12-31 |
DE2014903B2 (en) | 1973-06-28 |
DE2014903A1 (en) | 1970-10-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
746 | Register noted 'licences of right' (sect. 46/1977) | ||
PE20 | Patent expired after termination of 20 years |