GB1166014A - Preparation of Benzene - Google Patents

Preparation of Benzene

Info

Publication number
GB1166014A
GB1166014A GB1783668A GB1783668A GB1166014A GB 1166014 A GB1166014 A GB 1166014A GB 1783668 A GB1783668 A GB 1783668A GB 1783668 A GB1783668 A GB 1783668A GB 1166014 A GB1166014 A GB 1166014A
Authority
GB
United Kingdom
Prior art keywords
mixture
benzene
hydrogen
passing
reaction zone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1783668A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Texaco Development Corp
Original Assignee
Texaco Development Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Texaco Development Corp filed Critical Texaco Development Corp
Publication of GB1166014A publication Critical patent/GB1166014A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/08Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule
    • C07C4/12Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene
    • C07C4/14Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene splitting taking place at an aromatic-aliphatic bond
    • C07C4/16Thermal processes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/22Non-catalytic cracking in the presence of hydrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1,166,014. Benzene. TEXACO DEVELOPMENT CORP. 16 April, 1968 [5 May, 1967], No. 17836/68. Heading C5E. Benzene is produced by hydrodealkylating toluene, a xylene or ethylbenzene in a process comprising:- (a) passing the feed with hydrogen through a first heated reaction zone in which it attains a reaction initiating temperature of 1150- 1300‹ F.; (b) passing the mixture through a second heated reaction zone having a heat flux of 180-280 B.T.U./1b. mole/sec. applied thereto, the residence time being 2-1 seconds and the temperature of the mixture increasing to 1325-1425‹ F., and quenching the mixture with hydrogen to 1250-1350‹ F.; (c) passing the mixture through a third heated reaction zone having a heat flux of 250-350 B.T.U./1b. mole/sec., the residence time being 3À5-5À0 seconds, and the temperature being maintained at 1250-1425‹ F. by quenching with hydrogen; and (d) cooling the resulting mixture, and recovering benzene therefrom. The feed may contain recycled biphenyls, and the product may be clay treated before final fractionation.
GB1783668A 1967-05-05 1968-04-16 Preparation of Benzene Expired GB1166014A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US63635967A 1967-05-05 1967-05-05

Publications (1)

Publication Number Publication Date
GB1166014A true GB1166014A (en) 1969-10-01

Family

ID=24551550

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1783668A Expired GB1166014A (en) 1967-05-05 1968-04-16 Preparation of Benzene

Country Status (5)

Country Link
ES (1) ES353425A1 (en)
FR (1) FR1561017A (en)
GB (1) GB1166014A (en)
NL (1) NL6806349A (en)
SE (1) SE370385B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9068125B2 (en) 2009-03-11 2015-06-30 Thyssenkrupp Uhde Gmbh Process for the recovery of pure aromatics from hydrocarbon fractions containing aromatics

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9068125B2 (en) 2009-03-11 2015-06-30 Thyssenkrupp Uhde Gmbh Process for the recovery of pure aromatics from hydrocarbon fractions containing aromatics

Also Published As

Publication number Publication date
ES353425A1 (en) 1969-10-01
DE1768342B2 (en) 1976-11-18
SE370385B (en) 1974-10-14
FR1561017A (en) 1969-03-21
NL6806349A (en) 1968-11-06
DE1768342A1 (en) 1971-09-30

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee