GB1205918A - Method of manufacturing cyclohexanol and cyclohexanone by oxidising cyclohexane - Google Patents

Method of manufacturing cyclohexanol and cyclohexanone by oxidising cyclohexane

Info

Publication number
GB1205918A
GB1205918A GB39168/69A GB3916869A GB1205918A GB 1205918 A GB1205918 A GB 1205918A GB 39168/69 A GB39168/69 A GB 39168/69A GB 3916869 A GB3916869 A GB 3916869A GB 1205918 A GB1205918 A GB 1205918A
Authority
GB
United Kingdom
Prior art keywords
cyclohexanol
cyclohexanone
cyclohexane
manufacturing
aug
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB39168/69A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Vickers Zimmer AG
Original Assignee
Vickers Zimmer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vickers Zimmer AG filed Critical Vickers Zimmer AG
Publication of GB1205918A publication Critical patent/GB1205918A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/081—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing particle radiation or gamma-radiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2415—Tubular reactors
    • B01J19/243—Tubular reactors spirally, concentrically or zigzag wound
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/245—Stationary reactors without moving elements inside placed in series
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094—Jackets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00159—Controlling the temperature controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1,205,918. Oxidation of cyclohexane. VICKERS-ZIMMER A.G. PLANUNG UND BAU VON INDUSTRIEANLAGEN. 5 Aug., 1969 [22 Aug., 1968], No. 39168/69. Heading C2C. Cyclohexanol and cyclohexanone are manufactured by oxidizing cyclohexane in the liquid and/or gas phase with oxygen or a molecular oxygen-containing gas in the presence of ionizing radiation, preferably that from a cobalt-60-gamma source. The reaction preferably occurs under increased pressure at a temperature between 50‹ and 170‹ C. and in the presence of a catalyst such as a hydrocarbonsoluble cobalt, manganese or copper compound.
GB39168/69A 1968-08-22 1969-08-05 Method of manufacturing cyclohexanol and cyclohexanone by oxidising cyclohexane Expired GB1205918A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19681793249 DE1793249B1 (en) 1968-08-22 1968-08-22 Process for the production of cyclohexanol and cyclohexanone by oxidation of cyclohexane

Publications (1)

Publication Number Publication Date
GB1205918A true GB1205918A (en) 1970-09-23

Family

ID=5707631

Family Applications (1)

Application Number Title Priority Date Filing Date
GB39168/69A Expired GB1205918A (en) 1968-08-22 1969-08-05 Method of manufacturing cyclohexanol and cyclohexanone by oxidising cyclohexane

Country Status (4)

Country Link
US (1) US3706647A (en)
DE (1) DE1793249B1 (en)
FR (1) FR2016151A1 (en)
GB (1) GB1205918A (en)

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2615921A (en) * 1949-11-07 1952-10-28 Phillips Petroleum Co Hydrocarbon oxidation
DE1046610B (en) * 1955-06-15 1958-12-18 Basf Ag Process for the production of cyclohexanol and cyclohexanone by oxidation of cyclohexane
DE1078569B (en) * 1957-09-28 1960-03-31 Basf Ag Process for the preparation of alcohols and ketones by the oxidation of cycloaliphatic hydrocarbons
US3368955A (en) * 1962-09-18 1968-02-13 Atlas Chem Ind Radiochemical synthesis of cycloalkanols and cycloalkanones

Also Published As

Publication number Publication date
US3706647A (en) 1972-12-19
FR2016151A1 (en) 1970-05-08
DE1793249B1 (en) 1972-11-30

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PLNP Patent lapsed through nonpayment of renewal fees