GB1206431A - Oxidation of alkanes and cycloalkanes - Google Patents

Oxidation of alkanes and cycloalkanes

Info

Publication number
GB1206431A
GB1206431A GB8003/67A GB800367A GB1206431A GB 1206431 A GB1206431 A GB 1206431A GB 8003/67 A GB8003/67 A GB 8003/67A GB 800367 A GB800367 A GB 800367A GB 1206431 A GB1206431 A GB 1206431A
Authority
GB
United Kingdom
Prior art keywords
cycloalkanes
alkanes
oxidation
oxygen
vanadium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB8003/67A
Inventor
Christopher Stuart Elliott
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB8003/67A priority Critical patent/GB1206431A/en
Priority to NL6802191A priority patent/NL6802191A/xx
Priority to DE19681668316 priority patent/DE1668316A1/en
Priority to FR1558643D priority patent/FR1558643A/fr
Priority to BE711030D priority patent/BE711030A/xx
Publication of GB1206431A publication Critical patent/GB1206431A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

1,206,431. Oxidation of alkanes and cycloalkanes. IMPERIAL CHEMICAL INDUSTRIES Ltd. 7 Feb., 1968 [20 Feb., 1967], No. 8003/67. Heading C2C. Alcohols, ketones, acids and/or esters are produced by oxidation of alkanes and cycloalkanes, preferably containing up to 20 carbons, with molecular oxygen in the liquid phase in the presence of an organic vanadium complex or the vanadium salt of an organic acid, or of any vanadium compound and another transition metal chosen from the first transition series (i.e. Sc-Zn inclusive) and in the substantial absence of any boron-containing compound. Both of the transition metal compounds are present in 0À00001-1% by weight and the second catalyst is preferably a copper or cobalt carboxylate. The reaction may be carried out using an oxygen/inert gas mixture containing 5-20% by volume oxygen, at a pressure in the range 15-600 p.s.i.g., at a temperature in the range 90-190‹ C. or in an inert solvent. The volatile by-products may be immediately removed and some of the product of the process containing peroxide may be recycled to the reaction zone to act as an initiator. Alternatively, initiators such as azo compounds, hydroperoxides and peroxides may be added. In the examples cyclohexane is oxidized to cyclohexanol, cyclohexanone and adipic acid and cyclooctane is oxidized to cyclooctanol, cyclooctanone, adipic and stearic acids and their esters.
GB8003/67A 1967-02-20 1967-02-20 Oxidation of alkanes and cycloalkanes Expired GB1206431A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
GB8003/67A GB1206431A (en) 1967-02-20 1967-02-20 Oxidation of alkanes and cycloalkanes
NL6802191A NL6802191A (en) 1967-02-20 1968-02-15
DE19681668316 DE1668316A1 (en) 1967-02-20 1968-02-19 Process for the oxidation of an alkane or cycloalkane
FR1558643D FR1558643A (en) 1967-02-20 1968-02-20
BE711030D BE711030A (en) 1967-02-20 1968-02-20

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB8003/67A GB1206431A (en) 1967-02-20 1967-02-20 Oxidation of alkanes and cycloalkanes

Publications (1)

Publication Number Publication Date
GB1206431A true GB1206431A (en) 1970-09-23

Family

ID=9843922

Family Applications (1)

Application Number Title Priority Date Filing Date
GB8003/67A Expired GB1206431A (en) 1967-02-20 1967-02-20 Oxidation of alkanes and cycloalkanes

Country Status (5)

Country Link
BE (1) BE711030A (en)
DE (1) DE1668316A1 (en)
FR (1) FR1558643A (en)
GB (1) GB1206431A (en)
NL (1) NL6802191A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5426237A (en) * 1991-08-08 1995-06-20 Sumitomo Chemical Co., Ltd. Process for producing alcohols and ketones
CN105237345A (en) * 2015-10-28 2016-01-13 衢州群颖化学科技有限公司 Method for preparing cyclooctanol and cyclooctanone through cyclooctane oxidation

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5426237A (en) * 1991-08-08 1995-06-20 Sumitomo Chemical Co., Ltd. Process for producing alcohols and ketones
CN105237345A (en) * 2015-10-28 2016-01-13 衢州群颖化学科技有限公司 Method for preparing cyclooctanol and cyclooctanone through cyclooctane oxidation

Also Published As

Publication number Publication date
NL6802191A (en) 1968-08-21
DE1668316A1 (en) 1972-01-05
BE711030A (en) 1968-08-20
FR1558643A (en) 1969-02-28

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee