GB1273623A - Halomethyl vinyl glycidyl ethers and polymers thereof - Google Patents

Halomethyl vinyl glycidyl ethers and polymers thereof

Info

Publication number
GB1273623A
GB1273623A GB1950669A GB1950669A GB1273623A GB 1273623 A GB1273623 A GB 1273623A GB 1950669 A GB1950669 A GB 1950669A GB 1950669 A GB1950669 A GB 1950669A GB 1273623 A GB1273623 A GB 1273623A
Authority
GB
United Kingdom
Prior art keywords
group
epoxide
halomethyl
methylene
reacting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1950669A
Inventor
Arthur Emilio Gurgiolo
Robert William Mcada
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Priority to GB1950669A priority Critical patent/GB1273623A/en
Publication of GB1273623A publication Critical patent/GB1273623A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/04—Saturated ethers
    • C07C43/13—Saturated ethers containing hydroxy or O-metal groups
    • C07C43/137—Saturated ethers containing hydroxy or O-metal groups containing halogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C08G65/14—Unsaturated oxiranes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/22—Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring
    • C08G65/223—Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring containing halogens

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Epoxy Compounds (AREA)

Abstract

1,273,623. Halohydrins and epoxides. DOW CHEMICAL CO. 16 April, 1969, No. 19506/69. Heading C2C. [Also in Division C3] Novel compounds of Formula I (wherein R is an alkylene group, a haloalkylene group, an aralkylene group or haloaralkylene group having from 2 to 4 carbon atoms in the alkylene portion of the group, X is Cl, Br or I, A is halomethyl-methylene group or a group, Y is an (-OH) group and Z is C1, Br or I or Y and Z taken together represent an epoxide link, and n is an integer of from 0 to 6 except that (i) when A is then Y and Z are taken together to represent an epoxide link, (ii) when Y is OH and Z is Cl, Br or I then A is a halomethyl-methylene group, and (iii) when A is a halomethyl-methylene group, R is a haloalkylene group and Y and Z are taken together to form an epoxide link then n is an integer from 2 to 6), are prepared by reacting, at 20‹ to 100‹ C. in the presence of a Lewis acid, a glycerine di-halohydrin with 0 to 6 moles of an alkylene oxide and then with at least one mole of an epihalohydrin, to give a compound I in which Y is OH and Z is Cl, Br or I, and, if desired, reacting this compound with 1 or 2 molar equivalents of a dehydrohalogenating agent to give compounds I in which Y and Z together form an epoxide group and A is a halomethyl-methylene or CH 2 = C< group, respectively. Compounds I in which A is a group and Y and Z together form an epoxide group, can also be prepared by reacting a compound I in which A is a halomethylmethylene group and Y and Z together form an epoxide group, with at least an equimolar amount of a dehydrohalogenating agent.
GB1950669A 1969-04-16 1969-04-16 Halomethyl vinyl glycidyl ethers and polymers thereof Expired GB1273623A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1950669A GB1273623A (en) 1969-04-16 1969-04-16 Halomethyl vinyl glycidyl ethers and polymers thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1950669A GB1273623A (en) 1969-04-16 1969-04-16 Halomethyl vinyl glycidyl ethers and polymers thereof

Publications (1)

Publication Number Publication Date
GB1273623A true GB1273623A (en) 1972-05-10

Family

ID=10130502

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1950669A Expired GB1273623A (en) 1969-04-16 1969-04-16 Halomethyl vinyl glycidyl ethers and polymers thereof

Country Status (1)

Country Link
GB (1) GB1273623A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0448933A1 (en) * 1990-03-27 1991-10-02 Deutsche Solvay-Werke Gmbh Process for the preparation of 2,2-dimethyl-4-(2',3'-epoxy)-propoxy-methyl-1,3-dioxolane

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0448933A1 (en) * 1990-03-27 1991-10-02 Deutsche Solvay-Werke Gmbh Process for the preparation of 2,2-dimethyl-4-(2',3'-epoxy)-propoxy-methyl-1,3-dioxolane

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee