GB1258807A - - Google Patents

Info

Publication number
GB1258807A
GB1258807A GB1258807DA GB1258807A GB 1258807 A GB1258807 A GB 1258807A GB 1258807D A GB1258807D A GB 1258807DA GB 1258807 A GB1258807 A GB 1258807A
Authority
GB
United Kingdom
Prior art keywords
olefins
aromatics
pyrolysis
reforming
pyrolysate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Publication of GB1258807A publication Critical patent/GB1258807A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G69/00Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
    • C10G69/02Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
    • C10G69/06Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one step of thermal cracking in the absence of hydrogen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20C2-C4 olefins
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/40Ethylene production

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1,258,807. Producing aromatics, olefins and diolefins. FOSTER WHEELER CORP., and SUN OIL CO. 21 March, 1969 [21 March, 1968], No. 15059/69. Heading C5E. Aromatics, olefins (particularly ethylene) and di-olefins are obtained from naphtha by a process comprising (a) catalytic reforming to convert naphthenes to aromatics, (b) pyrolysing the reformate, without intermediate separation of its normally liquid components, at a coil outlet temperature of 1450-1550‹ F. for 0À1-0À6 second, and (c) quenching to produce a gas stream comprising olefins and di-olefins and a predominantly aromatic liquid stream boiling in the range 169-350‹ F. Suitable reforming conditions are 600-1000‹ F., pressures up to 1000 p.s.i.g., hydrogen : hydrocarbon ratio up to 10,000, and Pt/alumina or chromia/alumina or catalyst. The pyrolysis may be carried out in the presence of an inert diluent, e.g. steam, N 2 or CO 2 . As particularly described, the process also includes the following additional steps: (i) initial desulphurization of the naphtha; (ii) mixing the reformate, before pyrolysis, with a recycled C 5 cut; (iii) hydrotreating the aromatic-rich product to remove olefins and di-olefins; (iv) removing C 4 and C 5 cuts from the hydrotreated pyrolysate, and recycling the C 5 cut to (ii); (v) removing benzene from the pyrolysate; and (vi) dealkylating the higher aromatic residue in either the presence or the absence of a catalyst. Examples describe the reforming and pyrolysis steps (a) and (b), the products being ethylene, propylene, butadiene, benzene, toluene, xylenes and styrene.
GB1258807D 1968-03-21 1969-03-21 Expired GB1258807A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US71486968A 1968-03-21 1968-03-21

Publications (1)

Publication Number Publication Date
GB1258807A true GB1258807A (en) 1971-12-30

Family

ID=24871781

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1258807D Expired GB1258807A (en) 1968-03-21 1969-03-21

Country Status (6)

Country Link
US (1) US3542667A (en)
BE (1) BE730303A (en)
DE (1) DE1914603A1 (en)
FR (1) FR2004468A1 (en)
GB (1) GB1258807A (en)
NL (1) NL6904390A (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE792747A (en) * 1971-12-14 1973-03-30 Metallgesellschaft Ag HYDROGENATION PROCESS AND CATALYST, APPLICABLE IN PARTICULAR TO OBTAINING VERY PURE AROMATIC PRODUCTS
US4166025A (en) * 1973-08-22 1979-08-28 Bocharov Jury N Process for purifying aromatic hydrocarbons
US4053388A (en) * 1976-12-06 1977-10-11 Moore-Mccormack Energy, Inc. Process for preparing aromatics from naphtha
US4133842A (en) * 1977-10-25 1979-01-09 Uop Inc. Production and recovery of linear mono-olefins
US20080011644A1 (en) * 2006-07-13 2008-01-17 Dean Christopher F Ancillary cracking of heavy oils in conjuction with FCC unit operations
US20080011645A1 (en) * 2006-07-13 2008-01-17 Dean Christopher F Ancillary cracking of paraffinic naphtha in conjuction with FCC unit operations
KR101954472B1 (en) 2011-07-27 2019-03-05 사우디 아라비안 오일 컴퍼니 Fluidized catalytic cracking of paraffinic naphtha in a downflow reactor

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH371203A (en) * 1957-06-07 1963-08-15 Belge Produits Chimiques Sa Method and device for quenching hot gases
US3114696A (en) * 1958-10-03 1963-12-17 Socony Mobil Oil Co Inc Upgrading of naphthas
NL302682A (en) * 1962-12-31 1900-01-01

Also Published As

Publication number Publication date
FR2004468A1 (en) 1969-11-21
US3542667A (en) 1970-11-24
FR2004468B1 (en) 1974-03-15
NL6904390A (en) 1969-09-23
DE1914603A1 (en) 1969-10-09
BE730303A (en) 1969-09-22

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PLNP Patent lapsed through nonpayment of renewal fees