GB1189494A - Saturated Hydrocarbon Prepolymer and Reaction products thereof - Google Patents

Saturated Hydrocarbon Prepolymer and Reaction products thereof

Info

Publication number
GB1189494A
GB1189494A GB22017/67A GB2201767A GB1189494A GB 1189494 A GB1189494 A GB 1189494A GB 22017/67 A GB22017/67 A GB 22017/67A GB 2201767 A GB2201767 A GB 2201767A GB 1189494 A GB1189494 A GB 1189494A
Authority
GB
United Kingdom
Prior art keywords
groups
terminal
compounds
ethylene
reacted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB22017/67A
Inventor
James Edward Potts
Arnold Clifton Ashcraft
Edgar White Wise
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Priority to GB22017/67A priority Critical patent/GB1189494A/en
Publication of GB1189494A publication Critical patent/GB1189494A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M3/00—Liquid compositions essentially based on lubricating components other than mineral lubricating oils or fatty oils and their use as lubricants; Use as lubricants of single liquid substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/04—Reduction, e.g. hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/12—Hydrolysis
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/14—Esterification
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/40—Introducing phosphorus atoms or phosphorus-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/20—Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/40—Chemical modification of a polymer taking place solely at one end or both ends of the polymer backbone, i.e. not in the side or lateral chains
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/02—Groups 1 or 11

Abstract

1,189,494. Copolymers. UNION CARBIDE CORP. 11 May, 1967, No. 22017/67. Heading C3P. [Also in Division C5] Saturated hydrocarbon prepolymers comprise a substantially random interpolymer of ethylene and 5 to 70 weight per cent of an α-olefin or fluorine - substituted α - olefin H 2 C = CHCR 3 , where each R is C 1-6 alkyl or fluorine, said interpolymer having an average of 1 to 2 reactive functional groups attached to terminal carbon atoms of each polymer molecule and selected from hydroxy, carboxy, amino, cyano, formyl, aziridinyl and alkoxycarbonyl. Polymerization may be effected in bulk or solution, e.g. in hydrocarbons, ketones and cyclic ethers, in the presence of organic peroxides or azo compounds whereby such end groups as cyano, carboxy and alkoxycarbonyl may be introduced. These may be oxidized, reduced, hydrolysed or converted to chloride and reacted with ethylene imine to provide other desired end groups. The prepolymers may be converted to linear high polymers by reacting with difunctional compounds capable of reacting with the terminal groups, and cross-linked by reacting with compounds having a functionality greater than 2. Many suitable compounds are listed including polyepoxides, polyisocyanates, polyaziridines, polyamines, polyols and polybasic acids. The prepolymers may be used for potting compounds, polishes and inks and lithium and sodium salts thereof as lubricants, and the high polymers as potting compounds, electrical insulation, sealants, gaskets, weatherstrips, fibres, films and mouldings. In examples ethylene and neohexene are polymerized in the presence of (I-VI and X-XIV) benzene and azodiisobutyronitrile; (IX) tetrahydrofuran and succinic acid peroxide; (XVI) tetrahydrofuran and 4,4<SP>1</SP>-azobis-4-cyanopentanoic acid together with (XVII) dithiodibutyric acid; and (XVIII) benzene and diethyl - 2,2<SP>1</SP>- azobisisobutyrate; -CN terminal groups are hydrolysed to -COOH by acid or alkaline hydrolysis and terminal ethoxycarbonyl groups are reduced to -OH with lithium aluminium hydride; and ethylene/neohexene copolymers having terminal -COOH groups are reacted with (I) triglycidyl ether of p-aminophenol, 2,4-tolylene diisocyanate and succinic acid: (II) and (III) tris propylene imine phosphoric oxide; (IX) propane triol and ethylene glycol; and having terminal -OH groups are reacted with (XVIII) tris (N-methylethyleneimine) phosphorus oxide.
GB22017/67A 1967-05-11 1967-05-11 Saturated Hydrocarbon Prepolymer and Reaction products thereof Expired GB1189494A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB22017/67A GB1189494A (en) 1967-05-11 1967-05-11 Saturated Hydrocarbon Prepolymer and Reaction products thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB22017/67A GB1189494A (en) 1967-05-11 1967-05-11 Saturated Hydrocarbon Prepolymer and Reaction products thereof

Publications (1)

Publication Number Publication Date
GB1189494A true GB1189494A (en) 1970-04-29

Family

ID=10172573

Family Applications (1)

Application Number Title Priority Date Filing Date
GB22017/67A Expired GB1189494A (en) 1967-05-11 1967-05-11 Saturated Hydrocarbon Prepolymer and Reaction products thereof

Country Status (1)

Country Link
GB (1) GB1189494A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0508576A1 (en) * 1991-03-28 1992-10-14 Minnesota Mining And Manufacturing Company Microcapsules from polyfunctional aziridines

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0508576A1 (en) * 1991-03-28 1992-10-14 Minnesota Mining And Manufacturing Company Microcapsules from polyfunctional aziridines
US5401505A (en) * 1991-03-28 1995-03-28 Minnesota Mining And Manufacturing Microcapsules from polyfunctional aziridines

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees