GB1236421A - Photochromic recording member - Google Patents
Photochromic recording memberInfo
- Publication number
- GB1236421A GB1236421A GB7525/68A GB752568A GB1236421A GB 1236421 A GB1236421 A GB 1236421A GB 7525/68 A GB7525/68 A GB 7525/68A GB 752568 A GB752568 A GB 752568A GB 1236421 A GB1236421 A GB 1236421A
- Authority
- GB
- United Kingdom
- Prior art keywords
- photochromic
- compounds
- materials
- photo
- nitro
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000463 material Substances 0.000 abstract 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 9
- 235000019441 ethanol Nutrition 0.000 abstract 6
- -1 polycyclic aromatic compounds Chemical class 0.000 abstract 6
- 239000002585 base Substances 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 4
- 239000005995 Aluminium silicate Substances 0.000 abstract 3
- 235000012211 aluminium silicate Nutrition 0.000 abstract 3
- 239000011521 glass Substances 0.000 abstract 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 abstract 3
- 239000007787 solid Substances 0.000 abstract 3
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 abstract 2
- 239000001856 Ethyl cellulose Substances 0.000 abstract 2
- 239000002841 Lewis acid Substances 0.000 abstract 2
- 239000002879 Lewis base Substances 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- DZBUGLKDJFMEHC-UHFFFAOYSA-N acridine Chemical compound C1=CC=CC2=CC3=CC=CC=C3N=C21 DZBUGLKDJFMEHC-UHFFFAOYSA-N 0.000 abstract 2
- 239000011248 coating agent Substances 0.000 abstract 2
- 238000000576 coating method Methods 0.000 abstract 2
- 229920001249 ethyl cellulose Polymers 0.000 abstract 2
- 235000019325 ethyl cellulose Nutrition 0.000 abstract 2
- 150000007517 lewis acids Chemical class 0.000 abstract 2
- 150000007527 lewis bases Chemical class 0.000 abstract 2
- 239000003381 stabilizer Substances 0.000 abstract 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 abstract 1
- BTJIUGUIPKRLHP-UHFFFAOYSA-N 4-nitrophenol Chemical compound OC1=CC=C([N+]([O-])=O)C=C1 BTJIUGUIPKRLHP-UHFFFAOYSA-N 0.000 abstract 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000004793 Polystyrene Substances 0.000 abstract 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 150000004982 aromatic amines Chemical class 0.000 abstract 1
- 239000000440 bentonite Substances 0.000 abstract 1
- 229910000278 bentonite Inorganic materials 0.000 abstract 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 abstract 1
- 238000004061 bleaching Methods 0.000 abstract 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 229910001410 inorganic ion Inorganic materials 0.000 abstract 1
- 150000008040 ionic compounds Chemical class 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- FDZZZRQASAIRJF-UHFFFAOYSA-M malachite green Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](C)C)C=C1 FDZZZRQASAIRJF-UHFFFAOYSA-M 0.000 abstract 1
- 229940107698 malachite green Drugs 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- 150000007530 organic bases Chemical class 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- 229920002223 polystyrene Polymers 0.000 abstract 1
- 150000004053 quinones Chemical class 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 230000006641 stabilisation Effects 0.000 abstract 1
- 238000011105 stabilization Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- PCCVSPMFGIFTHU-UHFFFAOYSA-N tetracyanoquinodimethane Chemical compound N#CC(C#N)=C1C=CC(=C(C#N)C#N)C=C1 PCCVSPMFGIFTHU-UHFFFAOYSA-N 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/494—Silver salt compositions other than silver halide emulsions; Photothermographic systems ; Thermographic systems using noble metal compounds
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/72—Photosensitive compositions not covered by the groups G03C1/005 - G03C1/705
- G03C1/73—Photosensitive compositions not covered by the groups G03C1/005 - G03C1/705 containing organic compounds
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
- G03C5/26—Processes using silver-salt-containing photosensitive materials or agents therefor
- G03C5/29—Development processes or agents therefor
- G03C5/305—Additives other than developers
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C8/00—Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
- G03C8/02—Photosensitive materials characterised by the image-forming section
- G03C8/04—Photosensitive materials characterised by the image-forming section the substances transferred by diffusion consisting of inorganic or organo-metallic compounds derived from photosensitive noble metals
- G03C8/06—Silver salt diffusion transfer
Abstract
1,236,421. Photochromic materials and uses thereof. CANON K.K. 15 Feb., 1968 [20 Feb., 1967; 31 May, 1967; 19 June, 1967; 2 Aug., 1967; 16 Aug., 1967], No. 7525/68. Heading C4S. [Also in Division G2] A photochromic recordingmember comprises a base and photochromic coating comprising a wholly organic monomeric photochromic material, defined as including salts of organic bases involving inorganic ions selected from photoion dissociating, photo-radical dissociating, photo - hydrogen transmitting, photo - steric structure changing, and photo-oxidizing or - reducing materials, and a stabilizer comprising one or more of (a) an organic monomeric compound which is an electron donor selected from polycyclic aromatic compounds, aliphatic amines and aromatic amines, or a proton donor selected from phenols, alcohols and carboxylic acids, or an electron acceptor selected from quinones and nitroaromatic compounds or a proton acceptor selected from heterocyclic nitrogen containing aromatic compounds and azoaromatic compounds, the layer having been formed by coating the base with a solution of the photochromic material in a solvent of the compound (a); (b) a solid (or gel) material selected from acids (including Lewis acids), bases (including Lewis bases), and crystalline ionic compounds; (c) a solid (or gel) material which has been treated with an acid or base to cause a surface portion in contact with the photochromic material to behave as a Lewis acid or base. The solid (or gel) material (b) or (c) may have been coated on the surface and subsequently a solution or dispersion of the photochromic material added to form a heterogeneous rather than homogeneous system, the latter normally employing liquid matrices although film forming or adhesive substances may be matrices in both cases. A large number of photochromic materials and stabilizers are disclosed, the former of types such as carbinols, cyanides, sulphites, spiropyrans, anils, aromatic nitro compounds, bianthrones for instance. Specific example combinations include (a) malachite green cyanide, tetra cyanoquinodimethane, ethyl cellulose and alcohol, on glass, (b) salicylidene anil, acridine and resin; (c) kaolin, ethyl alcohol or acidic terra alba with ethyl alcohol or ethyl cellulose, dioxane, kaolin on art paper and bentonite, ethyl alcohol on Al with 6<SP>1</SP> - nitro - 1,3,3 - trimethylindolinobenzopyrylspiran, (d) kaolin, ethyl alcohol and 6<SP>1</SP>-nitro- 1,3,3-trimethylindolinobenzopyrylspiran on art paper, Al or glass, (e) 6<SP>1</SP>-nitro-1,3,3-trimethyl indolinobenzopyrylspiran, p-nitrophenol, polystyrene and xylene on glass. Stabilization for 60 hours, colorization and bleaching by U.V. and visible light is disclosed. Reference is made to a projection system as in Specification 1,236,424. Applications exemplified include, photography, electrophotography, calculation, translation, communication, documentation, information treating systems for recording, accumulating, modifying-and erasing information layout, e.g. phototyping materials, master sheets for printing, materials for telecommunication machines and computers.
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1107067 | 1967-02-20 | ||
| JP3507567A JPS5323699B1 (en) | 1967-05-31 | 1967-05-31 | |
| JP3920367 | 1967-06-19 | ||
| JP4928067 | 1967-08-02 | ||
| JP5285967 | 1967-08-16 | ||
| US67121867A | 1967-09-28 | 1967-09-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1236421A true GB1236421A (en) | 1971-06-23 |
Family
ID=27548311
Family Applications (5)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB32492/70A Expired GB1236423A (en) | 1967-02-20 | 1968-02-15 | Colour image recording member |
| GB7525/68A Expired GB1236421A (en) | 1967-02-20 | 1968-02-15 | Photochromic recording member |
| GB32493/70A Expired GB1236424A (en) | 1967-02-20 | 1968-02-15 | Photochromic projection system |
| GB32491/70A Expired GB1236422A (en) | 1967-02-20 | 1968-02-15 | Method of rendering photochromic images permanent |
| GB45959/68A Expired GB1183907A (en) | 1967-02-20 | 1968-09-27 | Photographic Silver Materials and Processes |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB32492/70A Expired GB1236423A (en) | 1967-02-20 | 1968-02-15 | Colour image recording member |
Family Applications After (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB32493/70A Expired GB1236424A (en) | 1967-02-20 | 1968-02-15 | Photochromic projection system |
| GB32491/70A Expired GB1236422A (en) | 1967-02-20 | 1968-02-15 | Method of rendering photochromic images permanent |
| GB45959/68A Expired GB1183907A (en) | 1967-02-20 | 1968-09-27 | Photographic Silver Materials and Processes |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3563740A (en) |
| BE (1) | BE721563A (en) |
| DE (5) | DE1797589A1 (en) |
| FR (1) | FR1602526A (en) |
| GB (5) | GB1236423A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102008049848A1 (en) * | 2008-10-01 | 2010-04-08 | Tesa Se | Multigrade indicator |
| CN108689978A (en) * | 2018-05-14 | 2018-10-23 | 南京信息工程大学 | 2- imido grpups -3-(4- nitrobenzophenones)-6-[4-(4- nitrophenylazos)Phenyl benzopyrane |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9610769D0 (en) * | 1996-05-23 | 1996-07-31 | Sls Wales Ltd | Image production |
| WO2001004702A1 (en) * | 1999-07-08 | 2001-01-18 | Kromotek Ltd | Dry photographic printing process |
| US7570423B2 (en) | 2007-01-25 | 2009-08-04 | Hewlett-Packard Development Company, L.P. | Projection screen |
-
1967
- 1967-09-28 US US671218A patent/US3563740A/en not_active Expired - Lifetime
-
1968
- 1968-02-15 GB GB32492/70A patent/GB1236423A/en not_active Expired
- 1968-02-15 GB GB7525/68A patent/GB1236421A/en not_active Expired
- 1968-02-15 GB GB32493/70A patent/GB1236424A/en not_active Expired
- 1968-02-15 GB GB32491/70A patent/GB1236422A/en not_active Expired
- 1968-02-20 DE DE19681797589 patent/DE1797589A1/en active Pending
- 1968-02-20 DE DE19681622263 patent/DE1622263A1/en active Pending
- 1968-02-20 DE DE19681797588 patent/DE1797588A1/en active Pending
- 1968-02-20 DE DE19681797590 patent/DE1797590A1/en active Pending
- 1968-09-19 FR FR1602526D patent/FR1602526A/fr not_active Expired
- 1968-09-24 DE DE19681797388 patent/DE1797388A1/en active Pending
- 1968-09-27 GB GB45959/68A patent/GB1183907A/en not_active Expired
- 1968-09-27 BE BE721563D patent/BE721563A/xx unknown
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102008049848A1 (en) * | 2008-10-01 | 2010-04-08 | Tesa Se | Multigrade indicator |
| CN108689978A (en) * | 2018-05-14 | 2018-10-23 | 南京信息工程大学 | 2- imido grpups -3-(4- nitrobenzophenones)-6-[4-(4- nitrophenylazos)Phenyl benzopyrane |
| CN108689978B (en) * | 2018-05-14 | 2021-11-12 | 南京信息工程大学 | 2-imino-3- (4-nitrophenyl) -6- [2- (4-nitrophenyl) azo ] benzopyran |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1797590A1 (en) | 1973-11-08 |
| US3563740A (en) | 1971-02-16 |
| DE1797388A1 (en) | 1970-12-23 |
| DE1622263A1 (en) | 1970-12-03 |
| GB1183907A (en) | 1970-03-11 |
| GB1236424A (en) | 1971-06-23 |
| BE721563A (en) | 1969-03-03 |
| FR1602526A (en) | 1970-12-21 |
| DE1797588A1 (en) | 1974-01-10 |
| GB1236422A (en) | 1971-06-23 |
| GB1236423A (en) | 1971-06-23 |
| DE1797589A1 (en) | 1973-11-08 |
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