GB1231273A - - Google Patents

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Publication number
GB1231273A
GB1231273A GB1231273DA GB1231273A GB 1231273 A GB1231273 A GB 1231273A GB 1231273D A GB1231273D A GB 1231273DA GB 1231273 A GB1231273 A GB 1231273A
Authority
GB
United Kingdom
Prior art keywords
activated
promoted
sulphide
precursor
oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Publication of GB1231273A publication Critical patent/GB1231273A/en
Expired legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00Aliphatic unsaturated hydrocarbons
    • C07C11/02Alkenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/23Rearrangement of carbon-to-carbon unsaturated bonds
    • C07C5/25Migration of carbon-to-carbon double bonds
    • C07C5/2506Catalytic processes
    • C07C5/2512Catalytic processes with metal oxides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • C07C6/06Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond at a cyclic carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
    • C07C7/148Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04Alumina
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08Silica
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24Chromium, molybdenum or tungsten
    • C07C2523/28Molybdenum
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24Chromium, molybdenum or tungsten
    • C07C2523/30Tungsten

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

1,231,273. Disproportionating olefins. PHILLIPS PETROLEUM CO. 2 April, 1968 [3 April, 1967], No. 52229/70. Divided out of 1,231,272. Heading C5E. In the catalytic disproportionation of olefins, the feed of one or more olefins is contacted with MgO at a temperature below which any substantial isomerization takes place, prior to contact with the disproportionation catalyst. The MgO is preferably activated prior to contact with the olefin by heating in an oxygencontaining gas stream at 500-1500‹ F. The disproportionation catalyst may be: (1) activated SiO 2 or thoria promoted with an oxide (or precursor thereof) of Mo, W or Re; or by a sulphide of W or Mo; (2) activated Al 2 O 3 promoted by an oxide (or precursor thereof) of Mo, W or Re; or by a sulphide of W or Mo; or by an alkali metal salt, alkaline earth metal salt, NH 4 <SP>+</SP> salt or Bi salt of phosphomolybdic acid; (3) activated phosphates of Al, Zr, Ca, Mg or Ti promoted by an oxide (or precursor thereof) of Mo, W or Re or by a sulphide of W or Mo or by magnesium tungstate or by beryllium phosphotungstate; or (4) activated SiO 2 , Al 2 O 3 , phosphates of Al, Zr, Ca, Mg or Ti promoted by hexacarbonyl of W or Mo. Examples describe the disproportion of pentene-1 and of a mixture of heptene-2 and heptene-3.
GB1231273D 1967-04-03 1968-04-02 Expired GB1231273A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US62763567A 1967-04-03 1967-04-03
US62766867A 1967-04-03 1967-04-03
US67849967A 1967-10-27 1967-10-27

Publications (1)

Publication Number Publication Date
GB1231273A true GB1231273A (en) 1971-05-12

Family

ID=27417424

Family Applications (4)

Application Number Title Priority Date Filing Date
GB1231273D Expired GB1231273A (en) 1967-04-03 1968-04-02
GB1231275D Expired GB1231275A (en) 1967-04-03 1968-04-02
GB1231274D Expired GB1231274A (en) 1967-04-03 1968-04-02
GB1231272D Expired GB1231272A (en) 1967-04-03 1968-04-02

Family Applications After (3)

Application Number Title Priority Date Filing Date
GB1231275D Expired GB1231275A (en) 1967-04-03 1968-04-02
GB1231274D Expired GB1231274A (en) 1967-04-03 1968-04-02
GB1231272D Expired GB1231272A (en) 1967-04-03 1968-04-02

Country Status (7)

Country Link
JP (1) JPS5516566B1 (en)
BE (1) BE713190A (en)
DE (1) DE1767117C3 (en)
ES (1) ES352051A1 (en)
FR (1) FR1560086A (en)
GB (4) GB1231273A (en)
NL (1) NL140830B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1357632A (en) * 1971-02-22 1974-06-26 Shell Int Research Process for the manufacture of higher olefins
US5986155A (en) * 1996-07-10 1999-11-16 The Lubrizol Corporation Catalytic process for making high reactivity alkylating agents and products resulting therefrom

Also Published As

Publication number Publication date
DE1767117C3 (en) 1975-02-20
JPS5516566B1 (en) 1980-05-02
FR1560086A (en) 1969-03-14
GB1231275A (en) 1971-05-12
NL6804601A (en) 1968-10-04
BE713190A (en) 1968-10-03
NL140830B (en) 1974-01-15
GB1231272A (en) 1971-05-12
DE1767117A1 (en) 1972-04-20
DE1767117B2 (en) 1974-07-04
GB1231274A (en) 1971-05-12
ES352051A1 (en) 1969-07-01

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Legal Events

Date Code Title Description
PS Patent sealed
PE20 Patent expired after termination of 20 years