GB1270292A - Method for obtaining bars of polymethyl methacrylate - Google Patents
Method for obtaining bars of polymethyl methacrylateInfo
- Publication number
- GB1270292A GB1270292A GB2083369A GB2083369A GB1270292A GB 1270292 A GB1270292 A GB 1270292A GB 2083369 A GB2083369 A GB 2083369A GB 2083369 A GB2083369 A GB 2083369A GB 1270292 A GB1270292 A GB 1270292A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polymethyl methacrylate
- bars
- cell
- temperature
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920003229 poly(methyl methacrylate) Polymers 0.000 title abstract 3
- 239000004926 polymethyl methacrylate Substances 0.000 title abstract 3
- 239000003999 initiator Substances 0.000 abstract 2
- 238000006116 polymerization reaction Methods 0.000 abstract 2
- 239000004342 Benzoyl peroxide Substances 0.000 abstract 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 abstract 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical group COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 abstract 1
- 239000004698 Polyethylene Substances 0.000 abstract 1
- 235000019400 benzoyl peroxide Nutrition 0.000 abstract 1
- 229920002301 cellulose acetate Polymers 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 abstract 1
- 229920003023 plastic Polymers 0.000 abstract 1
- 239000004033 plastic Substances 0.000 abstract 1
- -1 polyethylene Polymers 0.000 abstract 1
- 229920000573 polyethylene Polymers 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C39/00—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
- B29C39/003—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor characterised by the choice of material
- B29C39/006—Monomers or prepolymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/38—Moulds or cores; Details thereof or accessories therefor characterised by the material or the manufacturing process
- B29C33/40—Plastics, e.g. foam or rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2033/00—Use of polymers of unsaturated acids or derivatives thereof as moulding material
- B29K2033/04—Polymers of esters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2801/00—Use of cellulose, modified cellulose or cellulose derivatives, e.g. viscose, as mould material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2823/00—Use of polyalkenes or derivatives thereof as mould material
- B29K2823/04—Polymers of ethylene
- B29K2823/06—PE, i.e. polyethylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/06—Rods, e.g. connecting rods, rails, stakes
Abstract
1,270,292. Making polymethyl methacrylate bars. RUMANIA MINISTERUL INDUSTRIEIUSOARE MINISTER OF. 23 April, 1969, No. 20833/69. Heading C3P. Polymethyl methacrylate bars are prepared by prepolymerizing methyl methacrylate monomer to a monomer conversion of from 40-50% at a temperature of 80-90‹ C., and thereafter completing polymerization of the resulting prepolymer in a water-permeable, bar-shaped cell made of plastics material, the cell being immersed in water at a temperature of about 20‹ C. (e.g. 18-20‹ C.). The cell may be formed from porous polyethylene or cellulose acetate. In an example, the prepolymerization is effected with azoisobutyronitrile initiator, and polymerization is completed using a benzoyl peroxide/dimethyl aniline/cobalt naphthenate initiator system.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2083369A GB1270292A (en) | 1969-04-23 | 1969-04-23 | Method for obtaining bars of polymethyl methacrylate |
FR6913527A FR2041538A5 (en) | 1969-04-23 | 1969-04-29 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2083369A GB1270292A (en) | 1969-04-23 | 1969-04-23 | Method for obtaining bars of polymethyl methacrylate |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1270292A true GB1270292A (en) | 1972-04-12 |
Family
ID=10152477
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2083369A Expired GB1270292A (en) | 1969-04-23 | 1969-04-23 | Method for obtaining bars of polymethyl methacrylate |
Country Status (2)
Country | Link |
---|---|
FR (1) | FR2041538A5 (en) |
GB (1) | GB1270292A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4369299A (en) | 1977-11-11 | 1983-01-18 | Asahi Kasei Kogyo Kabushiki Kaisha | Acrylic resin having excellent solvent resistance and moldability |
US4937302A (en) * | 1988-02-05 | 1990-06-26 | Rohm Gmbh | Method for separating methanol-methyl methacrylate mixtures |
-
1969
- 1969-04-23 GB GB2083369A patent/GB1270292A/en not_active Expired
- 1969-04-29 FR FR6913527A patent/FR2041538A5/fr not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4369299A (en) | 1977-11-11 | 1983-01-18 | Asahi Kasei Kogyo Kabushiki Kaisha | Acrylic resin having excellent solvent resistance and moldability |
US4937302A (en) * | 1988-02-05 | 1990-06-26 | Rohm Gmbh | Method for separating methanol-methyl methacrylate mixtures |
Also Published As
Publication number | Publication date |
---|---|
FR2041538A5 (en) | 1971-01-29 |
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