GB1208832A - Chlorinated homo- and copolymers of olefins - Google Patents

Chlorinated homo- and copolymers of olefins

Info

Publication number
GB1208832A
GB1208832A GB722868A GB722868A GB1208832A GB 1208832 A GB1208832 A GB 1208832A GB 722868 A GB722868 A GB 722868A GB 722868 A GB722868 A GB 722868A GB 1208832 A GB1208832 A GB 1208832A
Authority
GB
United Kingdom
Prior art keywords
chlorine
ethylene
oxygen
carbon tetrachloride
benzoyl peroxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB722868A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of GB1208832A publication Critical patent/GB1208832A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/18Introducing halogen atoms or halogen-containing groups
    • C08F8/20Halogenation

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

1,208,832. Chlorinating olefin polymers. FARBENFABRIKEN BAYER A.G. 14 Feb., 1968 [24 Feb., 1967], No. 7228/68. Heading C3P. Chlorinated olefin polymers having a chlorine content of 60 to 72 weight per cent are prepared by treating the polymer in organic solvent solution with chlorine and simultaneously with oxygen in the presence of radical formers or actinic light at 50‹ to 100‹ C., the oxygen content of the reaction mixture being 0.5 to 10 weight per cent based on the chlorine. The polymer may be of ethylene, propylene, butylene or isobutylene, optionally with vinyl chloride, vinylidene chloride, vinyl acetate, vinyl propionate, acrylic or methacrylic acids, or unsaturated sulphonic acids. The products may be stabilized with conventional epoxy ether and metal salt stabilizers, and are useful as lacquer binders. Examples describe the chlorination of (1) polyethylene in carbon tetrachloride in the presence of benzoyl peroxide, chlorine and air, (2) an ethylene/vinyl acetate copolymer in carbon tetrachloride in the presence of azodiisobutyronitrile, chlorine and oxygen, (3) an ethylene/vinyl chloride copolymer in chloroform in the presence of benzoyl peroxide, chlorine and oxygen, and (4) an ethylene/methacrylic acid copolymer in carbon tetrachloride in the presence of benzoyl peroxide, chlorine and air.
GB722868A 1967-02-24 1968-02-14 Chlorinated homo- and copolymers of olefins Expired GB1208832A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEF0051626 1967-02-24

Publications (1)

Publication Number Publication Date
GB1208832A true GB1208832A (en) 1970-10-14

Family

ID=7104767

Family Applications (1)

Application Number Title Priority Date Filing Date
GB722868A Expired GB1208832A (en) 1967-02-24 1968-02-14 Chlorinated homo- and copolymers of olefins

Country Status (4)

Country Link
BE (1) BE711187A (en)
DE (1) DE1720622A1 (en)
GB (1) GB1208832A (en)
NL (1) NL6802478A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51135706A (en) * 1975-04-08 1976-11-24 Asahi Denka Kogyo Kk Composition of coloring material
EP0342659A2 (en) * 1988-05-20 1989-11-23 E.I. Du Pont De Nemours And Company Chlorinated terpolymers of ethylene

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51135706A (en) * 1975-04-08 1976-11-24 Asahi Denka Kogyo Kk Composition of coloring material
JPS5343845B2 (en) * 1975-04-08 1978-11-24
EP0342659A2 (en) * 1988-05-20 1989-11-23 E.I. Du Pont De Nemours And Company Chlorinated terpolymers of ethylene
EP0342659A3 (en) * 1988-05-20 1991-09-11 E.I. Du Pont De Nemours And Company Chlorinated terpolymers of ethylene

Also Published As

Publication number Publication date
DE1720622A1 (en) 1971-07-01
NL6802478A (en) 1968-08-26
BE711187A (en) 1968-07-01

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees