GB1236622A - Sulfur dehydrogenation of organic compounds - Google Patents
Sulfur dehydrogenation of organic compoundsInfo
- Publication number
- GB1236622A GB1236622A GB50682/68A GB5068268A GB1236622A GB 1236622 A GB1236622 A GB 1236622A GB 50682/68 A GB50682/68 A GB 50682/68A GB 5068268 A GB5068268 A GB 5068268A GB 1236622 A GB1236622 A GB 1236622A
- Authority
- GB
- United Kingdom
- Prior art keywords
- organic compounds
- dehydrogenation
- mole
- pyridine
- sulfur
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title abstract 2
- 238000006356 dehydrogenation reaction Methods 0.000 title abstract 2
- 150000002894 organic compounds Chemical class 0.000 title abstract 2
- 229910052717 sulfur Inorganic materials 0.000 title 1
- 239000011593 sulfur Substances 0.000 title 1
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 abstract 2
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 abstract 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract 2
- BHIWKHZACMWKOJ-UHFFFAOYSA-N methyl isobutyrate Chemical compound COC(=O)C(C)C BHIWKHZACMWKOJ-UHFFFAOYSA-N 0.000 abstract 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- NRGGMCIBEHEAIL-UHFFFAOYSA-N 2-ethylpyridine Chemical compound CCC1=CC=CC=N1 NRGGMCIBEHEAIL-UHFFFAOYSA-N 0.000 abstract 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 abstract 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Substances 0.000 abstract 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 1
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 abstract 1
- 229960003750 ethyl chloride Drugs 0.000 abstract 1
- 239000003701 inert diluent Substances 0.000 abstract 1
- WDAXFOBOLVPGLV-UHFFFAOYSA-N isobutyric acid ethyl ester Natural products CCOC(=O)C(C)C WDAXFOBOLVPGLV-UHFFFAOYSA-N 0.000 abstract 1
- 235000019260 propionic acid Nutrition 0.000 abstract 1
- FVSKHRXBFJPNKK-UHFFFAOYSA-N propionitrile Chemical compound CCC#N FVSKHRXBFJPNKK-UHFFFAOYSA-N 0.000 abstract 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
- C07C5/46—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with sulfur or a sulfur-containing compound as an acceptor
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
1,236,622. Dehydrogenation. ESSO RESEARCH & ENG. CO. 25 Oct., 1968 [1 Nov., 1967], No. 50682/68. Heading C2C. [Also in Division C5] C 2-20 organic compounds containing at least one group are dehydrogenated in the vapour phase at a temperature of at least 800 F. by reaction with at least 0À1 mole of sulphur (stated to be in the form S 2 ) per mole of feed and in the presence of an inert diluent, e.g. He, N, CO, CO 2 , H 2 S, steam and methane. A catalyst may be present, many suitable ones being listed. Particular reactions envisaged include the following: propionaldehyde to acrolein; ethylchloride to vinyl chloride; propionitrile to acrylonitrile; methyl isobutyrate to methyl methacrylate; propionic acid to acrylic acid; ethyl pyridine to vinyl pyridine.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US67966767A | 1967-11-01 | 1967-11-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1236622A true GB1236622A (en) | 1971-06-23 |
Family
ID=24727845
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB50682/68A Expired GB1236622A (en) | 1967-11-01 | 1968-10-25 | Sulfur dehydrogenation of organic compounds |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3456026A (en) |
| JP (1) | JPS5026522B1 (en) |
| DE (1) | DE1806255A1 (en) |
| FR (1) | FR1590431A (en) |
| GB (1) | GB1236622A (en) |
| NL (1) | NL6815621A (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4393263A (en) * | 1980-01-29 | 1983-07-12 | El Paso Products Company | Tertiary-butylstyrene production |
| US4291183A (en) * | 1980-01-29 | 1981-09-22 | El Paso Products Company | Production of tertiary-butylstyrene |
| US4568783A (en) * | 1985-06-24 | 1986-02-04 | The Standard Oil Company | Indenes by catalytic dehydrogenation of indanes |
| US5341405A (en) * | 1991-06-11 | 1994-08-23 | Digital Equipment Corporation | Data recovery apparatus and methods |
| US5436383A (en) * | 1992-03-02 | 1995-07-25 | Institut Francais Du Petrole | Process for the dehydrogenation of aliphatic hydrocarbons saturated into olefinic hydrocarbons |
| US6258992B1 (en) * | 1999-09-17 | 2001-07-10 | Saudi Basic Industries Corporation | Gas phase catalytic oxidation of hydrocarbons to carboxylic acids and dehydrogenated products |
| EP1136467A1 (en) * | 2000-03-24 | 2001-09-26 | Aventis Animal Nutrition S.A. | Catalytic conversion of alkanes to alkenes |
| JP4559714B2 (en) * | 2003-06-19 | 2010-10-13 | 独立行政法人科学技術振興機構 | Alkene production method, hydrogen sulfide production method, alkane dehydrogenation method, and catalyst |
| CN103861619A (en) * | 2012-12-11 | 2014-06-18 | 江苏省海洋石化股份有限公司 | Alkane dehydrogenation sulfide catalyst and alkane dehydrogenation method |
| EP3668824A1 (en) * | 2017-08-14 | 2020-06-24 | SABIC Global Technologies B.V. | Methods of producing 1,3-butadiene from ethylene and sulfur |
| CN114749191B (en) * | 2022-03-24 | 2023-06-30 | 淮阴工学院 | Ni/P-attapulgite clay catalyst and preparation method and application thereof |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2197872A (en) * | 1938-09-23 | 1940-04-23 | Universal Oil Prod Co | Treatment of hydrocarbons |
| US2392289A (en) * | 1943-09-08 | 1946-01-01 | Monsanto Chemicals | Process for producing styrene |
| US3247278A (en) * | 1963-03-21 | 1966-04-19 | Socony Mobil Oil Co Inc | Catalytic reactions of sulfur with organic compounds |
| US3387054A (en) * | 1965-06-07 | 1968-06-04 | Seymour C. Schuman | Conversion of c4, c5 hydrocarbons with elemental sulfur and metal sulfide catalyst |
| US3344201A (en) * | 1965-06-07 | 1967-09-26 | Seymour C Schuman | Production of styrene |
| US3344203A (en) * | 1965-06-07 | 1967-09-26 | Seymour C Schuman | Production of methyl acetylene and propylene |
| US3373213A (en) * | 1965-07-29 | 1968-03-12 | Exxon Research Engineering Co | Process for dehydrogenating hydrocarbons |
-
1967
- 1967-11-01 US US679667A patent/US3456026A/en not_active Expired - Lifetime
-
1968
- 1968-10-25 GB GB50682/68A patent/GB1236622A/en not_active Expired
- 1968-10-31 FR FR1590431D patent/FR1590431A/fr not_active Expired
- 1968-10-31 DE DE19681806255 patent/DE1806255A1/en active Pending
- 1968-11-01 JP JP43079851A patent/JPS5026522B1/ja active Pending
- 1968-11-01 NL NL6815621A patent/NL6815621A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE1806255A1 (en) | 1969-06-12 |
| FR1590431A (en) | 1970-04-13 |
| JPS5026522B1 (en) | 1975-09-01 |
| US3456026A (en) | 1969-07-15 |
| NL6815621A (en) | 1969-05-05 |
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