GB1137581A - Fibre-forming polyamides - Google Patents

Fibre-forming polyamides

Info

Publication number
GB1137581A
GB1137581A GB771766A GB771766A GB1137581A GB 1137581 A GB1137581 A GB 1137581A GB 771766 A GB771766 A GB 771766A GB 771766 A GB771766 A GB 771766A GB 1137581 A GB1137581 A GB 1137581A
Authority
GB
United Kingdom
Prior art keywords
diamine
salt
hydrogen halide
acids
aliphatic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB771766A
Inventor
Harold George Burrows
Stephen John Hepworth
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB771766A priority Critical patent/GB1137581A/en
Priority to NL6702336A priority patent/NL6702336A/xx
Priority to FR96083A priority patent/FR1522298A/en
Publication of GB1137581A publication Critical patent/GB1137581A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/26Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyamides (AREA)

Abstract

1,137,581. Polyamide production. IMPERIAL CHEMICAL INDUSTRIES Ltd. 23 Dec., 1966 [22 Feb., 1966], No. 7717/66. Heading C3R. [Also in Division D1] Polyamides of high M.W. and increased affinity for dyes are produced by interacting equimolar quantities of a diamine A and a dicarboxylic acid or a salt thereof in the presence of 0À1-10 mole per cent of a salt of an aliphatic diamine B and a hydrogen halide. The diamine A may be of formula where m = 2-12, e.g. hexamethylene diamine. The carboxyl groups of the dicarboxylic acid are separated by at least 2 carbon atoms. Acids specified include aliphatic acids, e.g. adipic acid, and iso- and terephthalic acids. The aliphatic diamine B may be one having 2-18 carbon atoms between the amino groups, e.g. hexamethylene diamine. Diamines A and B may be the same. Hydrogen halides specified are HCl, HBr and HI. The salt may contain 1 or 2 moles of hydrogen halide per mole of diamine. It may be added at any stage during the reaction, but preferably at the beginning, or may be prepared in situ from the diamine and an aqueous solution of the hydrogen halide. The reaction mixture may also contain TiO 2 and N,N<SP>1</SP>-bis-(3-aminopropyl). piperazine as a dyeing assistant. The reaction temperature may be 200-400‹ C. The hydrogen halide salt may be washed from the polymer when the latter is in chips or later when it has been made into fibres.
GB771766A 1966-02-22 1966-02-22 Fibre-forming polyamides Expired GB1137581A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB771766A GB1137581A (en) 1966-02-22 1966-02-22 Fibre-forming polyamides
NL6702336A NL6702336A (en) 1966-02-22 1967-02-16
FR96083A FR1522298A (en) 1966-02-22 1967-02-22 Process for the production of fibrogenic polyamides

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB771766A GB1137581A (en) 1966-02-22 1966-02-22 Fibre-forming polyamides

Publications (1)

Publication Number Publication Date
GB1137581A true GB1137581A (en) 1968-12-27

Family

ID=9838406

Family Applications (1)

Application Number Title Priority Date Filing Date
GB771766A Expired GB1137581A (en) 1966-02-22 1966-02-22 Fibre-forming polyamides

Country Status (2)

Country Link
GB (1) GB1137581A (en)
NL (1) NL6702336A (en)

Also Published As

Publication number Publication date
NL6702336A (en) 1967-08-23

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