GB1267259A - - Google Patents

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Publication number
GB1267259A
GB1267259A GB1267259DA GB1267259A GB 1267259 A GB1267259 A GB 1267259A GB 1267259D A GB1267259D A GB 1267259DA GB 1267259 A GB1267259 A GB 1267259A
Authority
GB
United Kingdom
Prior art keywords
ether
radical
ethers
carbon atoms
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Publication of GB1267259A publication Critical patent/GB1267259A/en
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/22—Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/04—Saturated ethers
    • C07C43/10—Saturated ethers of polyhydroxy compounds
    • C07C43/11—Polyethers containing —O—(C—C—O—)n units with ≤ 2 n≤ 10
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/321—Polymers modified by chemical after-treatment with inorganic compounds
    • C08G65/324—Polymers modified by chemical after-treatment with inorganic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/334—Polymers modified by chemical after-treatment with organic compounds containing sulfur
    • C08G65/3342—Polymers modified by chemical after-treatment with organic compounds containing sulfur having sulfur bound to carbon and hydrogen

Abstract

1,267,259. Ethers. L'OREAL. 9 Dec., 1969 [9 Dec., 1968], No. 60134/69. Heading C2C. A process for the preparation of polyhydroxylated ethers and polyhydroxylated polyethers and compositions containing them, comprises (1) reacting tertiary butyl-glycidyl-ether, in the presence of an acid or basic catalyst, with a compound, or mixture of compounds, containing at least one reactive hydrogen atom, having the general formula: R(XH) a in which a is an integer from 1 to 6; R is a radical of valency " a " and represents a hydrogen atom, a saturated or unsaturated, linear or branched, aliphatic hydrocarbon radical containing 1 to 30 carbon atoms, optionally substituted by one or more halogen atoms, a divalent polyoxyalkylene radical, an alkyl-polyoxyalkylene radical or an alkenyl-polyoxyalkylene radical containing 3 to 60 carbon atoms and 1 to 10 oxygen atoms, a saturated or unsaturated substituted or unsubstituted, cycloaliphatic radical containing 6 to 30 carbon atoms, or a substituted or unsubstituted aromatic radical; the or each of the X radicals, which may be the same or different, represents an oxygen or sulphur atom; the ratio (n), expressed in moles of tertiary butylglycidyl-ether per gram-atom of active hydrogen in the compound of formula R(XH) a being from 0À1 : 1 to 10 : 1 so as to obtain mono- or polyethers containing units of formula and (2) heterolysing the tertiary butoxy group or groups in the presence of controlled amounts of water (as hereinbefore defined) and a catalytic amount of a sulphonic acid. Stage (1) may be effected in the presence of acid or basic catalysts. Simple ethers or telomers may be produced. The catalysts from stage (2) may be removed as their insoluble salts by basic ionexchange resins or merely be neutralized. If they contain carboxyl groups these may esterify the hydroxy-ether product; such derivatives may be saponified. The hydroxy-ether products are surfactants. Examples prepare: the α-nhexyl ether of glycerine; telomers from lauryl alcohol, mixed cetyl and stearyl alcohols, propoxylated stearyl alcohol and glycerol α- monodichlorohydrin; 3-phenoxypropanediol-1,2 and dodecylthipropanediol, the t - butylated derivatives being obtained as intermediates in each case.
GB1267259D 1968-12-09 1969-12-09 Expired GB1267259A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
LU57504 1968-12-09

Publications (1)

Publication Number Publication Date
GB1267259A true GB1267259A (en) 1972-03-15

Family

ID=19725824

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1267259D Expired GB1267259A (en) 1968-12-09 1969-12-09

Country Status (6)

Country Link
BE (1) BE742779A (en)
CH (1) CH517136A (en)
DE (1) DE1961731C3 (en)
FR (1) FR2027585A1 (en)
GB (1) GB1267259A (en)
LU (1) LU57504A1 (en)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4003961A (en) * 1974-02-20 1977-01-18 The Dow Chemical Company Linear copolymers of glycidol
US4014854A (en) * 1974-02-20 1977-03-29 The Dow Chemical Company Linear copolymers of glycidol
US4048237A (en) * 1973-11-12 1977-09-13 The Dow Chemical Company Process for the dealkylation of t-butyl and t-amyl ethers on polymeric backbones
US4077991A (en) * 1974-05-02 1978-03-07 The Dow Chemical Company Copolymers of glycidol and glycidyl esters
US4086151A (en) * 1974-02-20 1978-04-25 The Dow Chemical Company Curable mixtures and cured resins made from linear polymers of glycidol
US4092339A (en) * 1974-05-02 1978-05-30 The Dow Chemical Company Process for making polyglycidyl esters
US4125369A (en) 1977-03-28 1978-11-14 The Dow Chemical Company Permanent topical textile antistats
US4496494A (en) * 1981-04-02 1985-01-29 The Dow Chemical Company Process for preparation of (halo)(hydroxy)-substituted phosphites and phosphorates
GB2185746A (en) * 1986-01-27 1987-07-29 Oreal New polyglycerol ethers and their use in cosmetics and in pharmacy
US4754048A (en) * 1981-04-02 1988-06-28 The Dow Chemical Company (Halo)(hydroxy)-substituted phosphites and phosphorates
US4864049A (en) * 1981-04-02 1989-09-05 The Dow Chemical Company (Halo)(hydroxy)-substituted phosphites and phosphorates
EP2524938A1 (en) 2011-05-18 2012-11-21 Evonik Goldschmidt GmbH Alkoxylation products and method for producing same by means of DMC catalysts
WO2013017360A1 (en) 2011-08-03 2013-02-07 Evonik Goldschmidt Gmbh Method for producing branched polyethercarbonates and use thereof
CN114716661A (en) * 2021-09-03 2022-07-08 联泓(江苏)新材料研究院有限公司 Short-chain alcohol intermediate for efficiently preparing high-molecular-weight polyether synthetic oil and preparation method and application thereof

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2430944A1 (en) * 1978-07-13 1980-02-08 Oreal NOVEL SURFACTANT POLYPOD COMPOUNDS, PROCESS FOR PREPARING THE SAME AND COMPOSITIONS CONTAINING THE SAME
JPS5993022A (en) * 1982-11-16 1984-05-29 Kao Corp Polyol ether compound, its preparation and cosmetic containing the same
FR2560880B1 (en) * 1984-03-07 1989-03-31 Oreal NOVEL GLYCOSYL POLYETHERS, THEIR PREPARATION PROCESS AND THEIR USE
FR2574786B1 (en) * 1984-12-17 1988-06-10 Oreal PROCESS FOR THE PREPARATION OF NON-IONIC SURFACES FROM GLYCEROL MONOCHLORHYDRIN, PRODUCTS OBTAINED AND COMPOSITION CONTAINING THEM
FR2641985B1 (en) * 1989-01-26 1992-06-19 Oreal
FR2643828B1 (en) * 1989-01-26 1994-01-07 Oreal PROCESS FOR THE PREPARATION OF NON-IONIC SURFACTANTS FROM ISOPROPYLIDENE-1,2 EPOXYPROPYL-3 GLYCEROL AND HYDROXYL COMPOUNDS, NEW NON-IONIC SURFACTANTS AND THEIR USE

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2089569A (en) * 1932-03-02 1937-08-10 Gen Aniline Works Inc Addition products of glycide to organic compounds
US2260753A (en) * 1939-10-23 1941-10-28 Shell Dev Process for the production of derivatives of epihalohydrins
GB802325A (en) * 1954-06-16 1958-10-01 Thomas Hedley & Company Ltd Improvements in or relating to alkyl polyglyceryl ether compounds

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4048237A (en) * 1973-11-12 1977-09-13 The Dow Chemical Company Process for the dealkylation of t-butyl and t-amyl ethers on polymeric backbones
US4014854A (en) * 1974-02-20 1977-03-29 The Dow Chemical Company Linear copolymers of glycidol
US4086151A (en) * 1974-02-20 1978-04-25 The Dow Chemical Company Curable mixtures and cured resins made from linear polymers of glycidol
US4003961A (en) * 1974-02-20 1977-01-18 The Dow Chemical Company Linear copolymers of glycidol
US4077991A (en) * 1974-05-02 1978-03-07 The Dow Chemical Company Copolymers of glycidol and glycidyl esters
US4092339A (en) * 1974-05-02 1978-05-30 The Dow Chemical Company Process for making polyglycidyl esters
US4125369A (en) 1977-03-28 1978-11-14 The Dow Chemical Company Permanent topical textile antistats
US4864049A (en) * 1981-04-02 1989-09-05 The Dow Chemical Company (Halo)(hydroxy)-substituted phosphites and phosphorates
US4496494A (en) * 1981-04-02 1985-01-29 The Dow Chemical Company Process for preparation of (halo)(hydroxy)-substituted phosphites and phosphorates
US4754048A (en) * 1981-04-02 1988-06-28 The Dow Chemical Company (Halo)(hydroxy)-substituted phosphites and phosphorates
GB2185746A (en) * 1986-01-27 1987-07-29 Oreal New polyglycerol ethers and their use in cosmetics and in pharmacy
GB2185746B (en) * 1986-01-27 1989-11-01 Oreal New polyglycerol ethers and their use in cosmetics and in pharmacy
EP2524938A1 (en) 2011-05-18 2012-11-21 Evonik Goldschmidt GmbH Alkoxylation products and method for producing same by means of DMC catalysts
DE102011076019A1 (en) 2011-05-18 2012-11-22 Evonik Goldschmidt Gmbh Alkoxylation products and processes for their preparation by means of DMC catalysts
US9068044B2 (en) 2011-05-18 2015-06-30 Evonik Degussa Gmbh Alkoxylation products and process for preparing them by means of DMC catalysts
WO2013017360A1 (en) 2011-08-03 2013-02-07 Evonik Goldschmidt Gmbh Method for producing branched polyethercarbonates and use thereof
DE102011109614A1 (en) 2011-08-03 2013-02-07 Evonik Goldschmidt Gmbh Process for the preparation of branched polyethercarbonates and their use
CN114716661A (en) * 2021-09-03 2022-07-08 联泓(江苏)新材料研究院有限公司 Short-chain alcohol intermediate for efficiently preparing high-molecular-weight polyether synthetic oil and preparation method and application thereof

Also Published As

Publication number Publication date
BE742779A (en) 1970-06-08
DE1961731A1 (en) 1970-06-18
LU57504A1 (en) 1970-06-09
FR2027585A1 (en) 1970-10-02
DE1961731B2 (en) 1980-10-09
DE1961731C3 (en) 1981-10-29
CH517136A (en) 1971-12-31

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Legal Events

Date Code Title Description
PS Patent sealed
PE20 Patent expired after termination of 20 years