GB1219713A - Bromoalkyl-(di)-thiolphosphoric acid esters - Google Patents
Bromoalkyl-(di)-thiolphosphoric acid estersInfo
- Publication number
- GB1219713A GB1219713A GB04383/69A GB1438369A GB1219713A GB 1219713 A GB1219713 A GB 1219713A GB 04383/69 A GB04383/69 A GB 04383/69A GB 1438369 A GB1438369 A GB 1438369A GB 1219713 A GB1219713 A GB 1219713A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkyl
- formula
- optionally substituted
- bromoalkyl
- acid esters
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002253 acid Substances 0.000 title abstract 2
- 150000002148 esters Chemical class 0.000 title abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 1
- KNIUHBNRWZGIQQ-UHFFFAOYSA-N 7-diethoxyphosphinothioyloxy-4-methylchromen-2-one Chemical compound CC1=CC(=O)OC2=CC(OP(=S)(OCC)OCC)=CC=C21 KNIUHBNRWZGIQQ-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Chemical group 0.000 abstract 1
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000004414 alkyl thio group Chemical group 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 abstract 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 abstract 1
- -1 diester chloride Chemical class 0.000 abstract 1
- 150000005690 diesters Chemical class 0.000 abstract 1
- 125000001188 haloalkyl group Chemical group 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 238000002955 isolation Methods 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 230000000361 pesticidal effect Effects 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/18—Esters of thiophosphoric acids with hydroxyaryl compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/20—Esters of thiophosphoric acids containing P-halide groups
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
1,219,713. Bromoalkyl-thiolphosphoric acid esters. FARBENFABRIKEN BAYER A.G. 19 March, 1969 [25 March, 1968], No. 14383/69. Heading C2C. [Also in Division A5] Compounds of the formula where R 1 to R 6 are hydrogen or C 1-2 alkyl or haloalkyl, R 7 is C 1-6 straight chain or branched alkyl group which may be substituted by 1 to 4 halogen atoms, or a phenyl radical optionally substituted by one or more halogen, C 1-6 alkyl, or alkoxy groups, Y is oxygen or sulphur, R 8 , when Y is S, is phenyl optionally substituted as for R 7 , or C 1-5 alkyl optionally substituted by alkyl mercapto, or, when Y is O, R 8 is C 1-6 alkyl or alkenyl, or cyclohexyl or cyclopentyl, at least one of R 7 and R 8 being substituted or unsubstituted phenyl, and n is 0 or 1, are prepared by reacting a diester chloride of formula Br-CR 1 R 2 -(CR 3 R 4 ) n -CR 5 R 6 -OP(O)(SR 7 )Cl with a compound HYR 8 . The starting diester may be prepared by reacting R 7 -S-Br with a compound of formula and used without isolation. The products have pesticidal properties.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19681768040 DE1768040A1 (en) | 1968-03-25 | 1968-03-25 | Process for the preparation of bromoalkyl- (di) -thiol-phosphoric acid esters |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1219713A true GB1219713A (en) | 1971-01-20 |
Family
ID=5699573
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB04383/69A Expired GB1219713A (en) | 1968-03-25 | 1969-03-19 | Bromoalkyl-(di)-thiolphosphoric acid esters |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US3641224A (en) |
| JP (1) | JPS5114577B1 (en) |
| AT (1) | AT290554B (en) |
| BE (1) | BE730354A (en) |
| CH (1) | CH515935A (en) |
| DE (1) | DE1768040A1 (en) |
| DK (1) | DK123271B (en) |
| ES (1) | ES365217A1 (en) |
| FR (1) | FR2004696A1 (en) |
| GB (1) | GB1219713A (en) |
| IL (1) | IL31611A0 (en) |
| NL (1) | NL6904578A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5342584U (en) * | 1976-09-17 | 1978-04-12 |
-
1968
- 1968-03-25 DE DE19681768040 patent/DE1768040A1/en active Pending
-
1969
- 1969-02-10 CH CH198669A patent/CH515935A/en not_active IP Right Cessation
- 1969-02-13 IL IL31611A patent/IL31611A0/en unknown
- 1969-03-13 US US807106A patent/US3641224A/en not_active Expired - Lifetime
- 1969-03-19 GB GB04383/69A patent/GB1219713A/en not_active Expired
- 1969-03-20 JP JP44020942A patent/JPS5114577B1/ja active Pending
- 1969-03-24 AT AT287669A patent/AT290554B/en not_active IP Right Cessation
- 1969-03-24 DK DK160969AA patent/DK123271B/en unknown
- 1969-03-24 BE BE730354D patent/BE730354A/xx unknown
- 1969-03-25 ES ES365217A patent/ES365217A1/en not_active Expired
- 1969-03-25 FR FR6908772A patent/FR2004696A1/fr not_active Withdrawn
- 1969-03-25 NL NL6904578A patent/NL6904578A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DK123271B (en) | 1972-06-05 |
| DE1768040A1 (en) | 1971-10-14 |
| AT290554B (en) | 1971-06-11 |
| JPS5114577B1 (en) | 1976-05-11 |
| BE730354A (en) | 1969-09-24 |
| IL31611A0 (en) | 1969-04-30 |
| ES365217A1 (en) | 1971-02-16 |
| CH515935A (en) | 1971-11-30 |
| FR2004696A1 (en) | 1969-11-28 |
| NL6904578A (en) | 1969-09-29 |
| US3641224A (en) | 1972-02-08 |
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