GB1139100A - Ethylenically unsaturated polymers - Google Patents

Ethylenically unsaturated polymers

Info

Publication number
GB1139100A
GB1139100A GB2270166A GB2270166A GB1139100A GB 1139100 A GB1139100 A GB 1139100A GB 2270166 A GB2270166 A GB 2270166A GB 2270166 A GB2270166 A GB 2270166A GB 1139100 A GB1139100 A GB 1139100A
Authority
GB
United Kingdom
Prior art keywords
acid
ethylenically unsaturated
polyester
copolymerized
fumaric
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2270166A
Inventor
Frank Fekete
William Joseph Plant
Patrick Joseph Keenan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HH Robertson Co
Original Assignee
HH Robertson Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HH Robertson Co filed Critical HH Robertson Co
Priority to GB2270166A priority Critical patent/GB1139100A/en
Publication of GB1139100A publication Critical patent/GB1139100A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • C08G63/56—Polyesters derived from ester-forming derivatives of polycarboxylic acids or of polyhydroxy compounds other than from esters thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/20—Esters of polyhydric alcohols or polyhydric phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/42—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
    • C08G59/4292—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof together with monocarboxylic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

1,139,100. Epoxy resin esters. H. H. ROBERTSON CO. 20 May, 1966, No. 22701/66. Headings C3B and C3P. A polymerizable polyhydroxy polyester having ethylenically unsaturated terminal groups and substantially free from unreacted epoxy groups is prepared by reacting : (a) one mol. of a diepoxy material having no substituent capable of reacting with -COOH other than hydroxyl; (b) 0À5 to 0À9 moles of a dicarboxylic acid; and (c) 1À0 to 0À2 moles of an unsaturated acid selected from acrylic acid, methacrylic acid, crotonic acid or a half-ester of fumaric or maleic acid, until substantially all the epoxy groups disappear. The diepoxide may be a diglycidyl ether of an alkane diol or a dihydric phenol, especially bisphenol A. The dicarboxylic acid may be phthalic, isophthalic, terephthalic, fumaric, maleic, adipic, succinic acid or the dimer acid of naturally occurring fatty acids. The unsaturated polyester of the invention may be copolymerized with a polymerizable ethylenically unsaturated monomer, e.g. styrene, vinyl toluene, divinyl benzene, acrylic acid, methacrylic acid ethyl or methyl (meth-)acrylate or mixtures thereof. In an example a polyester prepared from bisphenol A diglycidyl ether, crotonic acid and phthalic acid is copolymerized with an equal weight of 2-hydroxy-3-acryloxypropyl methacrylate.
GB2270166A 1966-05-20 1966-05-20 Ethylenically unsaturated polymers Expired GB1139100A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2270166A GB1139100A (en) 1966-05-20 1966-05-20 Ethylenically unsaturated polymers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2270166A GB1139100A (en) 1966-05-20 1966-05-20 Ethylenically unsaturated polymers

Publications (1)

Publication Number Publication Date
GB1139100A true GB1139100A (en) 1969-01-08

Family

ID=10183710

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2270166A Expired GB1139100A (en) 1966-05-20 1966-05-20 Ethylenically unsaturated polymers

Country Status (1)

Country Link
GB (1) GB1139100A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4440802A (en) * 1982-04-03 1984-04-03 Ciba-Geigy Corporation Preparation of prepregs from cellulosic fibers using water-borne resin compositions
EP0538923A2 (en) * 1991-10-03 1993-04-28 Dsm N.V. Process for the preparation of a thermosetting elongated object
WO2003064494A1 (en) * 2002-02-01 2003-08-07 Cook Composites And Polymers Company Inc. Low voc vinylester resin and applications

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4440802A (en) * 1982-04-03 1984-04-03 Ciba-Geigy Corporation Preparation of prepregs from cellulosic fibers using water-borne resin compositions
EP0538923A2 (en) * 1991-10-03 1993-04-28 Dsm N.V. Process for the preparation of a thermosetting elongated object
EP0538923A3 (en) * 1991-10-03 1993-06-16 Dsm N.V. Process for the preparation of a thermosetting elongated object
BE1005433A4 (en) * 1991-10-03 1993-07-20 Dsm Nv Process for making a thermosetting fiber.
WO2003064494A1 (en) * 2002-02-01 2003-08-07 Cook Composites And Polymers Company Inc. Low voc vinylester resin and applications
US6900276B2 (en) 2002-02-01 2005-05-31 Cook Composites & Polymers Co. Low VOC vinylester resin and applications

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