GB1262986A - Processes for the manufacture of organotin compounds - Google Patents
Processes for the manufacture of organotin compoundsInfo
- Publication number
- GB1262986A GB1262986A GB54060/69A GB5406069A GB1262986A GB 1262986 A GB1262986 A GB 1262986A GB 54060/69 A GB54060/69 A GB 54060/69A GB 5406069 A GB5406069 A GB 5406069A GB 1262986 A GB1262986 A GB 1262986A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sncl
- prepared
- tricyclohexyltin
- reacting
- tin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract 3
- -1 tricyclohexyltin halides Chemical class 0.000 abstract 3
- 239000000376 reactant Substances 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 230000007062 hydrolysis Effects 0.000 abstract 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 abstract 1
- YICRPERKKBDRSP-UHFFFAOYSA-N methyl 3-amino-4-methylthiophene-2-carboxylate Chemical compound COC(=O)C=1SC=C(C)C=1N YICRPERKKBDRSP-UHFFFAOYSA-N 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 1
- 125000000962 organic group Chemical group 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/2208—Compounds having tin linked only to carbon, hydrogen and/or halogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1,262,986. Preparation of tricyclohexyltin halides. M & T INTERNATIONAL N.V. 4 Nov., 1969 [4 Nov., 1968; 16 April, 1969], No. 54060/69. Heading C2J. A process for preparing a tricyclohexyltin halide, the cyclohexyl rings of which may be inertly substituted, comprises reacting an organotricyclohexyltin with a tin tetrahalide, usually in equimolar quantities at 0-120 C. in a solvent. Specified inert substituents are methyl, isopropyl, n-butyl, t-butyl and phenyl groups. The organo group in the first reactant may be alkyl, alkenyl, cycloalkyl, aralkyl, aryl or alkaryl and may be inertly substituted, many such groups being specified. The first reactant is usually obtained by reacting an organotin trihalide and a cyclohexyl magnesium halide in a hydrocarbon solvent, the organotricyclohexyl tin being recovered by hydrolysis of the reaction mixture with aqueous citric acid. The organotin trihalide may be prepared by reacting a tetraorganotin with a tin tetrahalide. In the examples, tricyclohexyltin chloride is prepared from (a) SnCl 4 and C 6 H 5 Sn(C 6 H 11 ) 3 , the latter being prepared from C 6 H 5 SnCl 3 (from SnCl 4 and (C 6 H 5 ) 4 Sn) and C 6 H 11 MgCl and from (b) SnCl 4 and C 4 H 9 Sn(C 6 H 11 ) 3 .
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US77333168A | 1968-11-04 | 1968-11-04 | |
| US81678369A | 1969-04-16 | 1969-04-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1262986A true GB1262986A (en) | 1972-02-09 |
Family
ID=27118739
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB54060/69A Expired GB1262986A (en) | 1968-11-04 | 1969-11-04 | Processes for the manufacture of organotin compounds |
Country Status (13)
| Country | Link |
|---|---|
| AT (1) | AT293437B (en) |
| BE (1) | BE741260A (en) |
| BR (1) | BR6913863D0 (en) |
| CH (1) | CH539655A (en) |
| DE (1) | DE1955463C3 (en) |
| DK (1) | DK130300B (en) |
| ES (1) | ES373121A1 (en) |
| FR (1) | FR2022521A1 (en) |
| GB (1) | GB1262986A (en) |
| IL (1) | IL33291A (en) |
| NL (1) | NL166946C (en) |
| NO (1) | NO131934C (en) |
| SE (2) | SE393382B (en) |
-
1969
- 1969-11-03 FR FR6937720A patent/FR2022521A1/fr active Pending
- 1969-11-03 IL IL33291A patent/IL33291A/en unknown
- 1969-11-03 BR BR213863/69A patent/BR6913863D0/en unknown
- 1969-11-03 SE SE7216419A patent/SE393382B/en unknown
- 1969-11-03 ES ES373121A patent/ES373121A1/en not_active Expired
- 1969-11-03 SE SE15018/69A patent/SE361481B/xx unknown
- 1969-11-03 NO NO4341/69A patent/NO131934C/no unknown
- 1969-11-03 DK DK579769AA patent/DK130300B/en not_active IP Right Cessation
- 1969-11-04 CH CH1644669A patent/CH539655A/en not_active IP Right Cessation
- 1969-11-04 GB GB54060/69A patent/GB1262986A/en not_active Expired
- 1969-11-04 NL NL6916581.A patent/NL166946C/en not_active IP Right Cessation
- 1969-11-04 BE BE741260D patent/BE741260A/xx unknown
- 1969-11-04 DE DE1955463A patent/DE1955463C3/en not_active Expired
- 1969-11-04 AT AT1036469A patent/AT293437B/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| DK130300C (en) | 1975-06-30 |
| DK130300B (en) | 1975-02-03 |
| NL166946B (en) | 1981-05-15 |
| NL166946C (en) | 1981-10-15 |
| IL33291A (en) | 1972-12-29 |
| NO131934B (en) | 1975-05-20 |
| DE1955463A1 (en) | 1970-05-06 |
| NL6916581A (en) | 1970-05-08 |
| SE393382B (en) | 1977-05-09 |
| SE361481B (en) | 1973-11-05 |
| BE741260A (en) | 1970-04-16 |
| AT293437B (en) | 1971-10-11 |
| NO131934C (en) | 1975-08-27 |
| BR6913863D0 (en) | 1973-04-05 |
| DE1955463C3 (en) | 1979-07-12 |
| FR2022521A1 (en) | 1970-07-31 |
| IL33291A0 (en) | 1970-01-29 |
| ES373121A1 (en) | 1971-12-16 |
| DE1955463B2 (en) | 1978-11-16 |
| CH539655A (en) | 1973-07-31 |
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