GB1262547A - Alkoxyvinylphosphonodithioates - Google Patents
AlkoxyvinylphosphonodithioatesInfo
- Publication number
- GB1262547A GB1262547A GB2271569A GB2271569A GB1262547A GB 1262547 A GB1262547 A GB 1262547A GB 2271569 A GB2271569 A GB 2271569A GB 2271569 A GB2271569 A GB 2271569A GB 1262547 A GB1262547 A GB 1262547A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkoxyvinylphosphonodithioates
- alkyl
- chlorophenyl
- phenyl
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- KNIUHBNRWZGIQQ-UHFFFAOYSA-N 7-diethoxyphosphinothioyloxy-4-methylchromen-2-one Chemical compound CC1=CC(=O)OC2=CC(OP(=S)(OCC)OCC)=CC=C21 KNIUHBNRWZGIQQ-UHFFFAOYSA-N 0.000 abstract 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 abstract 1
- 239000000443 aerosol Substances 0.000 abstract 1
- -1 alkyl vinyl ether Chemical compound 0.000 abstract 1
- 125000000068 chlorophenyl group Chemical group 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000006704 dehydrohalogenation reaction Methods 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 239000000428 dust Substances 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000001069 nematicidal effect Effects 0.000 abstract 1
- 125000003854 p-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Cl 0.000 abstract 1
- 125000005499 phosphonyl group Chemical group 0.000 abstract 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 150000003512 tertiary amines Chemical class 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4015—Esters of acyclic unsaturated acids
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Agronomy & Crop Science (AREA)
Abstract
1,262,547. Alkoxyvinylphosphonodithioates; alkoxyvinyl phosphonyl dichlorides. FARBENFABRIKEN BAYER A.G. 5 May, 1969, No. 22715/69. Heading C2P. The invention comprises alkoxyvinylphosphonodithioates of the formula wherein R 1 is methyl, propyl, isopropyl or tbutyl and R 2 and R 3 which may be the same or different are C 1 -C 8 alkyl, phenyl, C 1 -C 4 alkyl, phenyl or chlorophenyl. They may be obtained by reacting the corresponding alkyl vinyl ether with PCl 5 to form a 2-alkoxy-2-chloroethyl phosphorus tetrachloride complex, treating the latter with 2 moles of SO 2 per mole of complex with accompanying or subsequent dehydrohalogenation to form an alkoxyvinylphosphonyl dichloride and finally esterifying the latter with an appropriate mercaptan in the presence of a tertiary amine. The products have nematocidal properties and can be used in admixture with a solid or liquid diluent. The composition may also contain a surface active agent and may be in the form of a dust or in a form suitable for application as an aerosol. Some compounds of Formula I in which R 1 is ethyl and p-chlorophenyl are also referred to for comparative purposes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2271569A GB1262547A (en) | 1969-05-05 | 1969-05-05 | Alkoxyvinylphosphonodithioates |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2271569A GB1262547A (en) | 1969-05-05 | 1969-05-05 | Alkoxyvinylphosphonodithioates |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1262547A true GB1262547A (en) | 1972-02-02 |
Family
ID=10183945
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2271569A Expired GB1262547A (en) | 1969-05-05 | 1969-05-05 | Alkoxyvinylphosphonodithioates |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1262547A (en) |
-
1969
- 1969-05-05 GB GB2271569A patent/GB1262547A/en not_active Expired
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