GB1200273A - Method of producing aryl and vinyl phosphonic acid esters, aryl and vinyl phosphinic acid esters or aryl and vinyl phosphinic oxides - Google Patents

Method of producing aryl and vinyl phosphonic acid esters, aryl and vinyl phosphinic acid esters or aryl and vinyl phosphinic oxides

Info

Publication number
GB1200273A
GB1200273A GB56309/68A GB5630968A GB1200273A GB 1200273 A GB1200273 A GB 1200273A GB 56309/68 A GB56309/68 A GB 56309/68A GB 5630968 A GB5630968 A GB 5630968A GB 1200273 A GB1200273 A GB 1200273A
Authority
GB
United Kingdom
Prior art keywords
aryl
vinyl
acid esters
phosphinic
producing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB56309/68A
Inventor
Peter Tavs
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to CH1736368A priority Critical patent/CH505152A/en
Priority to DE19681810431 priority patent/DE1810431A1/en
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Priority to GB56309/68A priority patent/GB1200273A/en
Priority to NL6817815A priority patent/NL6817815A/xx
Priority to BE725475D priority patent/BE725475A/xx
Publication of GB1200273A publication Critical patent/GB1200273A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/30—Phosphinic acids R2P(=O)(OH); Thiophosphinic acids, i.e. R2P(=X)(XH) (X = S, Se)
    • C07F9/32—Esters thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se)
    • C07F9/40—Esters thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se)
    • C07F9/40—Esters thereof
    • C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4021—Esters of aromatic acids (P-C aromatic linkage)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/46—Phosphinous acids R2=P—OH; Thiophosphinous acids; Aminophosphines R2-P-NH2 including R2P(=O)H; derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C08K5/5397—Phosphine oxides

Abstract

1,200,273. Preparing aryl or vinyl esters. SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ N.V. 27 Nov., 1968, No. 56309/68. Heading C2C. A method of producing an aryl or a vinyl phosphonic acid ester, an aryl or a vinyl phosphinic acid ester, or an aryl or a vinyl phosphine oxide, or a mixture containing at least one such compound, comprises reacting a compound R(Hal) n where Hal is halogen, R is an optionally substituted aryl or vinyl group and n represents 1 or 2, with a trialkyl phosphite, an alkylalkylene phosphite, a dialkyl-phosphonite, or an alkyl phosphinite, optionally in the presence of a solvent, at a temperature between 50‹ and 250‹ C. in the presence of catalytic quantities of a nickel halide and in an inert gas atmosphere. The term "aryl" includes hetero aryl compounds e.g. thiophene. The nickel halide is preferably dried before use and an amount between 0À1 and 20 mol. per cent with respect to aryl or vinyl halide is preferably used. In general, temperatures between 130‹ and 200‹ C. are used, and the reaction may be carried out batchwise or continuously.
GB56309/68A 1968-11-21 1968-11-27 Method of producing aryl and vinyl phosphonic acid esters, aryl and vinyl phosphinic acid esters or aryl and vinyl phosphinic oxides Expired GB1200273A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CH1736368A CH505152A (en) 1968-11-21 1968-11-21 Process for the production of phosphonic acid esters, phosphinic acid esters or phosphine oxides
DE19681810431 DE1810431A1 (en) 1968-11-21 1968-11-22 Process for the production of aryl and vinyl phosphonic acid esters, aryl and vinyl phosphinic acid esters or aryl and vinyl phosphine oxides
GB56309/68A GB1200273A (en) 1968-11-21 1968-11-27 Method of producing aryl and vinyl phosphonic acid esters, aryl and vinyl phosphinic acid esters or aryl and vinyl phosphinic oxides
NL6817815A NL6817815A (en) 1968-11-21 1968-12-12
BE725475D BE725475A (en) 1968-11-21 1968-12-13

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
CH1736368A CH505152A (en) 1968-11-21 1968-11-21 Process for the production of phosphonic acid esters, phosphinic acid esters or phosphine oxides
DE19681810431 DE1810431A1 (en) 1968-11-21 1968-11-22 Process for the production of aryl and vinyl phosphonic acid esters, aryl and vinyl phosphinic acid esters or aryl and vinyl phosphine oxides
GB56309/68A GB1200273A (en) 1968-11-21 1968-11-27 Method of producing aryl and vinyl phosphonic acid esters, aryl and vinyl phosphinic acid esters or aryl and vinyl phosphinic oxides
NL6817815A NL6817815A (en) 1968-11-21 1968-12-12
BE725475 1968-12-13

Publications (1)

Publication Number Publication Date
GB1200273A true GB1200273A (en) 1970-07-29

Family

ID=27507704

Family Applications (1)

Application Number Title Priority Date Filing Date
GB56309/68A Expired GB1200273A (en) 1968-11-21 1968-11-27 Method of producing aryl and vinyl phosphonic acid esters, aryl and vinyl phosphinic acid esters or aryl and vinyl phosphinic oxides

Country Status (5)

Country Link
BE (1) BE725475A (en)
CH (1) CH505152A (en)
DE (1) DE1810431A1 (en)
GB (1) GB1200273A (en)
NL (1) NL6817815A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4279813A (en) * 1978-07-06 1981-07-21 Bayer Aktiengesellschaft Aqueous process for the preparation of aromatic phosphorus compounds
US4444930A (en) * 1981-08-26 1984-04-24 Ato Chimie Fire-resistant synthetic resin composition containing a polycarbonate, a phosphorous fireproofing additive, and possibly other additives and/or fillers, and articles made from this composition
WO2002042248A2 (en) * 2000-11-24 2002-05-30 Novartis Ag Naphthalene derivatives
US6613717B1 (en) 1999-04-27 2003-09-02 Basf Aktiengesellschaft Phosphoric benzoyl derivatives and their use as herbicides
AU2009240832B2 (en) * 2000-11-24 2012-03-15 Novartis Ag Naphthalene derivatives
CN112321637A (en) * 2020-11-26 2021-02-05 重庆化工职业学院 Novel diphosphonate compound and synthesis method thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3025377C2 (en) * 1980-07-04 1983-06-23 Bayer Ag, 5090 Leverkusen Process for the preparation of diphenyl benzene phosphonate

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4279813A (en) * 1978-07-06 1981-07-21 Bayer Aktiengesellschaft Aqueous process for the preparation of aromatic phosphorus compounds
US4444930A (en) * 1981-08-26 1984-04-24 Ato Chimie Fire-resistant synthetic resin composition containing a polycarbonate, a phosphorous fireproofing additive, and possibly other additives and/or fillers, and articles made from this composition
US6613717B1 (en) 1999-04-27 2003-09-02 Basf Aktiengesellschaft Phosphoric benzoyl derivatives and their use as herbicides
WO2002042248A2 (en) * 2000-11-24 2002-05-30 Novartis Ag Naphthalene derivatives
WO2002042248A3 (en) * 2000-11-24 2002-12-19 Novartis Ag Naphthalene derivatives
JP2004514663A (en) * 2000-11-24 2004-05-20 ノバルティス　アクチエンゲゼルシャフト Naphthalene derivatives
US7045533B2 (en) 2000-11-24 2006-05-16 Novartis Ag Naphthalene derivatives
JP2008050361A (en) * 2000-11-24 2008-03-06 Novartis Ag Naphthalene derivatives
AU2009240832B2 (en) * 2000-11-24 2012-03-15 Novartis Ag Naphthalene derivatives
CN112321637A (en) * 2020-11-26 2021-02-05 重庆化工职业学院 Novel diphosphonate compound and synthesis method thereof

Also Published As

Publication number Publication date
CH505152A (en) 1971-03-31
BE725475A (en) 1969-06-13
NL6817815A (en) 1970-06-16
DE1810431A1 (en) 1970-06-11

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PLNP Patent lapsed through nonpayment of renewal fees