GB1144390A - Production of aluminium trialkoxide and aliphatic alcohols - Google Patents

Production of aluminium trialkoxide and aliphatic alcohols

Info

Publication number
GB1144390A
GB1144390A GB37953/67A GB3795367A GB1144390A GB 1144390 A GB1144390 A GB 1144390A GB 37953/67 A GB37953/67 A GB 37953/67A GB 3795367 A GB3795367 A GB 3795367A GB 1144390 A GB1144390 A GB 1144390A
Authority
GB
United Kingdom
Prior art keywords
aluminium
alcohols
isopropanol
aliphatic alcohols
oxidation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB37953/67A
Inventor
Allan Jay Lundeen
James Edwim Yates
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ConocoPhillips Co
Original Assignee
Continental Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Continental Oil Co filed Critical Continental Oil Co
Publication of GB1144390A publication Critical patent/GB1144390A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C07C29/54—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only starting from compounds containing carbon-to-metal bonds and followed by conversion of the -O- metal to -OH groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1,144,390. Preparation of aluminium trialkoxides and alcohols. CONTINENTAL OIL CO. 17 Aug., 1967 [14 Nov., 1966], No. 37953/67. Heading C2C. Aluminium trialkoxides having 2-30 carbons in each alkyl group, and primary aliphatic alcohols, are prepared by partially oxidizing trialkylaluminiums with an oxygen containing gas, adding isopropanol to the partially oxidized product, completing the oxidation to give aluminium alkoxides, removing acetone and excess isopropanol from the reaction mixture, and, if required, hydrolysing the aluminium alkoxides to alcohols which are then recovered, the alcohols being prepared from trialkyl aluminiums having at least one primary alkyl group linked to the aluminium. The isopropanol is preferably added when the oxidation is from 70 to approaching 100% complete, in a proportion of 0À5-20% of the initial weight of alkyl aluminium. Reference has been directed by the Comptroller to Specification 943,340.
GB37953/67A 1966-11-14 1967-08-17 Production of aluminium trialkoxide and aliphatic alcohols Expired GB1144390A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US59369866A 1966-11-14 1966-11-14

Publications (1)

Publication Number Publication Date
GB1144390A true GB1144390A (en) 1969-03-05

Family

ID=24375770

Family Applications (1)

Application Number Title Priority Date Filing Date
GB37953/67A Expired GB1144390A (en) 1966-11-14 1967-08-17 Production of aluminium trialkoxide and aliphatic alcohols

Country Status (5)

Country Link
US (1) US3450735A (en)
BE (1) BE719962A (en)
DE (1) DE1643820A1 (en)
GB (1) GB1144390A (en)
NL (1) NL6713035A (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3547969A (en) * 1968-02-05 1970-12-15 Continental Oil Co Catalytic hydrogenation of oxidized aluminum trialkyls
US3547968A (en) * 1968-02-05 1970-12-15 Continental Oil Co Catalytic hydrogenation of oxidized aluminum trialkyls
US3935285A (en) * 1968-12-27 1976-01-27 Ruhrchemie Ag Recovery of alcohols from esters formed during an oxo-synthesis
US3655520A (en) * 1969-03-06 1972-04-11 Ethyl Corp Distillation of olefins with alkanol addition to prevent degradation
US3855320A (en) * 1973-08-02 1974-12-17 Continental Oil Co Purification of ziegler alcohols
US4596881A (en) * 1984-10-01 1986-06-24 Stauffer Chemical Company Stabilized liquid aluminum alkoxides and process
US4744974A (en) * 1986-09-23 1988-05-17 Vista Chemical Company Process for production of alumina
FR2732682B1 (en) * 1995-04-07 1997-06-20 Enichem Polymeres France LONG-CHAIN DIALKYLMAGNESIUM, PROCESS FOR THE PREPARATION THEREOF AND ITS APPLICATIONS

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3017438A (en) * 1962-01-16 Storage
NL131937C (en) * 1960-07-07 1900-01-01
US3257468A (en) * 1965-02-05 1966-06-21 Continental Oil Co Production of aliphatic alcohols

Also Published As

Publication number Publication date
NL6713035A (en) 1968-05-15
US3450735A (en) 1969-06-17
DE1643820A1 (en) 1971-08-19
BE719962A (en) 1969-02-03

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