GB1171787A - Aqueous Lubricants Containing Siloxane Polyoxyalkylene Compositions. - Google Patents

Aqueous Lubricants Containing Siloxane Polyoxyalkylene Compositions.

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Publication number
GB1171787A
GB1171787A GB56151/66A GB5615166A GB1171787A GB 1171787 A GB1171787 A GB 1171787A GB 56151/66 A GB56151/66 A GB 56151/66A GB 5615166 A GB5615166 A GB 5615166A GB 1171787 A GB1171787 A GB 1171787A
Authority
GB
United Kingdom
Prior art keywords
weight
amino
alkali metal
siloxane
lubricant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB56151/66A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US227700A external-priority patent/US3234252A/en
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of GB1171787A publication Critical patent/GB1171787A/en
Expired legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0834—Compounds having one or more O-Si linkage
    • C07F7/0838—Compounds with one or more Si-O-Si sequences
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    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
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    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/041—Carbon; Graphite; Carbon black
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    • C10M2201/04—Elements
    • C10M2201/041—Carbon; Graphite; Carbon black
    • C10M2201/042—Carbon; Graphite; Carbon black halogenated, i.e. graphite fluoride
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    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/063—Peroxides
    • C—CHEMISTRY; METALLURGY
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    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/065—Sulfides; Selenides; Tellurides
    • C10M2201/066—Molybdenum sulfide
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    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C10M2201/082—Inorganic acids or salts thereof containing nitrogen
    • C10M2201/083—Inorganic acids or salts thereof containing nitrogen nitrites
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    • C10M2201/102—Silicates
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    • C10M2205/022—Ethene
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    • C10M2205/14—Synthetic waxes, e.g. polythene waxes
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  • Organic Chemistry (AREA)
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  • Oil, Petroleum & Natural Gas (AREA)
  • Silicon Polymers (AREA)
  • Lubricants (AREA)

Abstract

1,171,787. Lubricants. UNION CARBIDE CORP. 15 Dec., 1966 [15 Dec., 1965], No. 56151/66. Addition to 1,074,575. Heading C5F. A lubricant comprises (1) an aqueous base fluid which is water or a mixture of up to 2 parts by weight per one part by weight water of a lubricant which is (a) a silicon-free polyoxyalkylene compound; (b) a dialkyl ester of an aliphatic dicarboxylic acid; (c) a hydrocarbon lubricating oil and/or (d) a fatty acid ester of a polyhydric compound; (2) 0À0005-0À1 part by weight per one part by weight of base fluid of a siloxane/oxyalkylene copolymer having (i) at least one siloxane block containing at least two siloxane groups of formula where R is a monovalent hydrocarbon group which may or may not be substituted by halo, cyano, amino, amido, carbalkoxy, acyloxy, mercapto, or nitro groups, or a divalent hydrocarbon group, b is 1, 2 or 3 and the block has at least one divalent hydrocarbon R group and (ii) at least one polyoxyalkylene block containing at least two groups of formula -R<SP>1</SP>O-, where R<SP>1</SP> is alkylene, and (3) 0À001-0À1 part by weight per one part by weight of base fluid of an olefin polymer in emulsified form having a molecular weight of 1,500-25,000. Specified lubricants which may be added to the water base are di - (2 - ethylhexyl) sebacate and and fatty acid esters of glycerol, pentaerythritol and trimethylol ethane. Polyolefins specified are those derived from olefins having 2-12 carbon atoms and which may have at least one polar group for every four olefin molecules. Exhaustive lists of examples of copolymer (2) are given. The lubricant may contain many optional additives e.g. methanol, ethylene glycol, glycerol, silanes, graphite, talc, molybdenum disulphide, alkylamine salts of acid alkyl esters of phosphoric acids, amine salts of long chain aliphatic acids, neutral aryl phosphates, neutral alkylaryl phosphates, quinazarin, alizarin, dialkyl selenides, amino- and phenolic-antioxidants, hydroquinone monobenzyl ether, hydroquinone dimethyl ether, morpholine, alkali metal nitrites, alkali metal mercaptobenzothiazoles, disalicylalpropylenediamine, amino-organosilicon compounds, alkali metal salts of carboxyorganosiloxanes, alkenyl succinic acids and anhydrides, dialkyl acid phosphates, sorbitan mono-oleate, butyl stearate, butylnaphthenate and aluminium stearate.
GB56151/66A 1962-10-02 1966-12-15 Aqueous Lubricants Containing Siloxane Polyoxyalkylene Compositions. Expired GB1171787A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US227700A US3234252A (en) 1962-10-02 1962-10-02 Siloxane-polyoxyalkylene copolymers
US51410465A 1965-12-15 1965-12-15
US75168568A 1968-07-29 1968-07-29

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GB1171787A true GB1171787A (en) 1969-11-26

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GB56151/66A Expired GB1171787A (en) 1962-10-02 1966-12-15 Aqueous Lubricants Containing Siloxane Polyoxyalkylene Compositions.

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2116996A (en) * 1981-11-02 1983-10-05 Inoue Japax Res Electrical machining fluid and method utilizing the same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2116996A (en) * 1981-11-02 1983-10-05 Inoue Japax Res Electrical machining fluid and method utilizing the same

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DE1594652B1 (en) 1972-03-23

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