GB1240843A - Production of olefin oxides and isobutyric acid - Google Patents

Production of olefin oxides and isobutyric acid

Info

Publication number
GB1240843A
GB1240843A GB5932268A GB5932268A GB1240843A GB 1240843 A GB1240843 A GB 1240843A GB 5932268 A GB5932268 A GB 5932268A GB 5932268 A GB5932268 A GB 5932268A GB 1240843 A GB1240843 A GB 1240843A
Authority
GB
United Kingdom
Prior art keywords
production
isobutyric acid
olefin oxides
isobutyraldehyde
dec
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5932268A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Badische Anilin and Sodafabrik AG filed Critical Badische Anilin and Sodafabrik AG
Publication of GB1240843A publication Critical patent/GB1240843A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1,240,843. Production of olefin oxides and isobutyric acid. BADISCHE ANILIN- & SODA-FABRIK A.G. 13 Dec., 1968 [14 Dec., 1967], No. 59322/68. Heading C2C. A process for the production of olefin oxides and isobutyric acid comprises reacting an olefinically unsaturated compound having at least three carbon atoms in the carbon chain jointly with isobutyraldehyde in the liquid phase with molecular oxygen at a temperature of from -10‹ to + 45‹ C., the molar ratio of isobutyraldehyde to the olefinically unsaturated compound being in the range 1:1 to 1:100, and if desired, under superatmospheric pressure. The reaction may be carried out in the presence of an inert solvent and/or catalyst, e.g. an oilsoluble salt of a fatty or naphthenic acid of a metal of subgroups 5 to 8 of the Periodic System. The production of propylene oxide, isobutene oxide and glycide each jointly with isobutyric acid is exemplified. Starting materials mentioned include cyclohexene, cyclooctene, butadiene, cyclooctadiene-(1,5), cyclododecatriene - (1,5,9), decene-(l), allyl chloride and methyl crotonate.
GB5932268A 1967-12-14 1968-12-13 Production of olefin oxides and isobutyric acid Expired GB1240843A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE1643713 1967-12-14

Publications (1)

Publication Number Publication Date
GB1240843A true GB1240843A (en) 1971-07-28

Family

ID=5684368

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5932268A Expired GB1240843A (en) 1967-12-14 1968-12-13 Production of olefin oxides and isobutyric acid

Country Status (4)

Country Link
BE (1) BE725454A (en)
FR (1) FR1594466A (en)
GB (1) GB1240843A (en)
SE (1) SE349027B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2848868A1 (en) * 1977-11-10 1979-05-17 Halcon Res & Dev PROCESS FOR THE SIMULTANEOUS OXIDATION OF OLEFINS AND BETA SUBSTITUTED SATURATED ALDEHYDE
US5367087A (en) * 1991-10-30 1994-11-22 Sumitomo Chemical Company, Limited Process for producing epoxide

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2848868A1 (en) * 1977-11-10 1979-05-17 Halcon Res & Dev PROCESS FOR THE SIMULTANEOUS OXIDATION OF OLEFINS AND BETA SUBSTITUTED SATURATED ALDEHYDE
US5367087A (en) * 1991-10-30 1994-11-22 Sumitomo Chemical Company, Limited Process for producing epoxide
US5466838A (en) * 1991-10-30 1995-11-14 Sumitomo Chemical Company, Limited Process for producing epoxide

Also Published As

Publication number Publication date
FR1594466A (en) 1970-06-01
BE725454A (en) 1969-06-13
SE349027B (en) 1972-09-18

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