GB1242229A - Manufacture of polypivalolactone fibres - Google Patents
Manufacture of polypivalolactone fibresInfo
- Publication number
- GB1242229A GB1242229A GB3656668A GB3656668A GB1242229A GB 1242229 A GB1242229 A GB 1242229A GB 3656668 A GB3656668 A GB 3656668A GB 3656668 A GB3656668 A GB 3656668A GB 1242229 A GB1242229 A GB 1242229A
- Authority
- GB
- United Kingdom
- Prior art keywords
- treatment
- heat
- elongation
- polypivalolactone
- room temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
- D01F6/625—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters derived from hydroxy-carboxylic acids, e.g. lactones
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
Abstract
1,242,229. Polypivalolactone fibres. KANEGAFUCHI BOSEKI K.K. 31 July, 1968 [31 July, 1967], No. 36566/68. Heading B5B A polypivalolactone fibre having an intrinsic viscosity # f of at least 1À0 and an elongation at break of at least 200% and enhanced heatsettability is made by melt-spinning a polymer consisting substantially of polypivalolactone having an intrinsic viscosity # p of at least 1À1 at an extrusion temperature from 240‹ to 310‹ C. through an orifice of a spinneret, and applying to the extruded polymer, while the latter is still in the molten or plasticized state, a high draw-down such that the deformation ratio A takes a value which satisfies the following two equations: to make the degree of orientation R of the resulting undrawn filament at least 0À87. Intrinsic viscosity is determined at 30‹ C. in a solvent consisting of a 6 : 4 by weight mixture of phenol and orthochlorophenol. A copolymer made by copolymerizing pivalolactone with up to 25 mole per cent of another lactone, e.g. #-propiolactone or α,α-diethyl propiolactone may be used. The undrawn filament may be elasticized either by heat-treatment or by swelling treatment while avoiding substantial drawing of the undrawn filament until it has a degree of orientation R of at least 0À9, a degree of crystallinity of at least 55%, a long period D of at least 80 Š and an average length L a of the amorphous part of at least 40 Š and a structure coefficient of less than 1À70. The filament may, however, be drawn up to 1À5 times its original length in the take-up step or in the heattreatment step. Preferably, heat-treatment is effected for a sufficient period of time for the resulting filament to retain a tensile strength of at least 15 g/d, a tensile recovery of at least 96% at 5% elongation at room temperature, at least 85% at 50% elongation at room temperature, of at least 90% at 5% elongation at 120‹ C., and of at least 80% at 50% elongation at 120‹ C., a work recovery at 50% elongation of at least 40% at room temperature and at least 35% at 120‹ C. and a fatigue resistivity enough to withstand at least ten 50% elongation-relaxation cycles at 120‹ C. Such heat-treatment may consist of steam heat-treatment or wet heat-treatment at 100‹ to 150‹ C., especially 120‹ to 150‹ C. Alternatively, such heat-treatment may consist of a dry heat-treatment at 175‹ to 210‹ C. for a length of time in the range satisfying the two equations: # # exp (16À2828 - 0À089456#) and # # exp (0 002003#<SP>2</SP> - 0 8662# + 95À1964) where # represents the duration of the heat treatment in minutes and # represents the temperature of the heat treatment. Swelling treatment preferably utilizes a swelling bath prepared by dissolving or dispersing at least one organic compound active to said polypivalolactone and comprising phenol, its derivatives, chlorinated hydrocarbons, e.g. monochlorobenzene, dichlorobenzene, trichlorobenzene and tetrachlorobenzene halogenated fatty acids, acid amides, e.g. dimethylformamide and dimethylacetamide, dimethyl sulphoxide or nitrobenzene in at least one liquid medium inert to said polypivalolactone and comprising water, alcohol glycerine or acetone; in a concentration suitably of at least 1À0% by weight. A 75-85% by weight solution of phenol, a 90-95% by weight solution of metacresol, and a 10-30 g/l. solution of chlorophenol, all used at room temperature, are especially mentioned. Alternatively, swelling treatment may utilize an aqueous solution of at least one inorganic compound active to said polypivalolaotone and selected from chlorides of the metals of Group II of the Periodic Table, thiocyanates and inorganic acids. Those specified include zinc chloride, calcium chloride and magnesium chloride; calcium, potassium and ammonium thiocyanates; and sulphuric, hydrochloric and nitric acids. Fibres so made may show a knot strength not smaller than their tensile strength, and intrinsic viscosities of 1 to 5, especially 1À3 to 3À5.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4919967 | 1967-07-31 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1242229A true GB1242229A (en) | 1971-08-11 |
Family
ID=12824315
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3656668A Expired GB1242229A (en) | 1967-07-31 | 1968-07-31 | Manufacture of polypivalolactone fibres |
Country Status (6)
Country | Link |
---|---|
BR (1) | BR6800894D0 (en) |
CH (2) | CH501738A (en) |
DE (1) | DE1760989A1 (en) |
FR (1) | FR1575288A (en) |
GB (1) | GB1242229A (en) |
NL (1) | NL139568B (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2015063784A (en) * | 2013-08-30 | 2015-04-09 | トヨタ紡織株式会社 | Method for producing woven fabric for molding, fiber molded article and composite article |
-
1968
- 1968-07-24 BR BR20089468A patent/BR6800894D0/en unknown
- 1968-07-30 NL NL6810795A patent/NL139568B/en unknown
- 1968-07-30 DE DE19681760989 patent/DE1760989A1/en active Pending
- 1968-07-31 CH CH1146968A patent/CH501738A/en not_active IP Right Cessation
- 1968-07-31 FR FR1575288D patent/FR1575288A/fr not_active Expired
- 1968-07-31 GB GB3656668A patent/GB1242229A/en not_active Expired
- 1968-07-31 CH CH1146968D patent/CH1146968A4/xx unknown
Also Published As
Publication number | Publication date |
---|---|
DE1760989A1 (en) | 1972-03-09 |
CH1146968A4 (en) | 1970-08-31 |
NL6810795A (en) | 1969-02-04 |
NL139568B (en) | 1973-08-15 |
BR6800894D0 (en) | 1973-04-12 |
CH501738A (en) | 1970-08-31 |
FR1575288A (en) | 1969-07-18 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0146084B2 (en) | Ultra-high-tenacity polyvinyl alcohol fiber and process for producing same | |
US5208104A (en) | High-tenacity water-soluble polyvinyl alcohol fiber and process for producing the same | |
KR900702096A (en) | Stretched polyethylene terephthalate yarn manufacturing process and stretched polyethylene terephthalate multifilament yarn manufactured therefrom | |
DE2404962B2 (en) | METHOD OF MANUFACTURING CARBON FIBERS | |
GB1193170A (en) | Manufacture of Industrial Acrylic Fibers | |
US4002426A (en) | Production of stabilized non-burning acrylic fibers and films | |
US5133916A (en) | Polyvinyl alcohol fiber having excellent resistance to hot water and process for producing the same | |
GB1242229A (en) | Manufacture of polypivalolactone fibres | |
JPH0611927B2 (en) | High-strength, high-modulus polyvinyl alcohol fiber and method for producing the same | |
DE1256838B (en) | Process for producing threads by wet spinning a polyvinylidene fluoride solution | |
CH646733A5 (en) | SPANDEX FIBER WITH INCREASED CHLORINE RESISTANCE AND METHOD FOR THE PRODUCTION THEREOF. | |
GB1174311A (en) | Polypivalolactone Fibres and a method for their manufacture | |
KR880001854A (en) | High-strength high modulus polyester fiber and its manufacturing method | |
US5658663A (en) | Vinylidene fluoride resin fiber and process for producing the same | |
DE2657144C2 (en) | Process for making hydrophilic fibers | |
DE1286684B (en) | Process for the production of threads, fibers or films by wet or dry spinning of an acrylonitrile polymer mixture | |
US3767755A (en) | Process for producing brilliant acrylic fibers of a noncircular crosssection | |
JPS6028926B2 (en) | Method for manufacturing fiber from cellulose derivative liquid crystal | |
US5091254A (en) | Polyvinyl alcohol monofilament yarns and process for producing the same | |
JPS61119710A (en) | Production of acrylic fiber having high tenacity and modules | |
US3238283A (en) | Methods of producing shaped products of polyvinyl alcohol | |
JP2776003B2 (en) | Method for producing polyester fiber | |
GB1196599A (en) | Polyacrylonitrile and carbon fibre production | |
JP2888496B2 (en) | Method for producing high modulus polyvinyl alcohol fiber | |
US5264173A (en) | Polyvinyl alcohol monofilament yarns and process for producing the same |