GB1164687A - Disproportionation of Alkenes - Google Patents

Disproportionation of Alkenes

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Publication number
GB1164687A
GB1164687A GB27709/67A GB2770967A GB1164687A GB 1164687 A GB1164687 A GB 1164687A GB 27709/67 A GB27709/67 A GB 27709/67A GB 2770967 A GB2770967 A GB 2770967A GB 1164687 A GB1164687 A GB 1164687A
Authority
GB
United Kingdom
Prior art keywords
disproportionation
ethylene
compound
oxide
predominating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB27709/67A
Inventor
Robert Van Helden
Willem Frederik Engel
Henk Johan Alkema
Pieter Krijger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of GB1164687A publication Critical patent/GB1164687A/en
Expired legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8872—Alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/36—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/30—Tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32—Manganese, technetium or rhenium
    • C07C2523/36—Rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/04—Sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/04—Sulfides
    • C07C2527/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/04—Sulfides
    • C07C2527/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • C07C2527/051—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/20—Carbonyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1,164,687. Disproportionation. SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ N.V. 15 June, 1967 [17 June, 1966], No. 27709/67. Heading C5E. The disproportionation of acyclic alkenes is carried out in the presence of a supported disproportionation catalyst which has been modified by the presence of a compound of potassium, rubidium or caesium (particularly an oxide or hydroxide), the support comprising at least 75 wt. per cent alumina. The catalyst suitably comprises an oxide, sulphide, #-alkenyl or carbonyl compound of molybdenum, tungsten or rhenium, and may be promoted by a compound of Co, Ni, V, Ti, Fe, Cr, Zr, Ta or Bi, particularly cobalt oxide. The support may be 100% Al 2 O 3 , or may contain up to 25% of thoria, magnesia or silica. The process may be carried out in the gas or liquid phase, and in the presence of a gaseous or liquid diluent. Water, oxygen, alkynes and dienes are preferably absent. Examples describe the disproportionation of propylene to ethylene and butenes; of butene-1 to mainly ethylene and hexene with some propylene and pentene; of n-octane-1 to a C 2-14 olefin mixture with ethylene and tetradecene predominating; and of n-dodecene to a C 2-22 olefin mixture with ethylene and C 22 olefin predominating.
GB27709/67A 1966-06-17 1967-06-15 Disproportionation of Alkenes Expired GB1164687A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL6608427A NL6608427A (en) 1966-06-17 1966-06-17

Publications (1)

Publication Number Publication Date
GB1164687A true GB1164687A (en) 1969-09-17

Family

ID=19796903

Family Applications (1)

Application Number Title Priority Date Filing Date
GB27709/67A Expired GB1164687A (en) 1966-06-17 1967-06-15 Disproportionation of Alkenes

Country Status (4)

Country Link
BE (1) BE699976A (en)
DE (1) DE1618914C3 (en)
GB (1) GB1164687A (en)
NL (2) NL6608427A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4547617A (en) * 1984-02-16 1985-10-15 Phillips Petroleum Company Olefin conversion
US4605810A (en) * 1985-08-09 1986-08-12 Phillips Petroleum Company Allene or alkyne treatment of olefin conversion catalysts
US4609769A (en) * 1984-02-15 1986-09-02 Phillips Petroleum Company Olefin conversion
WO2020020730A1 (en) 2018-07-25 2020-01-30 IFP Energies Nouvelles Method for olefin metathesis using a catalyst containing silicon, molybdenum and an alkaline element
FR3084362A1 (en) 2018-07-25 2020-01-31 IFP Energies Nouvelles PROCESS FOR THE METATHESIS OF OLEFINS USING A CATALYST CONTAINING SILICON, MOLYBDENE AND AN ALKALINE ELEMENT
FR3084361A1 (en) 2018-07-25 2020-01-31 IFP Energies Nouvelles PROCESS FOR THE METATHESIS OF OLEFINS USING A CATALYST CONTAINING SILICON, MOLYBDENE AND SULFUR
FR3103192A1 (en) 2019-11-15 2021-05-21 IFP Energies Nouvelles OLEFINS METATHESIS PROCESS USING A HIGH ALKALINE CATALYST CONTAINING SILICON, MOLYBDENE

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4609769A (en) * 1984-02-15 1986-09-02 Phillips Petroleum Company Olefin conversion
US4547617A (en) * 1984-02-16 1985-10-15 Phillips Petroleum Company Olefin conversion
US4605810A (en) * 1985-08-09 1986-08-12 Phillips Petroleum Company Allene or alkyne treatment of olefin conversion catalysts
WO2020020730A1 (en) 2018-07-25 2020-01-30 IFP Energies Nouvelles Method for olefin metathesis using a catalyst containing silicon, molybdenum and an alkaline element
FR3084362A1 (en) 2018-07-25 2020-01-31 IFP Energies Nouvelles PROCESS FOR THE METATHESIS OF OLEFINS USING A CATALYST CONTAINING SILICON, MOLYBDENE AND AN ALKALINE ELEMENT
FR3084361A1 (en) 2018-07-25 2020-01-31 IFP Energies Nouvelles PROCESS FOR THE METATHESIS OF OLEFINS USING A CATALYST CONTAINING SILICON, MOLYBDENE AND SULFUR
FR3103192A1 (en) 2019-11-15 2021-05-21 IFP Energies Nouvelles OLEFINS METATHESIS PROCESS USING A HIGH ALKALINE CATALYST CONTAINING SILICON, MOLYBDENE

Also Published As

Publication number Publication date
DE1618914A1 (en) 1971-03-18
NL137809C (en) 1900-01-01
DE1618914C3 (en) 1975-02-06
DE1618914B2 (en) 1974-06-20
BE699976A (en) 1967-12-15
NL6608427A (en) 1967-12-18

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee