GB1228810A - - Google Patents
Info
- Publication number
- GB1228810A GB1228810A GB1228810DA GB1228810A GB 1228810 A GB1228810 A GB 1228810A GB 1228810D A GB1228810D A GB 1228810DA GB 1228810 A GB1228810 A GB 1228810A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkyl
- cycloalkyl
- catalyst
- per cent
- halide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 abstract 3
- -1 Alkyl tin halides Chemical class 0.000 abstract 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 2
- 150000004820 halides Chemical class 0.000 abstract 2
- 150000002497 iodine compounds Chemical class 0.000 abstract 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 229910052740 iodine Inorganic materials 0.000 abstract 1
- 239000011630 iodine Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 125000000962 organic group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/2208—Compounds having tin linked only to carbon, hydrogen and/or halogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
1,228,810. Alkyl tin halides. NETHERLANDS APPLIED SCIENTIFIC RESEARCH. 16 July, 1968 [18 July, 1967], No. 33778/68. Heading C2J. Alkyl- or cycloalkyl-tin halides are formed by reacting metallic Sn with alkyl- or cycloalkylhalides or mixtures thereof, in the presence of at least one organo-antimony compound as catalyst. The main reaction product is R 2 SnX 2 . The catalyst is preferably used in an amount of 1-8 mol. per cent, based on the number of gram atoms of Sn present. Preferably the organic groups of the catalyst are the same as those in the alkyl- or cycloalkyl-halide. When the halide is a chloride or bromide, elementary iodine or an iodine compound may be added in an amount of 0À5-10 gram atoms per cent or mole per cent, based on the number of moles of chloride or bromide present. The iodine compound may be an alkyl- or cycloalkyl-iodide, or an alkyl tin iodide. Preferred reaction temperatures are 130-210 C.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL676709983A NL154742B (en) | 1967-07-18 | 1967-07-18 | PROCEDURE FOR PREPARING ALKYL OR CYCLOALKYL TIN HALOGENIDES. |
DE19681768914 DE1768914C (en) | 1967-07-18 | 1968-07-12 | Process for the preparation of alkyl or cycloalkyl tin halides |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1228810A true GB1228810A (en) | 1971-04-21 |
Family
ID=25755514
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1228810D Expired GB1228810A (en) | 1967-07-18 | 1968-07-16 |
Country Status (8)
Country | Link |
---|---|
US (1) | US3595892A (en) |
BE (1) | BE718175A (en) |
BR (1) | BR6800602D0 (en) |
CH (1) | CH501673A (en) |
FR (1) | FR1579116A (en) |
GB (1) | GB1228810A (en) |
NL (1) | NL154742B (en) |
SE (1) | SE354283B (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH581143A5 (en) * | 1973-08-16 | 1976-10-29 | Ciba Geigy Ag | |
EP1743898A1 (en) * | 2005-07-12 | 2007-01-17 | Arkema Vlissingen B.V. | Process for the preparation of monoalkyl tin trihalides and dialkyl tin dihalides |
EP4074717A1 (en) * | 2021-04-13 | 2022-10-19 | BNT Chemicals GmbH | Method for cleaving alkyl tin halides |
-
1967
- 1967-07-18 NL NL676709983A patent/NL154742B/en not_active IP Right Cessation
-
1968
- 1968-07-11 FR FR1579116D patent/FR1579116A/fr not_active Expired
- 1968-07-12 BR BR200602/68A patent/BR6800602D0/en unknown
- 1968-07-15 SE SE09703/68A patent/SE354283B/xx unknown
- 1968-07-15 US US744701A patent/US3595892A/en not_active Expired - Lifetime
- 1968-07-15 CH CH1053668A patent/CH501673A/en not_active IP Right Cessation
- 1968-07-16 GB GB1228810D patent/GB1228810A/en not_active Expired
- 1968-07-17 BE BE718175D patent/BE718175A/xx unknown
Also Published As
Publication number | Publication date |
---|---|
BR6800602D0 (en) | 1973-01-11 |
CH501673A (en) | 1971-01-15 |
FR1579116A (en) | 1969-08-22 |
NL154742B (en) | 1977-10-17 |
DE1768914A1 (en) | 1971-10-07 |
NL6709983A (en) | 1969-01-21 |
US3595892A (en) | 1971-07-27 |
BE718175A (en) | 1968-12-31 |
SE354283B (en) | 1973-03-05 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PCNP | Patent ceased through non-payment of renewal fee |