GB1129408A - Method of bonding glass to rubber - Google Patents

Method of bonding glass to rubber

Info

Publication number
GB1129408A
GB1129408A GB2054966A GB2054966A GB1129408A GB 1129408 A GB1129408 A GB 1129408A GB 2054966 A GB2054966 A GB 2054966A GB 2054966 A GB2054966 A GB 2054966A GB 1129408 A GB1129408 A GB 1129408A
Authority
GB
United Kingdom
Prior art keywords
rubber
composition
butadiene
phenol
formaldehyde
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2054966A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dunlop Co Ltd
Original Assignee
Dunlop Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dunlop Co Ltd filed Critical Dunlop Co Ltd
Publication of GB1129408A publication Critical patent/GB1129408A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
    • C08J5/08—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials glass fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/69—Polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2321/00—Characterised by the use of unspecified rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Manufacturing & Machinery (AREA)
  • Reinforced Plastic Materials (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

1,129,408. Coated glass. DUNLOP CO. Ltd. 10 May, 1966 [26 May, 1965], No. 20549/66. Headings B2E and B2K. [Also in Divisions C3 and D1] Glass fabrics or sheets are bonded to rubber by applying thereto an adhesive composition consisting at least in part of an aqueous dispersion or emulsion of a polyisocyanate, the isocyanate groups of which may be masked by, for example, reaction with a phenol, bisulphite or malonic ester, and a rubber latex, drying the applied coating, bringing the coated surface into contact with a vulcanisable rubber composition and vulcanising the rubber composition. Suitable polyisocyanates are 4, 4', 4"-triphenyl methane triisocyanate and the product of reacting one mole of triol with three moles of toluylene-2, 4-diisocyanate and the rubber latex in the adhesive composition which may be same as or different from the rubber in the rubber composition to which the glass material is to be bonded, may be natural rubber, a styrene-butadiene-vinylpyridine terpolymer, a styrene-butadiene copolymer, cis-polybutadiene, polychloroprene, a butadiene-acrylonitrile copolymer, a butyl rubber or an ethylene-propylene copolymer or a mixture thereof. The adhesive composition may also contain a polyepoxide composition, e.g. epoxidised polybutadiene and the diglycidyl ether of 'bis phenol A and its condensation products, a protective colloid, e.g. an ammoniacal casin solution, para formaldehyde and/or a phenol-aldehyde resin, e.g. a precondensed resorcinol-formaldehyde resin, which may be accompanied by a aqueous mixture of ammonia and formaldehyde, and the dispersion or emulsion of the composition may be aided by use of an anionic or non- ionic emulsifying agent, e.g. dioctyl sodium sulphosuccinate or a polyethylene oxide or polyvinyl ether emulsifier. The rubber in the vulcanisable rubber composition may be oilextended and the composition may contain sulphur, a peroxide cure system, carbon black, stearic acid, zinc oxide, N-cydohexylibenzthiazyl sulphonamide, phenyl-alpha-naphthylamine, mercaptobenzthiazyl disulphide, di-otolyl guanidine, magnesium oxide, tetramethylthiuram monosulphide and a triazine derivative.
GB2054966A 1965-05-26 1966-05-10 Method of bonding glass to rubber Expired GB1129408A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DED0047372 1965-05-26

Publications (1)

Publication Number Publication Date
GB1129408A true GB1129408A (en) 1968-10-02

Family

ID=7050384

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2054966A Expired GB1129408A (en) 1965-05-26 1966-05-10 Method of bonding glass to rubber

Country Status (3)

Country Link
BE (1) BE681671A (en)
DE (1) DE1544786C3 (en)
GB (1) GB1129408A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2187533A1 (en) * 1972-06-12 1974-01-18 Henkel & Cie Gmbh
EP0061628A2 (en) * 1981-03-27 1982-10-06 Bayer Ag Use of polyisocyanate products dispersable in water as an additive to aqueous adhesives
EP0215267A2 (en) * 1985-08-16 1987-03-25 Bayer Ag Use of polyisocyanates or polyisocyanate mixtures as additives for aqueous dispersion paints
USRE34093E (en) * 1982-05-24 1992-10-06 Aqueous adhesive compositions
US5717031A (en) * 1995-06-21 1998-02-10 Lord Corporation Aqueous adhesive compositions

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3329127A1 (en) * 1983-08-11 1985-02-28 Bayer Ag, 5090 Leverkusen REINFORCEMENT ELEMENTS FOR ELASTOMERS, PRODUCTION OF THE REINFORCED ELASTOMERS AND REINFORCED ELASTOMERS

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2187533A1 (en) * 1972-06-12 1974-01-18 Henkel & Cie Gmbh
EP0061628A2 (en) * 1981-03-27 1982-10-06 Bayer Ag Use of polyisocyanate products dispersable in water as an additive to aqueous adhesives
EP0061628A3 (en) * 1981-03-27 1982-12-08 Bayer Ag Use of polyisocyanate products dispersable in water as an additive to aqueous adhesives
US4433095A (en) * 1981-03-27 1984-02-21 Bayer Aktiengesellschaft Aqueous adhesives containing water-dispersible polyisocyanate preparations
USRE34093E (en) * 1982-05-24 1992-10-06 Aqueous adhesive compositions
EP0215267A2 (en) * 1985-08-16 1987-03-25 Bayer Ag Use of polyisocyanates or polyisocyanate mixtures as additives for aqueous dispersion paints
EP0215267A3 (en) * 1985-08-16 1988-10-12 Bayer Ag Use of polyisocyanates or polyisocyanate mixtures as additives for aqueous dispersion paints
US5717031A (en) * 1995-06-21 1998-02-10 Lord Corporation Aqueous adhesive compositions

Also Published As

Publication number Publication date
DE1544786A1 (en) 1969-09-25
BE681671A (en) 1966-10-31
DE1544786B2 (en) 1973-11-08
DE1544786C3 (en) 1974-07-04

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