GB1188736A - Method for Manufacturing Macroporous Polymers - Google Patents

Method for Manufacturing Macroporous Polymers

Info

Publication number
GB1188736A
GB1188736A GB00038/68A GB1003868A GB1188736A GB 1188736 A GB1188736 A GB 1188736A GB 00038/68 A GB00038/68 A GB 00038/68A GB 1003868 A GB1003868 A GB 1003868A GB 1188736 A GB1188736 A GB 1188736A
Authority
GB
United Kingdom
Prior art keywords
copolymer
monomers
acid
glycol
polymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB00038/68A
Inventor
Richard Chromecek
Otto Wichterle
Iva Gavrilova
Miroslav Kubin
Pavel Spacek
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Czech Academy of Sciences CAS
Original Assignee
Czech Academy of Sciences CAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Czech Academy of Sciences CAS filed Critical Czech Academy of Sciences CAS
Priority to GB00038/68A priority Critical patent/GB1188736A/en
Priority to FR141980A priority patent/FR1566455A/fr
Publication of GB1188736A publication Critical patent/GB1188736A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/06—Organic solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/20—Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/18—Introducing halogen atoms or halogen-containing groups
    • C08F8/20—Halogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
    • C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/44—Preparation of metal salts or ammonium salts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/28—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
    • C08J9/286—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum the liquid phase being a solvent for the monomers but not for the resulting macromolecular composition, i.e. macroporous or macroreticular polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/20—Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00—Foams characterised by the foaming process
    • C08J2201/04—Foams characterised by the foaming process characterised by the elimination of a liquid or solid component, e.g. precipitation, leaching out, evaporation
    • C08J2201/05—Elimination by evaporation or heat degradation of a liquid phase
    • C08J2201/0502—Elimination by evaporation or heat degradation of a liquid phase the liquid phase being organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

1,188,736. Porous polymers. CESKOSLOVENSKA AKADEMIE VED. 1 March, 1968, No. 10038/68. Heading C3P. Porous copolymers are obtained by copolymerizing a hydrophilic monomer which is a mono-acrylate or methacrylate of a hydrophilic polyol with a cross-linking agent soluble in the monomer mixture in the presence of an initiator and an inert liquid which dissolves the monomers but does not dissolve or swell the copolymer formed. The copolymer is formed in the presence of the inert liquid alone or in aqueous suspension e.g. using magnesium hydroxide as suspending agent. Specific ester monomers are acrylates and methacrylates of ethylene glycol, diethylene glycol, glycerol, mannitol or pentaerythritol and preferred cross-linking agents are diacrylate or methacrylate esters of glycol or polyglycols. Other monomers may be included containing ionic groups, e.g. (meth)acrylic acid, maleic anhydride, itaconic acid, ester or salt of ethylene sulphonic acid, styrene sulphonic acid, or dimethylacrylamide which may subsequently be reduced and quaternized. A small amount of a swelling agent for the copolymer may also be added. In the examples benzoyl peroxide or diisopropyl peroxydicarbonate is used as initiator. The products are particularly useful as chromatographic sorbents and for this purpose polymerization may be effected in situ in a tube. The products may also be after-treated; hydrochloric acid or thionyl chloride replaces the hydroxyl groups with chlorine and the chloro-polymers may be further treated with amines, cyanides (followed by hydrolysis), sulphites or hydrosulphides.
GB00038/68A 1968-03-01 1968-03-01 Method for Manufacturing Macroporous Polymers Expired GB1188736A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB00038/68A GB1188736A (en) 1968-03-01 1968-03-01 Method for Manufacturing Macroporous Polymers
FR141980A FR1566455A (en) 1968-03-01 1968-03-01

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB00038/68A GB1188736A (en) 1968-03-01 1968-03-01 Method for Manufacturing Macroporous Polymers
FR141980 1968-03-01

Publications (1)

Publication Number Publication Date
GB1188736A true GB1188736A (en) 1970-04-22

Family

ID=26181849

Family Applications (1)

Application Number Title Priority Date Filing Date
GB00038/68A Expired GB1188736A (en) 1968-03-01 1968-03-01 Method for Manufacturing Macroporous Polymers

Country Status (2)

Country Link
FR (1) FR1566455A (en)
GB (1) GB1188736A (en)

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2157627A1 (en) * 1970-11-24 1972-10-19 Ceskoslovenska Akademie Ved Process for the production of hydrophilic materials, which are particularly used in gel chromatography, by suspension copolymerization
DE2503774A1 (en) * 1974-02-01 1975-08-07 Ceskoslovenska Akademie Ved PROCESS FOR PRODUCING ION EXCHANGERS FROM HYDROPHILIC POLYMER GELS
US4999172A (en) * 1988-06-29 1991-03-12 Simons Paul B Absorber packing and method
WO1993007945A1 (en) * 1991-10-21 1993-04-29 Cornell Research Foundation, Inc. Column with macroporous polymer media
US5824328A (en) * 1987-04-01 1998-10-20 Stockhausen Gmbh Insecticidal delivery compositions and methods for controlling a population of insects in an aquatic environment
US6749749B2 (en) 2002-06-26 2004-06-15 Isco, Inc. Separation system, components of a separation system and methods of making and using them
US7473367B2 (en) 2002-06-26 2009-01-06 Dionex Corporation Monolithic column
WO2010120468A1 (en) * 2009-04-15 2010-10-21 3M Innovative Properties Company Process and apparatus for a nanovoided article
US8534849B2 (en) 2009-04-15 2013-09-17 3M Innovative Properties Company Retroreflecting optical construction
US8891038B2 (en) 2009-04-15 2014-11-18 3M Innovative Properties Company Lightguide with optical film containing voids and blacklight for display system
US8922733B2 (en) 2009-10-24 2014-12-30 3M Innovative Properties Company Light source and display system incorporating same
US8950924B2 (en) 2009-12-08 2015-02-10 3M Innovative Properties Company Optical constructions incorporating a light guide and low refractive index films
US9291752B2 (en) 2013-08-19 2016-03-22 3M Innovative Properties Company Retroreflecting optical construction
US9464179B2 (en) 2009-04-15 2016-10-11 3M Innovative Properties Company Process and apparatus for a nanovoided article
US9618663B2 (en) 2010-04-15 2017-04-11 3M Innovative Properties Company Retroreflective articles including optically active areas and optically inactive areas
US9791604B2 (en) 2010-04-15 2017-10-17 3M Innovative Properties Company Retroreflective articles including optically active areas and optically inactive areas
US9910194B2 (en) 2010-04-15 2018-03-06 3M Innovative Properties Company Retroreflective articles including optically active areas and optically inactive areas
US10539722B2 (en) 2009-04-15 2020-01-21 3M Innovative Properties Company Optical film
US10649274B2 (en) 2009-04-15 2020-05-12 3M Innovative Properties Company Optical construction and display system incorporating same
CN114262465A (en) * 2021-11-03 2022-04-01 赛分科技扬州有限公司 Polyacrylate-based sphere and amine salt modification method thereof

Cited By (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2157627A1 (en) * 1970-11-24 1972-10-19 Ceskoslovenska Akademie Ved Process for the production of hydrophilic materials, which are particularly used in gel chromatography, by suspension copolymerization
DE2503774A1 (en) * 1974-02-01 1975-08-07 Ceskoslovenska Akademie Ved PROCESS FOR PRODUCING ION EXCHANGERS FROM HYDROPHILIC POLYMER GELS
US5824328A (en) * 1987-04-01 1998-10-20 Stockhausen Gmbh Insecticidal delivery compositions and methods for controlling a population of insects in an aquatic environment
US4999172A (en) * 1988-06-29 1991-03-12 Simons Paul B Absorber packing and method
WO1993007945A1 (en) * 1991-10-21 1993-04-29 Cornell Research Foundation, Inc. Column with macroporous polymer media
US5453185A (en) * 1991-10-21 1995-09-26 Cornell Research Foundation, Inc. Column with macroporous polymer media
US5334310A (en) * 1991-10-21 1994-08-02 Cornell Research Foundation, Inc. Column with macroporous polymer media
US6749749B2 (en) 2002-06-26 2004-06-15 Isco, Inc. Separation system, components of a separation system and methods of making and using them
US7074331B2 (en) 2002-06-26 2006-07-11 Dionex Corporation Separation system, components of a separation system and methods of making and using them
US7473367B2 (en) 2002-06-26 2009-01-06 Dionex Corporation Monolithic column
US8795529B2 (en) 2002-06-26 2014-08-05 Dionex Corporation Disposable monolithic column
US7922908B2 (en) 2002-06-26 2011-04-12 Dionex Corporation Separation system, components of a separation system and methods of making and using them
US7922909B2 (en) 2002-06-26 2011-04-12 Dionex Corporation Separation system, components of a separation system and methods of making and using them
US8891038B2 (en) 2009-04-15 2014-11-18 3M Innovative Properties Company Lightguide with optical film containing voids and blacklight for display system
US10539722B2 (en) 2009-04-15 2020-01-21 3M Innovative Properties Company Optical film
CN102459440B (en) * 2009-04-15 2013-11-06 3M创新有限公司 Process and apparatus for a nanovoided article
CN102459440A (en) * 2009-04-15 2012-05-16 3M创新有限公司 Process and apparatus for a nanovoided article
US8808811B2 (en) 2009-04-15 2014-08-19 3M Innovative Properties Company Process and apparatus for a nanovoided article
WO2010120468A1 (en) * 2009-04-15 2010-10-21 3M Innovative Properties Company Process and apparatus for a nanovoided article
US11435616B2 (en) 2009-04-15 2022-09-06 3M Innovative Properties Company Optical construction and display system incorporating same
US10649274B2 (en) 2009-04-15 2020-05-12 3M Innovative Properties Company Optical construction and display system incorporating same
US8534849B2 (en) 2009-04-15 2013-09-17 3M Innovative Properties Company Retroreflecting optical construction
US9551816B2 (en) 2009-04-15 2017-01-24 3M Innovative Properties Company Retroreflecting optical construction
US9464179B2 (en) 2009-04-15 2016-10-11 3M Innovative Properties Company Process and apparatus for a nanovoided article
US9410677B2 (en) 2009-10-24 2016-08-09 3M Innovative Properties Company Light source and display system incorporating same
US8922733B2 (en) 2009-10-24 2014-12-30 3M Innovative Properties Company Light source and display system incorporating same
US9482807B2 (en) 2009-12-08 2016-11-01 3M Innovative Properties Company Optical constructions incorporating a light guide and low refractive index films
US8950924B2 (en) 2009-12-08 2015-02-10 3M Innovative Properties Company Optical constructions incorporating a light guide and low refractive index films
US9229149B2 (en) 2009-12-08 2016-01-05 3M Innovative Properties Company Optical constructions incorporating a light guide and low refractive index films
US10132969B2 (en) 2010-04-15 2018-11-20 3M Innovative Properties Company Retroreflective articles including optically active areas and optically inactive areas
US9910194B2 (en) 2010-04-15 2018-03-06 3M Innovative Properties Company Retroreflective articles including optically active areas and optically inactive areas
US10379271B2 (en) 2010-04-15 2019-08-13 3M Innovative Properties Company Retroreflective articles including optically active areas and optically inactive areas
US9791604B2 (en) 2010-04-15 2017-10-17 3M Innovative Properties Company Retroreflective articles including optically active areas and optically inactive areas
US10557976B2 (en) 2010-04-15 2020-02-11 3M Innovative Properties Company Retroreflective articles including optically active areas and optically inactive areas
US9618663B2 (en) 2010-04-15 2017-04-11 3M Innovative Properties Company Retroreflective articles including optically active areas and optically inactive areas
US10859738B2 (en) 2010-04-15 2020-12-08 3M Innovative Properties Company Retroreflective articles including optically active areas and optically inactive areas
US9291752B2 (en) 2013-08-19 2016-03-22 3M Innovative Properties Company Retroreflecting optical construction
CN114262465A (en) * 2021-11-03 2022-04-01 赛分科技扬州有限公司 Polyacrylate-based sphere and amine salt modification method thereof

Also Published As

Publication number Publication date
FR1566455A (en) 1969-05-09

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees