GB1205027A - Oxo process - Google Patents
Oxo processInfo
- Publication number
- GB1205027A GB1205027A GB04471/67A GB1447167A GB1205027A GB 1205027 A GB1205027 A GB 1205027A GB 04471/67 A GB04471/67 A GB 04471/67A GB 1447167 A GB1447167 A GB 1447167A GB 1205027 A GB1205027 A GB 1205027A
- Authority
- GB
- United Kingdom
- Prior art keywords
- carbon monoxide
- olefin
- march
- catalyst
- hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title abstract 4
- 150000001336 alkenes Chemical class 0.000 abstract 4
- 239000003446 ligand Substances 0.000 abstract 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 3
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 150000007942 carboxylates Chemical group 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052703 rhodium Inorganic materials 0.000 abstract 2
- 239000010948 rhodium Substances 0.000 abstract 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Substances 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 abstract 1
- 229910052785 arsenic Inorganic materials 0.000 abstract 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 230000000536 complexating effect Effects 0.000 abstract 1
- 238000007037 hydroformylation reaction Methods 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0073—Rhodium compounds
- C07F15/008—Rhodium compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
1,205,027. Oxo process. BRITISH PETROLEUM CO. Ltd. 22 March, 1968 [30 March, 1967], No. 14471/67. Heading C2C. A process for the hydroformylation of olefins to aldehydes with substantially no simultaneous formation of alcohols, comprises hydroformylating an olefin with carbon monoxide and hydrogen at elevated temperature and at pressure greater than 100 p.s.i.g. in the presence of not more than 1 mole per 3600 moles of the feed of a square planar complex of monovalent rhodium containing at least one carboxylate ligand. The catalyst/olefin mole ratio should preferably lie between 1: 3,600 and 1: 360,000. Complexing ligands co-ordinating through nitrogen, phosphorus, arsenic, antimony or sulphur may be contained in the rhodium complex as may be one or more carbon monoxide ligands. To assist the stability of the catalyst on recycle a carboxylic acid, preferably corresponding to the carboxylate ligand, may be present. The process is preferably carried out at a temperature between 40‹ and 100‹ C. using a hydrogen to carbon monoxide feed ratio between 4: 1 and 1: 4. In the examples hexene (1) is the olefin used.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB04471/67A GB1205027A (en) | 1967-03-30 | 1967-03-30 | Oxo process |
| FR146007A FR1558222A (en) | 1967-03-30 | 1968-03-28 | |
| BE712951D BE712951A (en) | 1967-03-30 | 1968-03-29 | |
| NL6804417A NL6804417A (en) | 1967-03-30 | 1968-03-29 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB04471/67A GB1205027A (en) | 1967-03-30 | 1967-03-30 | Oxo process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1205027A true GB1205027A (en) | 1970-09-09 |
Family
ID=10041785
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB04471/67A Expired GB1205027A (en) | 1967-03-30 | 1967-03-30 | Oxo process |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE712951A (en) |
| FR (1) | FR1558222A (en) |
| GB (1) | GB1205027A (en) |
| NL (1) | NL6804417A (en) |
-
1967
- 1967-03-30 GB GB04471/67A patent/GB1205027A/en not_active Expired
-
1968
- 1968-03-28 FR FR146007A patent/FR1558222A/fr not_active Expired
- 1968-03-29 BE BE712951D patent/BE712951A/xx unknown
- 1968-03-29 NL NL6804417A patent/NL6804417A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NL6804417A (en) | 1968-10-01 |
| BE712951A (en) | 1968-09-30 |
| FR1558222A (en) | 1969-02-21 |
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| US3697600A (en) | Preparation of a ketone and an aldehyde,by carbonylation of an olefin in the presence of a secondary alcohol | |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |