GB1347773A - Production of high octanerating unleaded gasoline - Google Patents
Production of high octanerating unleaded gasolineInfo
- Publication number
- GB1347773A GB1347773A GB3227971A GB3227971A GB1347773A GB 1347773 A GB1347773 A GB 1347773A GB 3227971 A GB3227971 A GB 3227971A GB 3227971 A GB3227971 A GB 3227971A GB 1347773 A GB1347773 A GB 1347773A
- Authority
- GB
- United Kingdom
- Prior art keywords
- line
- naphtha
- alkylation
- catalyst
- liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
- C10L1/06—Liquid carbonaceous fuels essentially based on blends of hydrocarbons for spark ignition
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G59/00—Treatment of naphtha by two or more reforming processes only or by at least one reforming process and at least one process which does not substantially change the boiling range of the naphtha
- C10G59/02—Treatment of naphtha by two or more reforming processes only or by at least one reforming process and at least one process which does not substantially change the boiling range of the naphtha plural serial stages only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G61/00—Treatment of naphtha by at least one reforming process and at least one process of refining in the absence of hydrogen
- C10G61/02—Treatment of naphtha by at least one reforming process and at least one process of refining in the absence of hydrogen plural serial stages only
- C10G61/06—Treatment of naphtha by at least one reforming process and at least one process of refining in the absence of hydrogen plural serial stages only the refining step being a sorption process
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
1347773 Cracking and reforming naphtha UNIVERSAL OIL PRODUCTS CO 9 July 1971 [10 July 1970] 32279/71 Heading C5E Unleaded gasoline of high octane number is obtained by (a) catalytically hydro-cracking a feed heavier than gasoline, (b) separating the product into a first saturated vapour and a liquid of gasoline boiling range, (c) reforming this liquid under conditions such that at least 80 mole per cent of naphthenes, but no more than 40 mole per cent of alkanes is converted to aromatics, (d) separating the reformate into an aromatic stream, a saturated liquid stream and a second saturated vapour, (e) cracking this saturated liquid, thermally or catalytically, to obtain a cracked gasoline and an unsaturated vapour, (f) alkylating part or all of this unsaturated vapour with part or all of the saturated vapours from steps (b) and (d), and (g) combining the aromatic stream, the cracked gasoline and the alkylate. As shown, kerosene, atmospheric gas oil and vacuum gas oil in line 1 are hydrocracked at 2 in two stages. In the first stage, the catalyst is of nickel and molybdenum on an amorphous alumina-silica carrier, and serves also to remove nitrogen and sulphur from the feed as ammonia and H 2 S. The product is cooled by heat-exchange before passing to the next stage, where the catalyst is of nickel on faujasite. The product is cooled by heat-exchange and separated into vapour and liquid. The vapour is rich in hydrogen and may be freed of H 2 S and light hydrocarbons and then recycled. The liquid is fractionated, butanes and lighter being taken off by line 7 and heavy naphtha (heptanes to 204 C.) by line 3; heavier material is recycled to the second hydrocracking step, pentanes and hexanes may go with the heavy naphtha (3) or may go directly to the pool 13. The naphtha in line 3, and straight-run naphtha from line 4 are reformed at 5 in the presence of hydrogen over a catalyst of platinum, germanium and chlorine on alumina. The reformate is separated into a hydrogen stream, which is recycled, a light hydrocarbon stream (up to butane) in line 6 and a reformed naphtha in line 9. This is extracted countercurrently with sulpholane at 10 to give a paraffinic raffinate in line 11 and an aromatic extract which is separated from the solvent and goes by line 12 to the pool 13. The raffinate 11 and a light naphtha (pentanes and hexanes) are cracked at 14 using a fluid catalyst of faujasite and alumina in a silica matrix, and without liquid recycle. The product is separated into cracked gasoline, which goes by line 16 to the pool 13, and an unsaturated gas in line 15. The saturated gases in lines 6 and 7 are fractionated at 8 to obtain propane (25), iso-butane (22) and normal butane (21). The propane may be used as LPG, dehydrogenated to propene or go to alkylation (24); the normal butane may be isomerized at 23, together with butane recycled from the alkylation, over a catalyst of alumina, aluminium chloride and platinum in a fixed bed, and then go to alkylation; alternatively it may go directly, like the isobutane, to alkylation. The unsaturated gas in line 15 is fractionated at 26 to give propene (26) which may be used to make isopropyl alcohol, isopropyl-benzene, tetramer, or other chemicals, or may go, like the butenes in line 19, to alkylation. The alkylation 24 is over a HF catalyst; unreacted material may be recycled, the alkylate goes by line 17 to the pool 13. The middle distillates 1, straight-run naphtha 4 and light naphtha going to the cracking zone 14 may all be obtained by fractionation of the same crude.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US5371970A | 1970-07-10 | 1970-07-10 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1347773A true GB1347773A (en) | 1974-02-27 |
Family
ID=21986082
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3227971A Expired GB1347773A (en) | 1970-07-10 | 1971-07-09 | Production of high octanerating unleaded gasoline |
Country Status (12)
Country | Link |
---|---|
US (1) | US3650943A (en) |
JP (1) | JPS5115524B1 (en) |
AR (1) | AR216412A1 (en) |
CA (1) | CA955551A (en) |
DE (1) | DE2134155B2 (en) |
FI (1) | FI53585C (en) |
FR (1) | FR2098298B1 (en) |
GB (1) | GB1347773A (en) |
NO (1) | NO129206B (en) |
SE (1) | SE364975B (en) |
SU (1) | SU510150A3 (en) |
ZA (1) | ZA714411B (en) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3931352A (en) * | 1974-07-11 | 1976-01-06 | Universal Oil Products Company | HF acid treating the paraffin feed stream to an integrated paraffin isomerization-alkylation process |
US4341911A (en) * | 1980-12-29 | 1982-07-27 | Uop Inc. | Hydrocarbon conversion process for the production of gasoline |
US4594144A (en) * | 1985-06-14 | 1986-06-10 | Uop Inc. | Process for making high octane gasoline |
US4853104A (en) * | 1988-04-20 | 1989-08-01 | Mobil Oil Corporation | Process for catalytic conversion of lube oil bas stocks |
US5414172A (en) * | 1993-03-08 | 1995-05-09 | Mobil Oil Corporation | Naphtha upgrading |
US20120277500A1 (en) * | 2011-04-29 | 2012-11-01 | Uop Llc | High Temperature Platforming Process |
US10160922B2 (en) * | 2015-11-23 | 2018-12-25 | Uop Llc | Processes and apparatuses for production of olefins |
US10899976B2 (en) * | 2019-03-28 | 2021-01-26 | Uop Llc | Integrated process for maximizing recovery of liquid petroleum gas |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1327010A (en) * | 1960-03-30 | 1963-05-17 | Socony Mobil Oil Co | Improvements in hydrocarbon treatments |
US3409540A (en) * | 1966-12-22 | 1968-11-05 | Chevron Res | Combination catalytic hydrocracking, pyrolytic cracking and catalytic reforming process for converting a wide boiling range crude hydrocarbon feedstock into various valuable products |
US3714023A (en) * | 1969-12-17 | 1973-01-30 | Universal Oil Prod Co | High octane gasoline production |
-
1970
- 1970-07-10 US US53719A patent/US3650943A/en not_active Expired - Lifetime
-
1971
- 1971-07-05 ZA ZA714411A patent/ZA714411B/en unknown
- 1971-07-06 FI FI1901/71A patent/FI53585C/en active
- 1971-07-07 FR FR7124796A patent/FR2098298B1/fr not_active Expired
- 1971-07-08 DE DE2134155A patent/DE2134155B2/en active Granted
- 1971-07-08 CA CA117,756A patent/CA955551A/en not_active Expired
- 1971-07-09 SU SU1681847A patent/SU510150A3/en active
- 1971-07-09 SE SE08934/71A patent/SE364975B/xx unknown
- 1971-07-09 NO NO02635/71A patent/NO129206B/no unknown
- 1971-07-09 GB GB3227971A patent/GB1347773A/en not_active Expired
- 1971-07-10 JP JP46050747A patent/JPS5115524B1/ja active Pending
- 1971-07-12 AR AR236723A patent/AR216412A1/en active
Also Published As
Publication number | Publication date |
---|---|
FI53585B (en) | 1978-02-28 |
FR2098298A1 (en) | 1972-03-10 |
SU510150A3 (en) | 1976-04-05 |
DE2134155A1 (en) | 1972-01-13 |
US3650943A (en) | 1972-03-21 |
DE2134155C3 (en) | 1974-05-22 |
FR2098298B1 (en) | 1974-09-06 |
DE2134155B2 (en) | 1973-10-11 |
FI53585C (en) | 1978-06-12 |
JPS5115524B1 (en) | 1976-05-18 |
NO129206B (en) | 1974-03-11 |
AR216412A1 (en) | 1979-12-28 |
ZA714411B (en) | 1972-04-26 |
CA955551A (en) | 1974-10-01 |
SE364975B (en) | 1974-03-11 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PCNP | Patent ceased through non-payment of renewal fee |