GB1169043A - Brighteners for Cyanide Zinc Electroplating Baths - Google Patents

Brighteners for Cyanide Zinc Electroplating Baths

Info

Publication number
GB1169043A
GB1169043A GB4179066A GB4179066A GB1169043A GB 1169043 A GB1169043 A GB 1169043A GB 4179066 A GB4179066 A GB 4179066A GB 4179066 A GB4179066 A GB 4179066A GB 1169043 A GB1169043 A GB 1169043A
Authority
GB
United Kingdom
Prior art keywords
radicals
monovalent
substituents
carbon atoms
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4179066A
Inventor
Robert Edward Harrover
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cowles Chemical Co
Original Assignee
Cowles Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US197598A priority Critical patent/US3274080A/en
Priority to DE19641271491 priority patent/DE1271491B/en
Application filed by Cowles Chemical Co filed Critical Cowles Chemical Co
Priority to GB4179066A priority patent/GB1169043A/en
Priority to NL6613192A priority patent/NL6613192A/xx
Priority to FR76782A priority patent/FR1493260A/en
Publication of GB1169043A publication Critical patent/GB1169043A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00—Electroplating: Baths therefor
    • C25D3/02—Electroplating: Baths therefor from solutions
    • C25D3/22—Electroplating: Baths therefor from solutions of zinc
    • C25D3/24—Electroplating: Baths therefor from solutions of zinc from cyanide baths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/66—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D233/86—Oxygen and sulfur atoms, e.g. thiohydantoin

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Electroplating And Plating Baths Therefor (AREA)

Abstract

1,169,043. Zinc electro-plating baths. COWLES CHEMICAL CO. Sept.19, 1966, No.41790/66. Heading C7B. An aqueous alkaline zinc cyanide plating solution contains zinc ions and at least one brightener having the formula where R is a monovalent or divalent substituted or unsubstituted hydrocarbon radical having 1-4 carbon atoms, substituents being selected from the group -NH 2 , -OH, and -COOR 1 , where R 1 is H, NH 4 or an alkali metal radical; M is NH 4 , CH 3 NH 3 , (CH 3 ) 2 NH 2 , Na, K, Ca, Zn, Mg, Cd, Ni, Fe, Co, Mo, Mn and n is equal to the valance of M. Examples are given of thiuram disulphides and thiocarbamates having the above formula. The electrolyte may also contain polyvinyl alcohol and/or a reaction product formed by reacting substantially equimolar quantities of at least one compound having the nucleus with a compound having the formula where R is a radical selected from hydrogen, monovalent and divalent saturated substituted and unsubstituted radicals having 1 to 4 carbon atoms in which the substituents may be -NH 2 , or -OH radicals, phenyl radicals, or monovalent or divalent substituted or unsubstituted alicyclic radicals containing 5 or 6 carbon atoms i the ring and in which the substituents may be -CH 3 , -NH 2 , or -OH radicals or amino phenyl radicals. Examples of substances (a) include 2-thiohydantoin and its 1- acetyl, 1- methyl, 5- furfural, 5- benzal, or 5-(2<SP>1</SP> hydroxylbenzal) derivatives; 2- thiobarbituric acid and its 1- acetyl, 1- benzoyl or 1, 5- diacetyl derivatives; 2- thiopyrrolidone -4; 3- thio -1, 2, 4- oxadiazolidinone-5 and the corresponding thiadiazolidinone and triazolidinone compounds; 2- thio -1, 3- diazolidinone -4; 2- thioperhydroazin -6- one and the corresponding 1, 4- diazinone compound Examples of substances (b) include ammonia, isopropylamine, ethanolamine, piperazine, aniline, p-aminophenyl -4- methylcyclohexylamine, phenylcyclohexanolamine and p-aminophenyl-3 -aminocyclopentylamine. E.g. the reaction product may be produced by the reaction of 2-thiohydantoin with ethanolamine.
GB4179066A 1962-05-25 1966-09-19 Brighteners for Cyanide Zinc Electroplating Baths Expired GB1169043A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
US197598A US3274080A (en) 1962-05-25 1962-05-25 Brighteners and process for cyanide zinc electrodeposition
DE19641271491 DE1271491B (en) 1964-05-05 1964-05-05 Galvanic alkaline zinc cyanide bath
GB4179066A GB1169043A (en) 1966-09-19 1966-09-19 Brighteners for Cyanide Zinc Electroplating Baths
NL6613192A NL6613192A (en) 1966-09-19 1966-09-19
FR76782A FR1493260A (en) 1966-09-19 1966-09-19 New shine

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB4179066A GB1169043A (en) 1966-09-19 1966-09-19 Brighteners for Cyanide Zinc Electroplating Baths
NL6613192A NL6613192A (en) 1966-09-19 1966-09-19

Publications (1)

Publication Number Publication Date
GB1169043A true GB1169043A (en) 1969-10-29

Family

ID=26264748

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4179066A Expired GB1169043A (en) 1962-05-25 1966-09-19 Brighteners for Cyanide Zinc Electroplating Baths

Country Status (2)

Country Link
GB (1) GB1169043A (en)
NL (1) NL6613192A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2155493A (en) * 1984-02-27 1985-09-25 Nippon Surface Treatment Chem Electroplating zinc-iron alloy from alkaline bath

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2155493A (en) * 1984-02-27 1985-09-25 Nippon Surface Treatment Chem Electroplating zinc-iron alloy from alkaline bath

Also Published As

Publication number Publication date
NL6613192A (en) 1968-03-20

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