GB1124765A - Co-oligomerization of olefines - Google Patents

Co-oligomerization of olefines

Info

Publication number
GB1124765A
GB1124765A GB919166A GB919166A GB1124765A GB 1124765 A GB1124765 A GB 1124765A GB 919166 A GB919166 A GB 919166A GB 919166 A GB919166 A GB 919166A GB 1124765 A GB1124765 A GB 1124765A
Authority
GB
United Kingdom
Prior art keywords
butene
reaction
oligomerization
reaction product
ethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB919166A
Inventor
Leslie Ernest Addy
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
British Hydrocarbon Chemicals Ltd
Original Assignee
British Hydrocarbon Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by British Hydrocarbon Chemicals Ltd filed Critical British Hydrocarbon Chemicals Ltd
Priority to GB919166A priority Critical patent/GB1124765A/en
Publication of GB1124765A publication Critical patent/GB1124765A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/24—Catalytic processes with metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/18—Carbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

C6-C8 olefins are produced by co-oligomerizing an n-butene fraction consisting predominantly of butene-1 with ethylene over a cobalt/activated carbon catalyst, said catalyst being activated by heating at temperatures below 350 DEG C. The reaction may be carried out in the liquid phase, possibly in the presence of a solvent which may be the reaction product. Reaction temperatures of -50-200 DEG C. and pressures of 100-1000 p.s.i.g. are specified. The reaction product may be fractionated to yield butene at least part of which may be recycled. The butene fraction may be obtained by simultaneous oligomerization of ethylene.
GB919166A 1966-03-02 1966-03-02 Co-oligomerization of olefines Expired GB1124765A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB919166A GB1124765A (en) 1966-03-02 1966-03-02 Co-oligomerization of olefines

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB919166A GB1124765A (en) 1966-03-02 1966-03-02 Co-oligomerization of olefines

Publications (1)

Publication Number Publication Date
GB1124765A true GB1124765A (en) 1968-08-21

Family

ID=9867158

Family Applications (1)

Application Number Title Priority Date Filing Date
GB919166A Expired GB1124765A (en) 1966-03-02 1966-03-02 Co-oligomerization of olefines

Country Status (1)

Country Link
GB (1) GB1124765A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011157674A1 (en) * 2010-06-15 2011-12-22 Basf Se Process for co-oligomerization of olefins
WO2013064302A1 (en) 2011-10-31 2013-05-10 Exxonmobil Chemical Patents Inc. Olefin oligomerization process
JP2017122081A (en) * 2015-11-19 2017-07-13 エボニック デグサ ゲーエムベーハーＥｖｏｎｉｋ Ｄｅｇｕｓｓａ ＧｍｂＨ Influencing viscosity of n-butene-based ester mixture by controlled use of ethene in preparation of ester precursor

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011157674A1 (en) * 2010-06-15 2011-12-22 Basf Se Process for co-oligomerization of olefins
CN102933527A (en) * 2010-06-15 2013-02-13 巴斯夫欧洲公司 Process for co-oligomerization of olefins
CN102933527B (en) * 2010-06-15 2014-12-31 巴斯夫欧洲公司 Process for co-oligomerization of olefins
WO2013064302A1 (en) 2011-10-31 2013-05-10 Exxonmobil Chemical Patents Inc. Olefin oligomerization process
CN103889938A (en) * 2011-10-31 2014-06-25 埃克森美孚化学专利公司 Olefin oligomerization process
CN103889938B (en) * 2011-10-31 2016-08-17 埃克森美孚化学专利公司 Alkene oligomerization process
US9580525B2 (en) 2011-10-31 2017-02-28 Exxonmobil Chemical Patents Inc. Olefin olegomerization process
JP2017122081A (en) * 2015-11-19 2017-07-13 エボニック デグサ ゲーエムベーハーＥｖｏｎｉｋ Ｄｅｇｕｓｓａ ＧｍｂＨ Influencing viscosity of n-butene-based ester mixture by controlled use of ethene in preparation of ester precursor
US20180208538A1 (en) * 2015-11-19 2018-07-26 Evonik Degussa Gmbh Influencing the viscosity of n-butene-based ester mixtures by controlled use of ethene in the preparation of the ester precursors

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