GB1209776A - Hydrocarbon-group iv metal compounds - Google Patents
Hydrocarbon-group iv metal compoundsInfo
- Publication number
- GB1209776A GB1209776A GB5165967A GB5165967A GB1209776A GB 1209776 A GB1209776 A GB 1209776A GB 5165967 A GB5165967 A GB 5165967A GB 5165967 A GB5165967 A GB 5165967A GB 1209776 A GB1209776 A GB 1209776A
- Authority
- GB
- United Kingdom
- Prior art keywords
- metal
- halide
- lithium
- hydrocarbon
- lead
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000002736 metal compounds Chemical class 0.000 title abstract 3
- -1 hydrocarbon halide Chemical class 0.000 abstract 8
- 229910052744 lithium Inorganic materials 0.000 abstract 6
- 239000004215 Carbon black (E152) Substances 0.000 abstract 5
- 229930195733 hydrocarbon Natural products 0.000 abstract 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 4
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 150000001340 alkali metals Chemical class 0.000 abstract 2
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 abstract 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 1
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- 150000005215 alkyl ethers Chemical class 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/30—Organic compounds compounds not mentioned before (complexes)
- C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
- C10L1/306—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond) organo Pb compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/24—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
- B65D81/28—Applications of food preservatives, fungicides, pesticides or animal repellants
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/24—Lead compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Food Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
1,209,776. Tetrahydrocarbon Group IV metal compounds. HOUSTON CHEMICAL CORP. 14 Nov., 1967 [14 Nov., 1966], No. 51659/67. Heading C2J. Tetrahydrocarbon Group IV metal compounds, especially those of tin and lead, and in which at least one hydrocarbon group is methyl, are made by introducing an ether, lithium metal containing at least 0À1% by weight of an alkali metal other than lithium, lead metal and at least one hydrocarbon halide including a methyl halide, to a reaction zone to produce a reaction mass, the hydrocarbon halide being introduced at a rate sufficiently slow to maintain an exothermic reaction until substantially all of the lithium metal has reacted, and recovering the tetrahydrocarbon compounds from the reaction mass. Preferably the reaction is carried out below 60‹ C., and 1À5 to 20 moles of the ether solvent (e.g. an alkyl ether, THF or tetrahydropyran) are used per mole of Group IV metal used, and at least 4À4 moles of lithium are introduced to the reaction zone per mole of lead. The hydrocarbon halide may comprise a methyl halide only but may also contain, e.g. an ethyl halide and/or a vinyl halide; and the alkali metal other than lithium is e.g. sodium. The lead metal may be provided as dry powder or slurried in hydrocarbon halide, and either or both the lead and lithium may be slurried in a diluent, e.g. a liquid hydrocarbon with a normal boiling-point between 90‹ and 150‹ C.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US59374766A | 1966-11-14 | 1966-11-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1209776A true GB1209776A (en) | 1970-10-21 |
Family
ID=24375980
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5165967A Expired GB1209776A (en) | 1966-11-14 | 1967-11-14 | Hydrocarbon-group iv metal compounds |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE1668218A1 (en) |
| GB (1) | GB1209776A (en) |
| GR (1) | GR35525B (en) |
-
1967
- 1967-10-17 GR GR670135525A patent/GR35525B/en unknown
- 1967-11-10 DE DE19671668218 patent/DE1668218A1/en active Pending
- 1967-11-14 GB GB5165967A patent/GB1209776A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GR35525B (en) | 1968-09-30 |
| DE1668218A1 (en) | 1971-09-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |