GB1222992A - Solutions containing noble metal compounds - Google Patents

Solutions containing noble metal compounds

Info

Publication number
GB1222992A
GB1222992A GB6333/68A GB633368A GB1222992A GB 1222992 A GB1222992 A GB 1222992A GB 6333/68 A GB6333/68 A GB 6333/68A GB 633368 A GB633368 A GB 633368A GB 1222992 A GB1222992 A GB 1222992A
Authority
GB
United Kingdom
Prior art keywords
methyl
ethylene glycol
dioxolane
ethylene
ethanol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB6333/68A
Inventor
William Gilbert Lloyd
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CB&I Technology Inc
Original Assignee
Lummus Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lummus Co filed Critical Lummus Co
Priority to GB6333/68A priority Critical patent/GB1222992A/en
Publication of GB1222992A publication Critical patent/GB1222992A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
    • C07D317/14—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D317/30—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/10—Chlorides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
    • B01J27/13—Platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0202—Alcohols or phenols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0205—Oxygen-containing compounds comprising carbonyl groups or oxygen-containing derivatives, e.g. acetals, ketals, cyclic peroxides
    • B01J31/0208—Ketones or ketals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0231—Halogen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2213—At least two complexing oxygen atoms present in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/24—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of esters of sulfuric acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/58—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by oxidation reactions introducing directly hydroxy groups on a =CH-group belonging to a six-membered aromatic ring with the aid of molecular oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/26—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D307/30—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/32—Oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
    • C07D317/14—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D317/16—Radicals substituted by halogen atoms or nitro radicals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/16—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • B01J31/30—Halides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

1,222,992. Oxidation reactions. LUMMUS CO. 8 Feb., 1968, No. 6333/68. Heading C2C. [Also in Division B1] Oxidation reactions are effected in solution in or in contact with a homogeneous solution comprising (a) a Group VIII noble metal compound, (b) a mono- or poly-hydric alcohol, (c) a promoter having an oxidation potential sufficient to oxidize the noble metal from a lower to a higher valence state and being an organic compound or a, Group I B or a different Group VIII metal compound, and (d) 0À1 to 12% by volume of water. Suitable organic promoters are benzoquinones, chloronil, vicinal diketones and substances oxidizable thereto and catechols. Molecular oxygen may or may not be present. Examples prepare (1) acetaldehyde diethyl acetal from ethylene in ethanolic solution, (2) 2-methyl-1,3-dioxolane and acetaldehyde from ethylene in ethylene glycol, (3) 2- methyl-1,3-dioxepane and 2-methyl-1,3-dioxe cane from ethylene in 1,4-butanediol and 1,5- pentanediol respectively, (4) octanones from octene-1 in n-propanol, (5) acetophenone and phenylacetaldehyde (mainly as acetals) from styrene in methanol, ethanol, n-propanol and n - butanol, (6) 2 - methyl - 2 - phenyl - 4- chloro - methyl - 1,3 - dioxolane, acetophenone and 2 - benzyl - 4 - chloromethyl - 1,3 - dioxolane from styrene in 3-chloropropanediol, (7) cyanoacetaldehyde dimethyl acetal from acrylonitrile in methanol, (8) 2-cyanomethyl-1,3- dioxolane from acrylonitrile in ethylene glycol, (9) 2-cyanomethyl-1,3-dioxane from acrylonitrile in 1,3-propanediol, (10), (11) and (13) cyclohexanone, 1,4-dioxaspiro(4,5)decano and 1,5-dioxaspiro(5,5)undecane from cyclohexene in ethanol, ethylene glycol and 1,3-propanediol, (12) propionaldehyde and n-propyl propionate from n-propanol, (14) pivalic aldehyde, pivalic aldehyde dineopentyl acetal (new compound) and neopentyl pivalate, (15) phenol from benzene in ethylene glycol, (16) methyl ethyl ketone from secondary butanol and cyclohexanone from cyclohexanol, (19) 3,3-diethoxyfuran from 2,5- dihydrofuran in ethanol, (20) 2-benzyl-1,3-dioxolane and acetophenone from styrene in ethylene glycol, (21) diethyl sulphate from SO 2 in ethanol and (22) ethylene carbonate from carbon monoxide in ethylene glycol. Reference has been directed by the Comptroller to Specification 1,123,907.
GB6333/68A 1968-02-08 1968-02-08 Solutions containing noble metal compounds Expired GB1222992A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB6333/68A GB1222992A (en) 1968-02-08 1968-02-08 Solutions containing noble metal compounds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB6333/68A GB1222992A (en) 1968-02-08 1968-02-08 Solutions containing noble metal compounds

Publications (1)

Publication Number Publication Date
GB1222992A true GB1222992A (en) 1971-02-17

Family

ID=9812588

Family Applications (1)

Application Number Title Priority Date Filing Date
GB6333/68A Expired GB1222992A (en) 1968-02-08 1968-02-08 Solutions containing noble metal compounds

Country Status (1)

Country Link
GB (1) GB1222992A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0645358A1 (en) * 1993-09-17 1995-03-29 Bayer Ag Method of selective catalytic oxidation of organic compounds
EP0885865A1 (en) * 1993-08-10 1998-12-23 Tosoh Corporation Process for producing phenols

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0885865A1 (en) * 1993-08-10 1998-12-23 Tosoh Corporation Process for producing phenols
EP0645358A1 (en) * 1993-09-17 1995-03-29 Bayer Ag Method of selective catalytic oxidation of organic compounds
US5504260A (en) * 1993-09-17 1996-04-02 Bayer Aktiengesellschaft Catalytic oxidation

Similar Documents

Publication Publication Date Title
Mijs et al. Organic syntheses by oxidation with metal compounds
US3953524A (en) Catalytic hydrogenation of alpha,beta-unsaturated aldehydes to alpha,beta-unsaturated alcohols
Ray et al. Gas phase oxidation of alkenes—Part II. The oxidation of 2-methylbutene-2 and 2, 3-dimethylbutene-2
GB1477391A (en) Catalytic process for polyhydric alcohols and derivatives
GB1186370A (en) Production of Aliphatic Ketones
Jeong et al. Preparations of bicycliclactols from allyl and/or homoallyl propargyl acetal-cobalt complexes and its application to the formal synthesis of (±) loganine
GB1222992A (en) Solutions containing noble metal compounds
GB1191113A (en) Production of Saturated Carbonyl Compounds
FI971268A0 (en) Process for the preparation of 1,3-alkanediols and 3-hydroxyaldehydes
GB923352A (en) Oxidation of cyclo-hexanones to epsilon caprolactones
Fétizon et al. Highly selective oxidations of diols by silver carbonate
GB1436467A (en) Dehydrocoupling aromatic and oleffinic compounds
GB1219281A (en) Improvements relating to catalysts
Tanaka et al. Facile synthesis of 3, 4-dihydro-4, 4-dimethyl-2H-pyran-2-one via palladium catalyzed terminal oxidation of 3, 3-dimethyl-4-pentenoates
JPS5473717A (en) Production of carboxylic ester
Coxon et al. Acetate participation in acyclic epoxide systems. Acid-catalyzed rearrangements of trans-and cis-1-acetoxy-3, 4-epoxypentanes,-4, 5-epoxyhexanes, and-5, 6-epoxyheptanes
ES334858A1 (en) Preparation of esters from olefins in the presence of an oxime
GOTO et al. The Characterization of Acutumine
FR2119600A5 (en) Polyoxymethylenedialkyl ether continuous prodn - from lower alcohols and formaldehyde forming cpds
GB1144223A (en) Oxidation catalysts and their preparation
GB1123907A (en) Production of oxygen-containing organic compounds
Parker et al. 14 C-tracer studies in the homogeneous rhodium-catalysed conversion of carbon monoxide and hydrogen into methanol and ethylene glycol
JPS5473716A (en) Production of carboxylic ester
GB1261458A (en) Catalysts for the preparation of carbonyl-containing compound
ATE23709T1 (en) PRODUCTION PROCESS OF ETHYL ACETATE BY HOMOLOGIZATION OF METHYL ACETATE.