GB1166014A - Preparation of Benzene - Google Patents
Preparation of BenzeneInfo
- Publication number
- GB1166014A GB1166014A GB1783668A GB1783668A GB1166014A GB 1166014 A GB1166014 A GB 1166014A GB 1783668 A GB1783668 A GB 1783668A GB 1783668 A GB1783668 A GB 1783668A GB 1166014 A GB1166014 A GB 1166014A
- Authority
- GB
- United Kingdom
- Prior art keywords
- mixture
- benzene
- hydrogen
- passing
- reaction zone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
- C07C4/08—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule
- C07C4/12—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene
- C07C4/14—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene splitting taking place at an aromatic-aliphatic bond
- C07C4/16—Thermal processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/22—Non-catalytic cracking in the presence of hydrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1,166,014. Benzene. TEXACO DEVELOPMENT CORP. 16 April, 1968 [5 May, 1967], No. 17836/68. Heading C5E. Benzene is produced by hydrodealkylating toluene, a xylene or ethylbenzene in a process comprising:- (a) passing the feed with hydrogen through a first heated reaction zone in which it attains a reaction initiating temperature of 1150- 1300‹ F.; (b) passing the mixture through a second heated reaction zone having a heat flux of 180-280 B.T.U./1b. mole/sec. applied thereto, the residence time being 2-1 seconds and the temperature of the mixture increasing to 1325-1425‹ F., and quenching the mixture with hydrogen to 1250-1350‹ F.; (c) passing the mixture through a third heated reaction zone having a heat flux of 250-350 B.T.U./1b. mole/sec., the residence time being 3À5-5À0 seconds, and the temperature being maintained at 1250-1425‹ F. by quenching with hydrogen; and (d) cooling the resulting mixture, and recovering benzene therefrom. The feed may contain recycled biphenyls, and the product may be clay treated before final fractionation.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US63635967A | 1967-05-05 | 1967-05-05 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1166014A true GB1166014A (en) | 1969-10-01 |
Family
ID=24551550
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1783668A Expired GB1166014A (en) | 1967-05-05 | 1968-04-16 | Preparation of Benzene |
Country Status (5)
Country | Link |
---|---|
ES (1) | ES353425A1 (en) |
FR (1) | FR1561017A (en) |
GB (1) | GB1166014A (en) |
NL (1) | NL6806349A (en) |
SE (1) | SE370385B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9068125B2 (en) | 2009-03-11 | 2015-06-30 | Thyssenkrupp Uhde Gmbh | Process for the recovery of pure aromatics from hydrocarbon fractions containing aromatics |
-
1968
- 1968-04-16 GB GB1783668A patent/GB1166014A/en not_active Expired
- 1968-05-02 ES ES353425A patent/ES353425A1/en not_active Expired
- 1968-05-03 SE SE601668A patent/SE370385B/xx unknown
- 1968-05-03 FR FR1561017D patent/FR1561017A/fr not_active Expired
- 1968-05-03 NL NL6806349A patent/NL6806349A/xx unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9068125B2 (en) | 2009-03-11 | 2015-06-30 | Thyssenkrupp Uhde Gmbh | Process for the recovery of pure aromatics from hydrocarbon fractions containing aromatics |
Also Published As
Publication number | Publication date |
---|---|
ES353425A1 (en) | 1969-10-01 |
DE1768342B2 (en) | 1976-11-18 |
SE370385B (en) | 1974-10-14 |
FR1561017A (en) | 1969-03-21 |
NL6806349A (en) | 1968-11-06 |
DE1768342A1 (en) | 1971-09-30 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |