GB1176692A - Continuous Processes for the production of Ethylene Polymers and Catalysts suitable therefor - Google Patents
Continuous Processes for the production of Ethylene Polymers and Catalysts suitable thereforInfo
- Publication number
- GB1176692A GB1176692A GB381267A GB381267A GB1176692A GB 1176692 A GB1176692 A GB 1176692A GB 381267 A GB381267 A GB 381267A GB 381267 A GB381267 A GB 381267A GB 1176692 A GB1176692 A GB 1176692A
- Authority
- GB
- United Kingdom
- Prior art keywords
- stream
- solution
- hydrocarbon solvent
- production
- ethylene polymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title abstract 5
- 238000010924 continuous production Methods 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 229920000573 polyethylene Polymers 0.000 title 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 4
- -1 hydrocarbyl aluminium compound Chemical class 0.000 abstract 4
- 239000004215 Carbon black (E152) Substances 0.000 abstract 3
- 229930195733 hydrocarbon Natural products 0.000 abstract 3
- 150000002430 hydrocarbons Chemical class 0.000 abstract 3
- 239000002904 solvent Substances 0.000 abstract 3
- 239000007788 liquid Substances 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 230000032683 aging Effects 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- WBKDDMYJLXVBNI-UHFFFAOYSA-K chromium(3+);2-ethylhexanoate Chemical compound [Cr+3].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O WBKDDMYJLXVBNI-UHFFFAOYSA-K 0.000 abstract 1
- XEHUIDSUOAGHBW-UHFFFAOYSA-N chromium;pentane-2,4-dione Chemical compound [Cr].CC(=O)CC(C)=O.CC(=O)CC(C)=O.CC(=O)CC(C)=O XEHUIDSUOAGHBW-UHFFFAOYSA-N 0.000 abstract 1
- 238000010586 diagram Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 150000003623 transition metal compounds Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/061—Aluminium compounds with C-aluminium linkage
- C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
- C07F5/068—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage) preparation of alum(in)oxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
1,176,692. Polymerisation catalysts. UNION CARBIDE CORP. 25 Jan., 1967, No. 3812/67. Heading B1E. [Also in Division C3] A catalyst complex is formed by a process comprising:-(1) introducing a first stream of a dry, inert, liquid hydrocarbon solvent to a first contact zone containing water to wet said first stream; (2) introducing the watercontaining first stream and a second stream which is a solution of a (C 1-12 ) hydrocarbyl aluminium compound in a dry, inert, liquid hydrocarbon solvent to a second reaction zone, wherein the hydrocarbyl aluminium compound and water react to form a solution of poly (hydrocarbyl aluminium oxide) in the hydrocarbon solvent, and (3) after aging said solution, adding thereto a Group IVA, VA or VIA transition metal compound to complete the formation of the catalyst complex. A flow diagram of the process is provided. Exemplified catalysts are mixtures of poly (isobutyl aluminium oxide) and chromic 2-ethylhexanoate or chromium acetylacetonate.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB381267A GB1176692A (en) | 1967-01-25 | 1967-01-25 | Continuous Processes for the production of Ethylene Polymers and Catalysts suitable therefor |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB381267A GB1176692A (en) | 1967-01-25 | 1967-01-25 | Continuous Processes for the production of Ethylene Polymers and Catalysts suitable therefor |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1176692A true GB1176692A (en) | 1970-01-07 |
Family
ID=9765367
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB381267A Expired GB1176692A (en) | 1967-01-25 | 1967-01-25 | Continuous Processes for the production of Ethylene Polymers and Catalysts suitable therefor |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1176692A (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0237294A2 (en) * | 1986-03-07 | 1987-09-16 | Nippon Oil Co. Ltd. | Process for preparing ethylene polymers |
EP0257695A2 (en) * | 1986-08-15 | 1988-03-02 | Shell Internationale Researchmaatschappij B.V. | Process for preparing aluminoxanes |
EP0258924A2 (en) * | 1986-08-15 | 1988-03-09 | Shell Internationale Researchmaatschappij B.V. | Process for the preparation of aluminoxanes |
EP0273284A2 (en) * | 1986-12-18 | 1988-07-06 | Nippon Oil Co., Ltd. | Polyethylene composition |
EP0405221A2 (en) * | 1989-06-26 | 1991-01-02 | Ethyl Corporation | Alkylaluminoxane process |
EP0672671A1 (en) * | 1994-03-18 | 1995-09-20 | Witco GmbH | Process for producing alkyl-aluminoxane on inert carriers |
WO2014105614A1 (en) * | 2012-12-28 | 2014-07-03 | Univation Technologies, Llc | Methods of integrating aluminoxane production into catalyst production |
CN116023528A (en) * | 2021-10-26 | 2023-04-28 | 中国石油化工股份有限公司 | Method, device and use for preparing alkylaluminoxane for in situ cut-in olefin oligomerization and polymerization |
-
1967
- 1967-01-25 GB GB381267A patent/GB1176692A/en not_active Expired
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0237294A2 (en) * | 1986-03-07 | 1987-09-16 | Nippon Oil Co. Ltd. | Process for preparing ethylene polymers |
EP0237294A3 (en) * | 1986-03-07 | 1989-01-25 | Nippon Oil Co. Ltd. | Process for preparing ethylene polymers |
EP0258924A3 (en) * | 1986-08-15 | 1989-09-06 | Shell Internationale Researchmaatschappij B.V. | Process for the preparation of aluminoxanes |
EP0257695A2 (en) * | 1986-08-15 | 1988-03-02 | Shell Internationale Researchmaatschappij B.V. | Process for preparing aluminoxanes |
EP0258924A2 (en) * | 1986-08-15 | 1988-03-09 | Shell Internationale Researchmaatschappij B.V. | Process for the preparation of aluminoxanes |
EP0257695A3 (en) * | 1986-08-15 | 1989-09-06 | Shell Internationale Researchmaatschappij B.V. | Process for preparing aluminoxanes |
EP0273284A2 (en) * | 1986-12-18 | 1988-07-06 | Nippon Oil Co., Ltd. | Polyethylene composition |
EP0273284A3 (en) * | 1986-12-18 | 1989-01-25 | Nippon Oil Co., Ltd. | Polyethylene composition |
EP0405221A2 (en) * | 1989-06-26 | 1991-01-02 | Ethyl Corporation | Alkylaluminoxane process |
EP0405221A3 (en) * | 1989-06-26 | 1991-06-05 | Ethyl Corporation | Alkylaluminoxane process |
EP0672671A1 (en) * | 1994-03-18 | 1995-09-20 | Witco GmbH | Process for producing alkyl-aluminoxane on inert carriers |
WO2014105614A1 (en) * | 2012-12-28 | 2014-07-03 | Univation Technologies, Llc | Methods of integrating aluminoxane production into catalyst production |
CN104918947A (en) * | 2012-12-28 | 2015-09-16 | 尤尼威蒂恩技术有限责任公司 | Methods for integrating aluminoxane production into catalyst production |
US9650453B2 (en) | 2012-12-28 | 2017-05-16 | Univation Technologies, Llc | Methods of integrating aluminoxane production into catalyst production |
CN116023528A (en) * | 2021-10-26 | 2023-04-28 | 中国石油化工股份有限公司 | Method, device and use for preparing alkylaluminoxane for in situ cut-in olefin oligomerization and polymerization |
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