GB1132979A - A method of producing an ammonium salt and iron oxide from a solution of ferrous salt - Google Patents
A method of producing an ammonium salt and iron oxide from a solution of ferrous saltInfo
- Publication number
- GB1132979A GB1132979A GB5083065A GB5083065A GB1132979A GB 1132979 A GB1132979 A GB 1132979A GB 5083065 A GB5083065 A GB 5083065A GB 5083065 A GB5083065 A GB 5083065A GB 1132979 A GB1132979 A GB 1132979A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ferrous
- aqueous solution
- iron
- slurry
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 title abstract 6
- 150000003863 ammonium salts Chemical class 0.000 title abstract 5
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 title abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 5
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 abstract 4
- 239000007864 aqueous solution Substances 0.000 abstract 4
- 239000002002 slurry Substances 0.000 abstract 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 3
- 238000006386 neutralization reaction Methods 0.000 abstract 3
- 230000001590 oxidative effect Effects 0.000 abstract 3
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- 229910021529 ammonia Inorganic materials 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 229940056319 ferrosoferric oxide Drugs 0.000 abstract 2
- 239000007789 gas Substances 0.000 abstract 2
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 abstract 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 abstract 2
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 abstract 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 229910001448 ferrous ion Inorganic materials 0.000 abstract 1
- 239000000706 filtrate Substances 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- 239000011259 mixed solution Substances 0.000 abstract 1
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- PXXKQOPKNFECSZ-UHFFFAOYSA-N platinum rhodium Chemical compound [Rh].[Pt] PXXKQOPKNFECSZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000012266 salt solution Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 235000010288 sodium nitrite Nutrition 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 235000011149 sulphuric acid Nutrition 0.000 abstract 1
- 239000001117 sulphuric acid Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/24—Sulfates of ammonium
- C01C1/242—Preparation from ammonia and sulfuric acid or sulfur trioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
- C01G49/02—Oxides; Hydroxides
- C01G49/08—Ferroso-ferric oxide [Fe3O4]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Compounds Of Iron (AREA)
Abstract
1,132,979. Iron oxide; ammonium salts. KAWASKI STEEL CORP., and MEIWA CHEMICAL ENG. CO. Ltd. 30 Nov., 1965, No. 50830/65. Heading C1A. Ammonium salts (e.g. sulphate and chloride) and iron oxide (Fe 3 O 4 ) are produced by oxidizing, using air or oxygen, and NO 2 gas as a catalyst, an aqueous solution of a ferrous salt (e.g. sulphate or chloride) containing a free acid (e.g. H 2 SO 4 or HCl) in a quantity corresponding to at least a half mol number of ferrous ions, to oxidize the ferrous iron to ferric iron, mixing the oxidized aqueous solution with a further quantity of the unoxidized ferrous salt starting solution to provide a mol ratio of ferrous salts to ferric salts of 1: 4-2: 3 respectively, neutralizing the mixed aqueous solution with ammonia gas to give a slurry containing ferroso-ferric oxide and an ammonium salt (e.g. sulphate or chloride) and then separating ferroso-ferric oxide from the ammonium salt solution by filtering the neutralized slurry and crystallizing from the filtrate. The nitrogen dioxide gas, preferably present in a mol ratio of at least <SP>1</SP>/ 30 th the amount of ferrous iron, may be manufactured from ammonia and air using a platinum or platinum-rhodium catalyst or by reacting sodium nitrite with sulphuric acid. Excess N0 2 from the oxidizing step together with nitrogen, unreacted oxygen and moisture from the oxidizing step may be absorbed into the aqueous solution before entering the oxidizer. The pH of the slurry is preferably adjusted to more than 7.0 in the neutralization step which may average more than two hours. Ammonia and steam produced in the neutralization step may be absorbed into the mixed solution before it enters the neutralizer. The slurry may be agitated for more than 30 minutes after neutralization.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB5083065A GB1132979A (en) | 1965-11-30 | 1965-11-30 | A method of producing an ammonium salt and iron oxide from a solution of ferrous salt |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB5083065A GB1132979A (en) | 1965-11-30 | 1965-11-30 | A method of producing an ammonium salt and iron oxide from a solution of ferrous salt |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1132979A true GB1132979A (en) | 1968-11-06 |
Family
ID=10457545
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5083065A Expired GB1132979A (en) | 1965-11-30 | 1965-11-30 | A method of producing an ammonium salt and iron oxide from a solution of ferrous salt |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1132979A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5128078B1 (en) * | 1971-06-28 | 1976-08-17 |
-
1965
- 1965-11-30 GB GB5083065A patent/GB1132979A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5128078B1 (en) * | 1971-06-28 | 1976-08-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB1531758A (en) | Gas desulphurization | |
| GB1389730A (en) | Method of treatment of gas containing sulphur dioxide | |
| US4364871A (en) | Process for making aminopolycarboxylic acid chelates of iron | |
| GB1135552A (en) | Process for the preparation of white iron phosphate | |
| GB1492068A (en) | Method for removing sulphur dioxide from an exhaust gas | |
| Nakayama | Hydrates of organic compounds. VII. The effect of anions on the formation of clathrate hydrates of tetrabutylammonium salts. | |
| GB1132979A (en) | A method of producing an ammonium salt and iron oxide from a solution of ferrous salt | |
| CA1234962A (en) | Manufacturing and using nitrogen fertilizer solutions on a farm | |
| ES471032A1 (en) | Purification process | |
| GB1445288A (en) | Process for producing goethite | |
| JP2741137B2 (en) | Production method of iron-based flocculant | |
| GB1229107A (en) | ||
| KR870008793A (en) | Method of manufacturing copper hydroxide | |
| DE69018645T2 (en) | PRODUCTION OF COPPER CONNECTIONS. | |
| KR850006870A (en) | New manufacturing method of magaldrate | |
| JPS5820892B2 (en) | Production method of basic ferric sulfate | |
| Furman et al. | APPLICATIONS OF CERIC SULFATE IN VOLUMETRIC ANALYSIS. V. POTENTIOMETRIC STUDY OF THE REACTION BETWEEN FERROCYANIDE AND CERIC IONS | |
| JPS61286228A (en) | Production of iron-system flocculant | |
| JPH0513095B2 (en) | ||
| GB1430786A (en) | ||
| JP3532074B2 (en) | Method for producing ferric solution of low nitrogen polysulfate | |
| GB1533287A (en) | Treating calcium nitrate in a used nitrogen oxide(s)absorption liquid | |
| SU644759A1 (en) | Method of obtaining complex fertilizers | |
| Dash et al. | Kinetics & Mechanism of Cerium (IV) Oxidation of Oxalatopentaammine-cobalt (III) Ion in Perchloric Acid Medium | |
| SU560867A1 (en) | Method for producing organo-mineral fertilizers |