GB1160021A - Resin-Impregnated Glass Fiber - Google Patents
Resin-Impregnated Glass FiberInfo
- Publication number
- GB1160021A GB1160021A GB2143/67A GB214367A GB1160021A GB 1160021 A GB1160021 A GB 1160021A GB 2143/67 A GB2143/67 A GB 2143/67A GB 214367 A GB214367 A GB 214367A GB 1160021 A GB1160021 A GB 1160021A
- Authority
- GB
- United Kingdom
- Prior art keywords
- resin
- impregnated
- fibreglass
- composition
- dibasic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003365 glass fiber Substances 0.000 title abstract 2
- 239000011152 fibreglass Substances 0.000 abstract 5
- 229920005989 resin Polymers 0.000 abstract 4
- 239000011347 resin Substances 0.000 abstract 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 abstract 3
- 239000002253 acid Substances 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- 239000003381 stabilizer Substances 0.000 abstract 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- 229920000180 alkyd Polymers 0.000 abstract 2
- 150000008064 anhydrides Chemical class 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 239000004744 fabric Substances 0.000 abstract 2
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 2
- 206010073306 Exposure to radiation Diseases 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000004698 Polyethylene Substances 0.000 abstract 1
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 150000002009 diols Chemical class 0.000 abstract 1
- 230000032050 esterification Effects 0.000 abstract 1
- 238000005886 esterification reaction Methods 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000000864 peroxy group Chemical group O(O*)* 0.000 abstract 1
- -1 polyethylene Polymers 0.000 abstract 1
- 229920000573 polyethylene Polymers 0.000 abstract 1
- 239000002952 polymeric resin Substances 0.000 abstract 1
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 1
- 150000003254 radicals Chemical class 0.000 abstract 1
- 239000011342 resin composition Substances 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 229910000077 silane Inorganic materials 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 229920003002 synthetic resin Polymers 0.000 abstract 1
- 238000004804 winding Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C03C25/323—Polyesters, e.g. alkyd resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/003—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts characterised by the matrix material, e.g. material composition or physical properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
- C08J5/244—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using glass fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2309/00—Use of inorganic materials not provided for in groups B29K2303/00 - B29K2307/00, as reinforcement
- B29K2309/08—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/06—Unsaturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/08—Polyesters modified with higher fatty oils or their acids, or with resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
Abstract
1,160,021. Coating. FERRO CORP. 16 Jan., 1967 [19 Jan., 1966], No. 2143/67. Heading B2E. [Also in Divisions B5, B8, C3 and Dl] A fibreglass composition comprises fibreglass impregnated with 15-40% based on the combined weight of resin and fibreglass of a resin composition which contains (1) 50-95% of (a) polymeric polyallyl ester or (b) an unsaturated alkyd resin, (2) 50-5% of a polyallyl ester and (3) 0.1 - 10% of a stabiliser. The alkyd resin must be the esterification product of a diol with an equimolar quantity of a dibasic acid component which comprises 5-95% of an unsaturated dibasic acid or anhydride thereof and 95 - 5% of a saturated dibasic acid or anhydride thereof. The stabiliser is defined as being a compound containing straight chain carbon atoms each of which is attached by at least one valence to an oxygen atom with at least one of the carbon atoms being attached by two valencies to its oxygen atom. The valencies of the remaining oxygens are satisfied by hydrogen. Examples of stabilisers are acyloins and compounds of formula R.(CO) x R', X being 2 or more. The polymer resin can have a m.w. of 1,500-20,000. The composition can contain 1-10% of a specified peroxy - or azo - compound to act as a freeradical - generating catalyst. The catalyst can contain cobalt naphthaneate. The fibreglass can be in the form of cloth, roving, mat or filaments having diameters of 0.00006-0.0006 inch. The fibres can be modified by a silane. The fibre glass can be impregnated with a solution containing 20-80% resin and a volatile solvent, e.g. acetone or methyl ethyl ketone. The impregnating glass fibre composition is relatively non-hardening and can be wound up with a polyethylene sheet interleaf or impregnated filaments can be formed into a wound article by simultaneously winding into a mandrel and curing with U.V. light. The resin can be cured by exposure to radiation, e.g. from Co - 60, atomic piles, high power lined accelerators or U.V. light, e.g. of wavelength 120 - 320 m. The cure can be effected under pressure. A laminate can be formed assembling layers of a procured resin - impregnated glass cloth within a flexible polyvinyl alcohol bag, withdrawing the air to 50 mm Hg and exposing to U.V. light. The laminate can be cured in an oven.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US52155566A | 1966-01-19 | 1966-01-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1160021A true GB1160021A (en) | 1969-07-30 |
Family
ID=24077191
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2143/67A Expired GB1160021A (en) | 1966-01-19 | 1967-01-16 | Resin-Impregnated Glass Fiber |
Country Status (9)
| Country | Link |
|---|---|
| AT (2) | AT285946B (en) |
| BE (1) | BE692873A (en) |
| CH (1) | CH529078A (en) |
| DE (1) | DE1619039A1 (en) |
| FR (1) | FR1508664A (en) |
| GB (1) | GB1160021A (en) |
| LU (1) | LU52839A1 (en) |
| NL (1) | NL6700853A (en) |
| SE (1) | SE313639B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2421619A1 (en) * | 1974-05-04 | 1975-11-13 | Stiebel Eltron Gmbh & Co Kg | Glass fibre reinforced wound pressure container - made by progressive ultraviolet hardening from inside outwards during winding |
| DE3743485A1 (en) * | 1987-12-22 | 1989-07-13 | Mtu Muenchen Gmbh | METHOD FOR PRODUCING A SPACIOUSLY WINDED ROTOR BLADE |
| DE4022235A1 (en) * | 1990-07-12 | 1992-01-16 | Herberts Gmbh | METHOD FOR FIXING WRAPPED GOODS AND USE OF RADICALLY POLYMERIZABLE MEASURES HERE |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2441593B2 (en) * | 1974-08-30 | 1981-03-12 | Chemische Werke Hüls AG, 4370 Marl | Molding or coating compounds |
| CH632522A5 (en) * | 1977-10-26 | 1982-10-15 | Herbert Schreiber | Photocurable prepreg |
| PT71757B (en) * | 1979-09-11 | 1981-07-09 | Scott Bader Co | Preimpregnated materials and methods of making and using them |
| DE3445870A1 (en) * | 1984-12-15 | 1986-06-26 | Goetze Ag, 5093 Burscheid | IMPREGNATED FLAT GASKET, IN PARTICULAR CYLINDER HEAD GASKET FOR COMBUSTION ENGINES, AND THEIR PRODUCTION PROCESS |
| DE4022234A1 (en) * | 1990-07-12 | 1992-01-16 | Herberts Gmbh | METHOD FOR THE PRODUCTION OF PROTECTIVE, AUXILIARY AND INSULATING MATERIALS ON A FIBER BASE, FOR ELECTRICAL PURPOSES AND OPTICAL LADDER USING IMPREGNABLE DIMENSIONS THAT ARE CURRENT BY ENERGY RADIATION |
-
1967
- 1967-01-10 DE DE19671619039 patent/DE1619039A1/en active Pending
- 1967-01-16 GB GB2143/67A patent/GB1160021A/en not_active Expired
- 1967-01-16 AT AT41667A patent/AT285946B/en not_active IP Right Cessation
- 1967-01-16 AT AT1027668A patent/AT309087B/en not_active IP Right Cessation
- 1967-01-17 SE SE689/67A patent/SE313639B/xx unknown
- 1967-01-19 FR FR91826A patent/FR1508664A/en not_active Expired
- 1967-01-19 BE BE692873D patent/BE692873A/xx unknown
- 1967-01-19 CH CH78767A patent/CH529078A/en not_active IP Right Cessation
- 1967-01-19 LU LU52839D patent/LU52839A1/xx unknown
- 1967-01-19 NL NL6700853A patent/NL6700853A/xx unknown
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2421619A1 (en) * | 1974-05-04 | 1975-11-13 | Stiebel Eltron Gmbh & Co Kg | Glass fibre reinforced wound pressure container - made by progressive ultraviolet hardening from inside outwards during winding |
| DE3743485A1 (en) * | 1987-12-22 | 1989-07-13 | Mtu Muenchen Gmbh | METHOD FOR PRODUCING A SPACIOUSLY WINDED ROTOR BLADE |
| GB2213793A (en) * | 1987-12-22 | 1989-08-23 | Mtu Muenchen Gmbh | Winding airfoil |
| DE4022235A1 (en) * | 1990-07-12 | 1992-01-16 | Herberts Gmbh | METHOD FOR FIXING WRAPPED GOODS AND USE OF RADICALLY POLYMERIZABLE MEASURES HERE |
| WO1992001015A1 (en) * | 1990-07-12 | 1992-01-23 | Herberts Gesellschaft mit beschränkter Haftung | Process and device for fixing wound-up materials and use therefor of radically polymerizable compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1619039A1 (en) | 1969-09-18 |
| SE313639B (en) | 1969-08-18 |
| AT285946B (en) | 1970-11-25 |
| NL6700853A (en) | 1967-07-20 |
| FR1508664A (en) | 1968-01-05 |
| LU52839A1 (en) | 1967-03-20 |
| BE692873A (en) | 1967-07-03 |
| AT309087B (en) | 1973-08-10 |
| CH529078A (en) | 1972-10-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |