GB1161971A - Improvement in the manufacture of Alcohols by Oxidation of Hydrocarbons - Google Patents

Improvement in the manufacture of Alcohols by Oxidation of Hydrocarbons

Info

Publication number
GB1161971A
GB1161971A GB9483/68A GB948368A GB1161971A GB 1161971 A GB1161971 A GB 1161971A GB 9483/68 A GB9483/68 A GB 9483/68A GB 948368 A GB948368 A GB 948368A GB 1161971 A GB1161971 A GB 1161971A
Authority
GB
United Kingdom
Prior art keywords
hydrocarbons
alcohols
parts
hydrocarbon
oxidation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB9483/68A
Inventor
Christian Busson
Jacob Alagy
Bernard Cha
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR96705A external-priority patent/FR1512800A/en
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Publication of GB1161971A publication Critical patent/GB1161971A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C07C29/52—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only in the presence of mineral boron compounds with, when necessary, hydrolysis of the intermediate formed
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/08—Systems containing only non-condensed rings with a five-membered ring the ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1,161,971. Alcohols. INSTITUT FRANCAIS DU PETROLE DES CARBURANTS ET LUBRIFIANTS. 27 Feb., 1968 [27 Feb., 1967; 31 March, 1967], No. 9483/68. Heading C2C. Saturated unbranched hydrocarbons containing from 5 to 8 carbon atoms per molecule are converted to the corresponding alcohols of the same number of carbon atoms by contacting the hydrocarbons in the liquid phase with a gas containing molecular oxygen, in the presence of a boron compound and subsequently hydrolysing the reaction product, the conversion being conducted in the presence of from 10 to 20,000 parts by weight of saturated branched hydrocarbon per million parts by weight of the saturated unbranched hydrocarbon subjected to the conversion. In addition to the branched hydrocarbon, 2 to 20,000 parts per million of an aromatic hydrocarbon may also be present. In the examples cyclic branched hydrocarbons, e.g. methylcyclopentane and methylcyclohexane are used. Cyclohexanone is a further oxidation product in the oxidation of cyclohexane to cyclohexanol.
GB9483/68A 1967-02-27 1968-02-27 Improvement in the manufacture of Alcohols by Oxidation of Hydrocarbons Expired GB1161971A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR96705A FR1512800A (en) 1967-02-27 1967-02-27 Improvement in the manufacture of cyclohexanol by oxidation of cyclohexane
FR101157A FR92428E (en) 1967-02-27 1967-03-31 Improvement in the manufacture of cyclohexanol by oxidation of cyclohexane

Publications (1)

Publication Number Publication Date
GB1161971A true GB1161971A (en) 1969-08-20

Family

ID=26174809

Family Applications (1)

Application Number Title Priority Date Filing Date
GB9483/68A Expired GB1161971A (en) 1967-02-27 1968-02-27 Improvement in the manufacture of Alcohols by Oxidation of Hydrocarbons

Country Status (5)

Country Link
AT (1) AT283304B (en)
DE (1) DE1668315A1 (en)
FR (1) FR92428E (en)
GB (1) GB1161971A (en)
NL (1) NL6802215A (en)

Also Published As

Publication number Publication date
DE1668315A1 (en) 1971-09-16
AT283304B (en) 1970-08-10
FR92428E (en) 1968-11-08
NL6802215A (en) 1968-08-28

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Legal Events

Date Code Title Description
414F Notice of opposition given (sect. 14/1949)
414E Application relinquished (sect. 14/1949)
CSNS Application of which complete specification have been accepted and published, but patent is not sealed