GB1214733A - A method for the preparation of stannous salt/palladium compositions - Google Patents
A method for the preparation of stannous salt/palladium compositionsInfo
- Publication number
- GB1214733A GB1214733A GB30369/68A GB3036968A GB1214733A GB 1214733 A GB1214733 A GB 1214733A GB 30369/68 A GB30369/68 A GB 30369/68A GB 3036968 A GB3036968 A GB 3036968A GB 1214733 A GB1214733 A GB 1214733A
- Authority
- GB
- United Kingdom
- Prior art keywords
- stannous salt
- palladium
- solution
- salt
- compositions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
- C23C18/28—Sensitising or activating
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemically Coating (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1,214,733. Acidic stannous salt/palladium composition. MACDERMID Inc. 26 June, 1968 [28 June, 1967], No. 30369/68. Heading ClA. [Also in Division C7] Acidic stannous salt/palladium compositions are prepared by dissolving a palladium II salt, suitable PdCl 2 , in HCl and adding a stannous salt, preferably 5nCl 2 , just equivalent to the palladium in solution. The mixture is agitated to completely dissolve the stannous salt and to effect the reduction Pd<SP>2</SP>+ --> Pd. A solution of additional stannous salt in HCI, which solution may also contain Na 2 SnO 3 , is added, with stirring to the solution to form a protective colloid for the reduced Pd. The reaction may be carried out at room temperature or, if more active compositions are required, at temperatures between 100-120 C. In a preferred embodiment the reactants are present in amounts to provide a composition containing 0À05-5À0 g/I. of Pd, 2À5-250 g/1. of Sn= ions, 0À35-35À0 0 g/l. of Ne 2 SnO 3 , HCI and water.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US65430767A | 1967-06-28 | 1967-06-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1214733A true GB1214733A (en) | 1970-12-02 |
Family
ID=24624315
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB30369/68A Expired GB1214733A (en) | 1967-06-28 | 1968-06-26 | A method for the preparation of stannous salt/palladium compositions |
Country Status (3)
Country | Link |
---|---|
US (1) | US3532518A (en) |
ES (1) | ES355956A1 (en) |
GB (1) | GB1214733A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2422187A1 (en) * | 1978-04-04 | 1979-11-02 | Polaroid Corp | PROCESS FOR FORMING SILVER PRECIPITATION CORES BY A NOBLE METAL |
Families Citing this family (57)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3655433A (en) * | 1970-07-06 | 1972-04-11 | Standard Oil Co | Platable polymers |
US3790400A (en) * | 1972-07-24 | 1974-02-05 | Macdermid Inc | Preparation of plastic substrates for electroless plating and solutions therefor |
US3841881A (en) * | 1972-09-13 | 1974-10-15 | Rca Corp | Method for electroless deposition of metal using improved colloidal catalyzing solution |
US3902908A (en) * | 1973-03-21 | 1975-09-02 | Macdermid Inc | Catalyst system for activating surfaces prior to electroless deposition |
CA1005808A (en) * | 1973-06-27 | 1977-02-22 | Shipley Company Inc. | Catalyst solution for electroless metal deposition on a substrate |
US3915717A (en) * | 1973-11-12 | 1975-10-28 | Rca Corp | Stabilized autocatalytic metal deposition baths |
US4212768A (en) * | 1975-05-05 | 1980-07-15 | Jameson Melvin N | Electroless plating of nonconductive substrates |
US4008343A (en) * | 1975-08-15 | 1977-02-15 | Bell Telephone Laboratories, Incorporated | Process for electroless plating using colloid sensitization and acid rinse |
US4048354A (en) * | 1975-10-23 | 1977-09-13 | Nathan Feldstein | Method of preparation and use of novel electroless plating catalysts |
US4025343A (en) * | 1976-01-14 | 1977-05-24 | Polaroid Corporation | Image receiving elements comprising stannic oxide polymers having noble metals reduced thereon |
ZA764709B (en) * | 1976-01-26 | 1978-02-22 | Borg Warner | Catalytically active composition for electroless plating |
US4100037A (en) * | 1976-03-08 | 1978-07-11 | Western Electric Company, Inc. | Method of depositing a metal on a surface |
US4065316A (en) * | 1976-07-19 | 1977-12-27 | Western Electric Company, Incorporated | Printing ink |
US4181759A (en) * | 1976-08-05 | 1980-01-01 | Nathan Feldstein | Process for metal deposition of a non-conductor substrate |
US4167601A (en) * | 1976-11-15 | 1979-09-11 | Western Electric Company, Inc. | Method of depositing a stress-free electroless copper deposit |
US4073981A (en) * | 1977-03-11 | 1978-02-14 | Western Electric Company, Inc. | Method of selectively depositing metal on a surface |
US4322457A (en) * | 1978-01-25 | 1982-03-30 | Western Electric Co., Inc. | Method of selectively depositing a metal on a surface |
US4381951A (en) * | 1978-01-25 | 1983-05-03 | Western Electric Co. Inc. | Method of removing contaminants from a surface |
US4339476A (en) * | 1978-08-17 | 1982-07-13 | Nathan Feldstein | Dispersions for activating non-conductors for electroless plating |
US4282271A (en) * | 1978-08-17 | 1981-08-04 | Nathan Feldstein | Dispersions for activating non-conductors for electroless plating |
US4318940A (en) * | 1978-08-17 | 1982-03-09 | Surface Technology, Inc. | Dispersions for activating non-conductors for electroless plating |
US4204013A (en) * | 1978-10-20 | 1980-05-20 | Oxy Metal Industries Corporation | Method for treating polymeric substrates prior to plating employing accelerating composition containing an alkyl amine |
US4228213A (en) * | 1979-08-13 | 1980-10-14 | Western Electric Company, Inc. | Method of depositing a stress-free electroless copper deposit |
WO1983004268A1 (en) * | 1982-05-26 | 1983-12-08 | Macdermid Incorporated | Catalyst solutions for activating non-conductive substrates and electroless plating process |
US4863758A (en) * | 1982-05-26 | 1989-09-05 | Macdermid, Incorporated | Catalyst solutions for activating non-conductive substrates and electroless plating process |
US4450191A (en) * | 1982-09-02 | 1984-05-22 | Omi International Corporation | Ammonium ions used as electroless copper plating rate controller |
DE3242162A1 (en) * | 1982-11-13 | 1984-05-17 | Bayer Ag, 5090 Leverkusen | METHOD FOR PRODUCING COMPOSITES |
DE3248778A1 (en) * | 1982-12-31 | 1984-07-12 | Bayer Ag, 5090 Leverkusen | METHOD FOR PRODUCING METALLIZED POROESE SOLIDS |
US4759952A (en) * | 1984-01-26 | 1988-07-26 | Learonal, Inc. | Process for printed circuit board manufacture |
US4847114A (en) * | 1984-01-26 | 1989-07-11 | Learonal, Inc. | Preparation of printed circuit boards by selective metallization |
US4761304A (en) * | 1984-01-26 | 1988-08-02 | Learonal, Inc. | Process for printed circuit board manufacture |
US4593016A (en) * | 1985-02-14 | 1986-06-03 | International Business Machines Corporation | Process for manufacturing a concentrate of a palladium-tin colloidal catalyst |
US4749626A (en) * | 1985-08-05 | 1988-06-07 | Olin Corporation | Whisker resistant tin coatings and baths and methods for making such coatings |
US4820643A (en) * | 1986-03-10 | 1989-04-11 | International Business Machines Corporation | Process for determining the activity of a palladium-tin catalyst |
US4717421A (en) * | 1986-04-28 | 1988-01-05 | Mcgean-Rohco, Inc. | Solid tin-palladium catalyst for electroless deposition incorporating stannous salts of organic acids |
JP2615804B2 (en) | 1988-04-14 | 1997-06-04 | 日本電気株式会社 | Manufacturing method of magnetic recording medium |
US5147692A (en) * | 1990-05-08 | 1992-09-15 | Macdermid, Incorporated | Electroless plating of nickel onto surfaces such as copper or fused tungston |
US5328561A (en) * | 1992-07-10 | 1994-07-12 | Macdermid Incorporated | Microetchant for copper surfaces and processes for using same |
US5368718A (en) * | 1993-09-13 | 1994-11-29 | Enthone-Omi, Inc. | Electrowinning of direct metallization accelerators |
US5545429A (en) * | 1994-07-01 | 1996-08-13 | International Business Machines Corporation | Fabrication of double side fully metallized plated thru-holes, in polymer structures, without seeding or photoprocess |
DE19524601C1 (en) * | 1995-07-06 | 1996-03-21 | Deutsche Automobilgesellsch | Activating porous plastic surfaces for chemical metallisation |
US5648125A (en) * | 1995-11-16 | 1997-07-15 | Cane; Frank N. | Electroless plating process for the manufacture of printed circuit boards |
DE19630581A1 (en) * | 1996-07-30 | 1998-02-05 | Studiengesellschaft Kohle Mbh | Process for the production of solvent-stabilized metal colloids and carrier-fixed metal clusters |
US5792248A (en) * | 1996-10-16 | 1998-08-11 | Fidelity Chemical Products Corporation, A Division Of Auric Corporation | Sensitizing solution |
US5770032A (en) * | 1996-10-16 | 1998-06-23 | Fidelity Chemical Products Corporation | Metallizing process |
DE10024239C1 (en) * | 2000-05-15 | 2001-09-20 | Atotech Deutschland Gmbh | Process for galvanically treating workpieces used e.g. in the production of circuit boards comprises contacting the workpieces with a palladium colloidal solution, and recovering the solution after use |
KR20020061530A (en) * | 2001-01-18 | 2002-07-24 | 쉬플리 캄파니, 엘.엘.씨. | A method for recovering catalytic metals |
US6586047B2 (en) | 2001-09-05 | 2003-07-01 | Brad Durkin | Process for plating particulate matter |
US6645557B2 (en) | 2001-10-17 | 2003-11-11 | Atotech Deutschland Gmbh | Metallization of non-conductive surfaces with silver catalyst and electroless metal compositions |
DE60209095T2 (en) | 2001-11-21 | 2006-08-17 | Shipley Co., L.L.C., Marlborough | Process for recovering catalytic metals |
DE60201404T2 (en) * | 2001-11-21 | 2005-03-10 | Shipley Co., L.L.C., Marlborough | Process for the recovery of catalyst metals using a porous metal filter |
US20050016416A1 (en) * | 2003-07-23 | 2005-01-27 | Jon Bengston | Stabilizer for electroless copper plating solution |
JP4729108B2 (en) * | 2007-02-07 | 2011-07-20 | 株式会社きもと | Electroless plating forming material, catalyst adhesion coating solution, electroless plating forming method, and plating method |
US20090056994A1 (en) * | 2007-08-31 | 2009-03-05 | Kuhr Werner G | Methods of Treating a Surface to Promote Metal Plating and Devices Formed |
WO2009029871A1 (en) * | 2007-08-31 | 2009-03-05 | Zettacore, Inc. | Methods of treating a surface to promote binding of molecule(s) of interest, coatings and devices formed therefrom |
US20090238979A1 (en) * | 2008-03-21 | 2009-09-24 | William Decesare | Method of Applying Catalytic Solution for Use in Electroless Deposition |
EP2591645B1 (en) | 2010-07-06 | 2018-09-05 | Namics Corporation | Methods of treating copper surfaces for enhancing adhesion to organic substrates for use in printed circuit boards |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3011920A (en) * | 1959-06-08 | 1961-12-05 | Shipley Co | Method of electroless deposition on a substrate and catalyst solution therefor |
US3099608A (en) * | 1959-12-30 | 1963-07-30 | Ibm | Method of electroplating on a dielectric base |
-
1967
- 1967-06-28 US US654307A patent/US3532518A/en not_active Expired - Lifetime
-
1968
- 1968-06-26 GB GB30369/68A patent/GB1214733A/en not_active Expired
- 1968-06-28 ES ES355956A patent/ES355956A1/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2422187A1 (en) * | 1978-04-04 | 1979-11-02 | Polaroid Corp | PROCESS FOR FORMING SILVER PRECIPITATION CORES BY A NOBLE METAL |
Also Published As
Publication number | Publication date |
---|---|
ES355956A1 (en) | 1970-02-16 |
US3532518A (en) | 1970-10-06 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PE20 | Patent expired after termination of 20 years |