GB1128216A - Oxidation of hydrocarbons to alcohols - Google Patents

Oxidation of hydrocarbons to alcohols

Info

Publication number
GB1128216A
GB1128216A GB52775/65A GB5277565A GB1128216A GB 1128216 A GB1128216 A GB 1128216A GB 52775/65 A GB52775/65 A GB 52775/65A GB 5277565 A GB5277565 A GB 5277565A GB 1128216 A GB1128216 A GB 1128216A
Authority
GB
United Kingdom
Prior art keywords
hydrocarbons
alcohol
alcohols
boric acid
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB52775/65A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Universal Oil Products Co
Original Assignee
Universal Oil Products Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Universal Oil Products Co filed Critical Universal Oil Products Co
Publication of GB1128216A publication Critical patent/GB1128216A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C07C29/52—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only in the presence of mineral boron compounds with, when necessary, hydrolysis of the intermediate formed
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1,128,216. Alcohols. UNIVERSAL OIL PRODUCTS CO. 13 Dec., 1965 [21 Dec., 1964], No. 52775/65. Heading C2C. Alcohols are prepared by heating saturated hydrocarbons within 100‹ to 225‹ C. with a gas containing oxygen and an alkyl metaborate to form a dialkyl boric acid, hydrolysing a portion of the acid to alcohol and acid, separating and recovering the alcohol, reacting the boric acid with another portion of the dialkyl boric acid to form alkyl metaborate, and reacting the latter with further saturated hydrocarbon and oxygen. Hydrocarbons may be butane, isobutane, pentane, isopentane, hexane, heptane, octane, decane, dodecane, tetradecane and pentadecane, cyclopentane, methylcyclopentane, cyclohexane, methylcyclohexane, cyclooctane, cyclodecane and cyclododecane, and a pressure sufficient to maintain the hydrocarbons in the liquid phase is preferred. A suitable apparatus is described and by-product ketone and aldehyde products may be hydrogenated to alcohol using conventional catalysts. The oxidation of dodecane and cyclohexane is described in examples.
GB52775/65A 1964-12-21 1965-12-13 Oxidation of hydrocarbons to alcohols Expired GB1128216A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US41981064A 1964-12-21 1964-12-21

Publications (1)

Publication Number Publication Date
GB1128216A true GB1128216A (en) 1968-09-25

Family

ID=23663852

Family Applications (1)

Application Number Title Priority Date Filing Date
GB52775/65A Expired GB1128216A (en) 1964-12-21 1965-12-13 Oxidation of hydrocarbons to alcohols

Country Status (7)

Country Link
DE (1) DE1518156A1 (en)
ES (1) ES320845A1 (en)
FR (1) FR1460488A (en)
GB (1) GB1128216A (en)
IL (1) IL24780A (en)
NL (1) NL6516569A (en)
SE (1) SE343291B (en)

Also Published As

Publication number Publication date
IL24780A (en) 1969-11-30
ES320845A1 (en) 1966-12-16
FR1460488A (en) 1966-11-25
NL6516569A (en) 1966-06-22
DE1518156A1 (en) 1969-02-13
SE343291B (en) 1972-03-06

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