GB1193904A - New Polymers and Copolymers Containing Silver & Copper - Google Patents
New Polymers and Copolymers Containing Silver & CopperInfo
- Publication number
- GB1193904A GB1193904A GB24837/68D GB2483768D GB1193904A GB 1193904 A GB1193904 A GB 1193904A GB 24837/68 D GB24837/68 D GB 24837/68D GB 2483768 D GB2483768 D GB 2483768D GB 1193904 A GB1193904 A GB 1193904A
- Authority
- GB
- United Kingdom
- Prior art keywords
- silver
- copolymer
- polymer
- cations
- groups
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000642 polymer Polymers 0.000 title abstract 7
- 229920001577 copolymer Polymers 0.000 title abstract 6
- 229910052709 silver Inorganic materials 0.000 title abstract 6
- 239000004332 silver Substances 0.000 title abstract 6
- 229910052802 copper Inorganic materials 0.000 title abstract 2
- 239000010949 copper Substances 0.000 title abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title 1
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 abstract 8
- -1 copper cations Chemical class 0.000 abstract 4
- 229910052751 metal Inorganic materials 0.000 abstract 4
- 239000002184 metal Substances 0.000 abstract 4
- 229910001961 silver nitrate Inorganic materials 0.000 abstract 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract 3
- 150000001768 cations Chemical class 0.000 abstract 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 2
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 abstract 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 abstract 1
- 239000004160 Ammonium persulphate Substances 0.000 abstract 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 239000012190 activator Substances 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 abstract 1
- 235000019395 ammonium persulphate Nutrition 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Chemical compound CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 150000002500 ions Chemical class 0.000 abstract 1
- 229920002521 macromolecule Polymers 0.000 abstract 1
- 239000012528 membrane Substances 0.000 abstract 1
- 229910017604 nitric acid Inorganic materials 0.000 abstract 1
- 125000002560 nitrile group Chemical group 0.000 abstract 1
- 229920002239 polyacrylonitrile Polymers 0.000 abstract 1
- RWPGFSMJFRPDDP-UHFFFAOYSA-L potassium metabisulfite Chemical compound [K+].[K+].[O-]S(=O)S([O-])(=O)=O RWPGFSMJFRPDDP-UHFFFAOYSA-L 0.000 abstract 1
- 235000010263 potassium metabisulphite Nutrition 0.000 abstract 1
- 229940071536 silver acetate Drugs 0.000 abstract 1
- BWYYYTVSBPRQCN-UHFFFAOYSA-M sodium;ethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=C BWYYYTVSBPRQCN-UHFFFAOYSA-M 0.000 abstract 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0079—Manufacture of membranes comprising organic and inorganic components
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/14—Dynamic membranes
- B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/76—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
- B01D71/80—Block polymers
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
- C02F1/505—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment by oligodynamic treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/10—Metal compounds
- C08K3/105—Compounds containing metals of Groups 1 to 3 or of Groups 11 to 13 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/18—Homopolymers or copolymers of nitriles
- C08L33/20—Homopolymers or copolymers of acrylonitrile
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/04—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with macromolecular additives; with layer-forming substances
- G03C1/053—Polymers obtained by reactions involving only carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/494—Silver salt compositions other than silver halide emulsions; Photothermographic systems ; Thermographic systems using noble metal compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- General Physics & Mathematics (AREA)
- Water Supply & Treatment (AREA)
- General Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Hydrology & Water Resources (AREA)
- Life Sciences & Earth Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
1,193,904. Polymer metal complexes. CESKOSLOVENSKA AKADEMIE VED. 24 May, 1968 [25 May, 1967], No. 24837/68. Heading C3P. [Also in Division G2] A polymer-metal complex is formed by contacting a polymer system containing nitrile groups and groups capable of forming the anions -OSO- 2 , -OSO- 3 or -OPO<SP>2-</SP> 3 in ionizing media. both groups being attached to macromolecular main chains, with silver or copper cations. The ionizing media may be water. The groups may be borne by the same or different macromolecules. The polymer system is preferably a copolymer of acrylonitrile with vinyl sulphonic acid, styrene sulphonic acid or an alkali metal salt of one of these acids. The complex metal cation may be reduced thus forming a dispersion of the free metal in the copolymer. The free metal may be reconstituted by contacting the copolymer with silver or cuprous cations. The copolymer complex containing silver cations may be treated with a halide solution, and this polymer system containing dispersed silver halide may be contacted with silver or cuprous cations. In the examples, acrylonitrile, sodium vinyl sulphonate and optionally ethylene glycol bis-methacrylate or acrylamide, are co-polymerized using a catalyst comprising potassium pyrosulphite and ammonium persulphate with a copper sulphate activator. The polymer is formed into a membrane layer or filament which is treated with silver nitrate or acetate solutions or a solution containing cuprous ions. In other examples silver nitrate is added to polyethylene- or polystyrene-sulphonic acid and this is mixed with polyacrylonitrile; alternatively the two polymers are mixed and together added to a silver nitrate solution. In, a further example, a nitric acid solution of polyacryonitrile is treated with silver nitrate and then reacted with an acrylonitrile-ethylenesulphonic acid copolymer.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS382167 | 1967-05-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1193904A true GB1193904A (en) | 1970-06-03 |
Family
ID=5379412
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB24837/68D Expired GB1193904A (en) | 1967-05-25 | 1968-05-24 | New Polymers and Copolymers Containing Silver & Copper |
Country Status (7)
| Country | Link |
|---|---|
| AT (1) | AT286624B (en) |
| BE (1) | BE715510A (en) |
| DE (1) | DE1770498C3 (en) |
| FR (1) | FR1567494A (en) |
| GB (1) | GB1193904A (en) |
| NO (1) | NO129001B (en) |
| SE (3) | SE359169B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3209795A1 (en) * | 1982-03-18 | 1983-09-29 | Hoechst Ag, 6230 Frankfurt | METHOD FOR PRODUCING THERMOSTABLE FIBERS AND THREADS |
-
1968
- 1968-05-21 NO NO01971/68A patent/NO129001B/no unknown
- 1968-05-21 SE SE03598/71A patent/SE359169B/xx unknown
- 1968-05-21 SE SE6877/68A patent/SE345469B/xx unknown
- 1968-05-21 SE SE7103597A patent/SE372278B/xx unknown
- 1968-05-22 BE BE715510D patent/BE715510A/xx unknown
- 1968-05-22 FR FR1567494D patent/FR1567494A/fr not_active Expired
- 1968-05-24 AT AT498168A patent/AT286624B/en not_active IP Right Cessation
- 1968-05-24 GB GB24837/68D patent/GB1193904A/en not_active Expired
- 1968-05-25 DE DE1770498A patent/DE1770498C3/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| SE345469B (en) | 1972-05-29 |
| DE1770498B2 (en) | 1974-05-22 |
| SE359169B (en) | 1973-08-20 |
| AT286624B (en) | 1970-12-10 |
| SE372278B (en) | 1974-12-16 |
| BE715510A (en) | 1968-10-16 |
| DE1770498C3 (en) | 1975-02-20 |
| DE1770498A1 (en) | 1971-10-28 |
| FR1567494A (en) | 1969-05-16 |
| NO129001B (en) | 1974-02-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB855767A (en) | Improvements in and relating to polyacrylonitrile solutions | |
| GB1307393A (en) | Primary cell electrolyte | |
| ATE26451T1 (en) | STABLE AND AMPHOTERIC AQUEOUS DISPERSIONS OF SYNTHETIC POLYMERS. | |
| GB1193904A (en) | New Polymers and Copolymers Containing Silver & Copper | |
| GB1185242A (en) | Polymer Deposition process and product | |
| GB1510714A (en) | Process for the production of acrylonitrile-vinyl chloride copolymers with whiteness | |
| GB997498A (en) | Improvements relating to block copolymers | |
| JPS55127312A (en) | Pack cosmetic | |
| GB907178A (en) | A process for the production of acrylonitrile polymers | |
| GB954612A (en) | Process for the production of acrylonitrile polymers | |
| GB1348044A (en) | Filaments and films of acrylonitrile polymers which are free from vacuoles | |
| GB911886A (en) | Process for the production of photographic silver halide emulsions | |
| ES383791A1 (en) | Production of polymers having betaine groups containing sulfur atoms | |
| GB1337160A (en) | Process for the preparation of vinyl chloride polymers | |
| IE780105L (en) | Acrylonitrile-vinyl chloride copolymer | |
| GB1162276A (en) | Production of Acrylonitrile Polymers by Photo-Polymerisation | |
| JPS57162704A (en) | Production of anticoagulant acrylonitrile polymer | |
| GB971055A (en) | Acrylic acid polymers | |
| GB1423468A (en) | Catalytic process for the preparation of polyacrylonitrile and acrylonitrile copolymers | |
| GB1535694A (en) | Process for the continuous production of acrylonitrile-vinyl chloride copolymers | |
| GB1215351A (en) | The polymerisation of acrylonitrile | |
| GB1471283A (en) | Method for dissolving acrylamide polymers | |
| GB1390918A (en) | Aromatic polymers | |
| ES427985A1 (en) | A catalytic procedure to prepare polymers and acrylonitrile copolymers. (Machine-translation by Google Translate, not legally binding) | |
| GB1257106A (en) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |