GB1265198A - - Google Patents

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Publication number
GB1265198A
GB1265198A GB1265198DA GB1265198A GB 1265198 A GB1265198 A GB 1265198A GB 1265198D A GB1265198D A GB 1265198DA GB 1265198 A GB1265198 A GB 1265198A
Authority
GB
United Kingdom
Prior art keywords
propylene
group
pentene
ethylene
hydrocarbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Publication of GB1265198A publication Critical patent/GB1265198A/en
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F16/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F16/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F16/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an alcohol radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/10—Acylation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/10—Copolymer characterised by the proportions of the comonomers expressed as molar percentages

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

1,265,198. Hydrocarbon copolymers. MITSUI PETROCHEMICAL INDUSTRIES Ltd. 17 Sept., 1969 [17 Sept., 1968; 2 June, 1969], No. 45929/69. Heading C3P. [Also in Division C2] Copolymers, claimed per se, consisting of (A) an alpha-monoethylenically unsaturated hydrocarbon unit, and (B) a unit of the formula wherein Z is a divalent C 2-20 hydrocarbon group, the -CH 2 -CH- group being separated from the oxygen atom by at least two carbon atoms, and A<SP>1</SP> is hydrogen or an acyl group, the unit (B) being present as 0À005-30 mol. per cent relative to unit (A), are prepared by polymerizing at least one alpha-monoethylenically unsaturated hydrocarbon with at least one ethylenically unsaturated hydrocarbyloxy compound of the general formula wherein Z is a divalent C 2-20 hydrocarbon group, the vinyl group being separated from the oxygen atom by at least two carbon atoms, A is halogen and/or a monovalent C 1-8 hydrocarbon group, M is a Group I, II, III or IV metal, n is an integer from 1 to the valency of the metal M and m is equal to (M-n), or MAm is vanadyl and n is 3 in the presence of a catalyst which comprises a halogen compound of titanium or vanadium, and, where the ethylenically unsaturated hydrocarbyloxy compound contains no metal-carbon bond, an organoaluminium or organozinc compound which contains one or more such bonds. The catalyst can be destroyed with an alcohol, hydrochloric acid or a carboxylic acid anhydride to give a copolymer containing hydrogen or an acyl group (i.e. A<SP>1</SP>). In the examples the following are prepared: copolymers of propylene with 10 - undecene - 1 - ol, 10 - undecenyl acetate, 2 - allyl phenol, 4 - pentene - 1 - ol, 5 - hexene- 1 - ol, 1 - methyl - 5 - pentene - 1 - ol, and 2,7- octadiene - l - ol, ethylene/10 - undecen - l - ol, ethylene/4-pentene-1-ol, 4 - methyl - 1 - pentene/10 - undecen - 1 - ol and a terpolymer of ethylene, propylene and 10-undecen-1-ol. The exemplified metals M are Al, Zn, K, Ti, Ca, Mg and Na; the exemplified titanium and vanadium compounds are TiCl 4 , TiCl 3 and VOCl 3 and the exemplified additional organo metallic compounds are (C 2 H 5 ) 2 AlCl, 2-allylphenoxydiethylaluminium, (C 2 H 5 ) 2 Zn and ethylaluminium sesquichloride. The aftertreatment of the polymer products described comprises (a) acetylation by treatment with pyridine and acetic anhydride in xylene; (b) uretanation by treatment with phenyl isocyanate; (c) moulding into pellets, extruding and stretching in water to form filaments which are dyed in a bath containing a disperse dye in a dispersing agent; (d) blending with a homopolymer of ethylene or propylene, in one case followed by dyeing; and (e) blending of propylene/10-undecene-1-ol copolymer with propylene homopolymer and toluene diisocyanate and forming a cross-linked copolymer by the action of heat and pressure.
GB1265198D 1968-09-17 1969-09-17 Expired GB1265198A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP6661968 1968-09-17
JP4244269 1969-06-02

Publications (1)

Publication Number Publication Date
GB1265198A true GB1265198A (en) 1972-03-01

Family

ID=26382132

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1265198D Expired GB1265198A (en) 1968-09-17 1969-09-17

Country Status (3)

Country Link
DE (1) DE1947109C3 (en)
FR (1) FR2018263A1 (en)
GB (1) GB1265198A (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2901647A1 (en) * 1979-01-17 1980-07-24 Bayer Ag METHOD FOR PRODUCING ALPHA-OLEFIN COPOLYMERS CONTAINING POLAR GROUPS
DE2901646A1 (en) * 1979-01-17 1980-07-24 Bayer Ag METHOD FOR PRODUCING ALPHA -OLEFIN-COPOLYMERS CONTAINING POLAR GROUPS
US5382642A (en) * 1993-07-28 1995-01-17 Arco Chemical Technology, L.P. Copolymers of allyl alcohol propoxylates and vinyl aromatic monomers
US5451652A (en) * 1994-04-28 1995-09-19 Arco Chemical Technology, L.P. Polymers from propoxylated allyl alcohol
US5543483A (en) * 1994-09-21 1996-08-06 Arco Chemical Technology, L.P. Hydroxy-functional allyl terpolymers
US6423787B1 (en) * 1997-04-18 2002-07-23 Kaneka Corporation Polymers, processes for producing the same, and curable compositions produced therefrom

Also Published As

Publication number Publication date
DE1947109C3 (en) 1978-03-23
DE1947109B2 (en) 1977-07-21
FR2018263A1 (en) 1970-05-29
DE1947109A1 (en) 1970-03-26

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee