GB1195652A - Anionic Surface-Active Agents and Cosmetic Compositions Containing them - Google Patents
Anionic Surface-Active Agents and Cosmetic Compositions Containing themInfo
- Publication number
- GB1195652A GB1195652A GB3764468A GB3764468A GB1195652A GB 1195652 A GB1195652 A GB 1195652A GB 3764468 A GB3764468 A GB 3764468A GB 3764468 A GB3764468 A GB 3764468A GB 1195652 A GB1195652 A GB 1195652A
- Authority
- GB
- United Kingdom
- Prior art keywords
- radical
- formula
- acid
- defined above
- atom
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
- A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Cosmetics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1,195,652. Anionic surface-active agents. L'OREAL. 7 Aug., 1968 [7 Aug., 1967], No. 37644/68. Heading C2C. [Also in Divisions C5 and D1] Novel anionic chemical compounds having surface activity and having the Formula (I): in which R is an aliphatic alkyl or alkenyl radical having from 8 to 22 carbon atoms or an alkyl-aryl radical having from 12 to 22 carbon atoms, X and X<SP>1</SP> may be identical or different and represent oxygen, sulphur or the sulphoxide grouping, A represents an ethylene, propylene or butylene radical, A<SP>1</SP> represents a radical -C 2 H 3 (CH 2 OH)- or -CH 2 CHOH-CH 2 -, A<SP>11</SP> represents a radical -CH 2 CHOH-CH 2 -, a radical -CH 2 CH 2 CH- or a radical -CH 2 CH(CH 3 )-, at least one of the radicals A<SP>1</SP> and A<SP>11</SP> being a hydroxyalkylene radical, respectively, as defined above, each of m and n, which may be the same or different, represents a statistical average value from 0 to 10 inclusive, and R<SP>1</SP> represents a H atom or a methyl or ethyl radical, it being understood that if m and n are simultaneously nought, X<SP>1</SP> is necessarily the sulphoxide grouping, are prepared by:-(a) when X<SP>1</SP> is the sulphoxide grouping, treating a compound of the Formula (I) having a thioether bond with hydrogen peroxide in the presence of a carboxylic acid and preferably acetic acid (about 1 or 2% of the total dry extract) at a temperature between 0‹ and 50‹ C.; (b) when X<SP>1</SP> is an oxygen atom, reacting a polyether alcohol alcoholate of the formula in which R, X, A, A<SP>11</SP>, m and n are as defined above and A<SP>111</SP> is identical to A<SP>1</SP> or may represent radicals -C 2 H 3 (CH 2 Cl)- or -C 2 H 3 - (CH 2 Br)- and M is an alkali metal, with a salt of a haloalkanecarboxylic acid of the formula where R<SP>1</SP> is as defined above and M<SP>1</SP> is an alkali or alkaline earth metal and Y represents a halogen atom, preferably bromine or chlorine; or when A<SP>1</SP> represents a group -C 2 H 3 (CH 2 OH)- and A<SP>11</SP> represents a group -CH 2 CHOHCH 2 -, reacting a glycidyl ether of the Formula (VIII): with a haloalkane carboxylic acid of the formula where R, X, A, R<SP>1</SP>, m and n are as defined above and Y and Z, which may be the same or different, represent a halogen atom and the product is treated with an alkali-metal hydroxide, and optionally liberating the free acid from its salt by means of an aqueous solution of a strong mineral acid, and the replacement of the halogen atoms Z is finally effected by hydroxyl groups; (c) when X<SP>1</SP> is a sulphur atom, reacting a mercaptoalkanoic acid or a salt or alkyl (of 1 to 6 carbon atoms) ester of such an acid with either an ether of glycidyl of the Formula (II): where R, X, A, A<SP>111</SP>, m and n are as defined above, or with an ether of allyl alcohol of the formula where R, X, A, A<SP>111</SP>, m and n are as defined above, and hydrolysis and/or saponification of the product obtained is thereafter optionally effected. The reaction employing the compound (II) is carried out at a temperature between 20‹ and 150‹ C. and as alkaline catalyst there may be used alkaline alcoholates, mercaptides, alkaline hydroxides or tertiary amines. The molar ratios of mercaptoalkanoic acid, of its salts or of its esters to the glycidyl ether employed are of the order of 1:1 to 1À5: 1 and preferably about 1: 1 to 1À1: 1.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
LU54263 | 1967-08-07 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1195652A true GB1195652A (en) | 1970-06-17 |
Family
ID=19725299
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3764468A Expired GB1195652A (en) | 1967-08-07 | 1968-08-07 | Anionic Surface-Active Agents and Cosmetic Compositions Containing them |
Country Status (7)
Country | Link |
---|---|
BE (1) | BE719103A (en) |
CH (1) | CH497896A (en) |
DE (1) | DE1793123C3 (en) |
FR (1) | FR1578344A (en) |
GB (1) | GB1195652A (en) |
IT (1) | IT1059803B (en) |
LU (1) | LU54263A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5055230A (en) * | 1987-07-14 | 1991-10-08 | Ciba-Geigy Corporation | Corrosion inhibiting compositions |
CN102070498A (en) * | 2011-01-12 | 2011-05-25 | 华东师范大学 | Preparation method of sulfoxide |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2521135B1 (en) * | 1982-02-05 | 1986-05-09 | Oreal | POLYANIONIC COMPOUNDS, PROCESS FOR THE PREPARATION THEREOF, AND COMPOSITIONS CONTAINING THEM |
LU84941A1 (en) * | 1983-08-02 | 1985-04-24 | Oreal | NOVEL POLYANIONIC COMPOUNDS DERIVED FROM ARYLETHERS OF POLYGLYCEROLS |
-
1967
- 1967-08-07 LU LU54263D patent/LU54263A1/xx unknown
-
1968
- 1968-08-02 CH CH1165368A patent/CH497896A/en not_active IP Right Cessation
- 1968-08-06 FR FR1578344D patent/FR1578344A/fr not_active Expired
- 1968-08-06 BE BE719103D patent/BE719103A/xx not_active IP Right Cessation
- 1968-08-06 IT IT5274168A patent/IT1059803B/en active
- 1968-08-06 DE DE19681793123 patent/DE1793123C3/en not_active Expired
- 1968-08-07 GB GB3764468A patent/GB1195652A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5055230A (en) * | 1987-07-14 | 1991-10-08 | Ciba-Geigy Corporation | Corrosion inhibiting compositions |
CN102070498A (en) * | 2011-01-12 | 2011-05-25 | 华东师范大学 | Preparation method of sulfoxide |
Also Published As
Publication number | Publication date |
---|---|
IT1059803B (en) | 1982-06-21 |
DE1793123A1 (en) | 1972-01-27 |
CH497896A (en) | 1970-10-31 |
DE1793123C3 (en) | 1980-06-26 |
LU54263A1 (en) | 1969-03-24 |
FR1578344A (en) | 1969-08-14 |
DE1793123B2 (en) | 1979-10-11 |
BE719103A (en) | 1969-01-16 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
429A | Application made for amendment of specification (sect. 29/1949) | ||
429H | Application (made) for amendment of specification now open to opposition (sect. 29/1949) | ||
429D | Case decided by the comptroller ** specification amended (sect. 29/1949) | ||
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |