GB1120803A - Method of reducing the coefficient of friction of elastomer surfaces - Google Patents

Method of reducing the coefficient of friction of elastomer surfaces

Info

Publication number
GB1120803A
GB1120803A GB152565A GB152565A GB1120803A GB 1120803 A GB1120803 A GB 1120803A GB 152565 A GB152565 A GB 152565A GB 152565 A GB152565 A GB 152565A GB 1120803 A GB1120803 A GB 1120803A
Authority
GB
United Kingdom
Prior art keywords
rubber
natural rubber
neoprene
toluene
elastomers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB152565A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
RICHARD GEORGE CHRISTOPHER JEN
Original Assignee
RICHARD GEORGE CHRISTOPHER JEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by RICHARD GEORGE CHRISTOPHER JEN filed Critical RICHARD GEORGE CHRISTOPHER JEN
Priority to GB19476/67A priority Critical patent/GB1120804A/en
Priority to GB152565A priority patent/GB1120803A/en
Publication of GB1120803A publication Critical patent/GB1120803A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/12—Chemical modification
    • C08J7/16—Chemical modification with polymerisable compounds
    • C08J7/18—Chemical modification with polymerisable compounds using wave energy or particle radiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/08—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
    • B05D5/083—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface involving the use of fluoropolymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/02—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/12—Chemical modification
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/12—Chemical modification
    • C08J7/16—Chemical modification with polymerisable compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0254—After-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
    • B05D3/061—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
    • B05D3/065—After-treatment
    • B05D3/067—Curing or cross-linking the coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
    • B05D3/068—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using ionising radiations (gamma, X, electrons)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2321/00—Characterised by the use of unspecified rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Toxicology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)

Abstract

A method of reducing the coefficient of friction at surfaces of cured elastomeric products consists substantially of contacting the surfaces to be treated with at least one compound capable of addition polymerization and either (a) subjecting the contacted surfaces to ultra-violet or gamma radiation, or (b) incorporating a thermal polymerization initiator into the contacting compound and subjecting the contacted surfaces to the action of heat, the steps (a) or (b) being carried out in a manner to cause chemical combination and/or physical integration at the said surfaces of the contacting compounds with the elastomeric material and to cause polymerization of the contacting compounds. The elastomeric materials, e.g. elastomers containing residual unsaturation such as natural rubber, neoprene, nitrile rubber, SBR and polybutadienes and virtually saturated elastomers such as butyl rubber, silicone rubber, ethylene-propylene rubbers, and polyurethanes are treated with vinyl and vinylidene monomers or oligomers. The unsaturated elastomers may be treated with fluorine- or chlorine-containing monomers. In the examples, slabs of the elastomers are washed with soap and water and rinsed with acetone prior to being soaked in monomer or monomer solution and exposed to U.V. light or heated. The elastomers, monomers, solvents and catalysts used are as follows: (1) natural rubber and styrene, (2) neoprene and methyl methacrylate, (3) SBR and n-butyl acrylate, (4) natural rubber, ethyl acrylate and benzoyl peroxide, (5) acrylonitrile rubber, acrylic acid and benzoyl peroxide, (6) natural rubber, methyl acrylate and azobisisobutyronitrile, (7) natural rubber, n-perfluorobutyl acrylate and benzene, (8) natural rubber, perfluoropropylene and toluene, (9) acrylonitrile rubber, perfluoropropylene, toluene and benzoyl peroxide, (10) natural rubber, n-perfluorobutyl acrylate, toluene and benzoyl peroxide, (11) acrylonitrile rubber, n-perfluorobutyl acrylate, toluene and azobisisobutyronitrile, (12) neoprene, perfluoropropylene, toluene and azobisisobutyronitrile, (13) to (15) natural rubbers acrylonitrile rubber or neoprene and perchloroethylene and (16) to (18) natural rubber, neoprene or SBR and trichloroethylene. In Examples 13 to 18, the soaking of the slab in monomer and exposure to U.V. light are repeated.
GB152565A 1965-01-13 1965-01-13 Method of reducing the coefficient of friction of elastomer surfaces Expired GB1120803A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB19476/67A GB1120804A (en) 1965-01-13 1965-01-13 Method of reducing the coefficient of friction of elastomer surfaces
GB152565A GB1120803A (en) 1965-01-13 1965-01-13 Method of reducing the coefficient of friction of elastomer surfaces

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB19476/67A GB1120804A (en) 1965-01-13 1965-01-13 Method of reducing the coefficient of friction of elastomer surfaces
GB152565A GB1120803A (en) 1965-01-13 1965-01-13 Method of reducing the coefficient of friction of elastomer surfaces

Publications (1)

Publication Number Publication Date
GB1120803A true GB1120803A (en) 1968-07-24

Family

ID=62526031

Family Applications (2)

Application Number Title Priority Date Filing Date
GB152565A Expired GB1120803A (en) 1965-01-13 1965-01-13 Method of reducing the coefficient of friction of elastomer surfaces
GB19476/67A Expired GB1120804A (en) 1965-01-13 1965-01-13 Method of reducing the coefficient of friction of elastomer surfaces

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB19476/67A Expired GB1120804A (en) 1965-01-13 1965-01-13 Method of reducing the coefficient of friction of elastomer surfaces

Country Status (1)

Country Link
GB (2) GB1120803A (en)

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2465527A1 (en) * 1979-09-25 1981-03-27 Dukhovskoi Evgeny METHOD FOR MODIFYING THE SURFACE OF RUBBER INDUSTRIAL OBJECTS AND DEVICE FOR IMPLEMENTING SAID METHOD
FR2722202A1 (en) * 1994-07-07 1996-01-12 Gkn Automotive Inc PROCESS FOR COATING A SUBSTRATE AND PROTECTING A JOINT BELLOWS
EP0872512A2 (en) * 1997-04-14 1998-10-21 Hüls Aktiengesellschaft Process for modifying the surface of polymeric substrates by graft polymerisation
EP0890601A1 (en) * 1997-01-10 1999-01-13 Nippon Valqua Industries, Ltd. Process for producing surface-modified rubber, surface-modified rubber, and sealing material
ES2245871A1 (en) * 2004-02-26 2006-01-16 Lodosa Auxiliar De Calzado, S.L. Washing technique for rubber products comprises ultrasonic treatment combined with detergent based water cleaning
US20080271277A1 (en) * 2007-04-27 2008-11-06 Mitsuba Corporation Rubber product for wiping, rubber for wiper blade, method for producing rubber for wiper blade, and wiper unit
ITTO20090238A1 (en) * 2009-03-27 2010-09-28 Dayco Europe Srl ELASTOMERIC COMPOSITIONS INCLUDING FLUORURED ADDITIVES AND ITS USE FOR THE MANUFACTURE OF TRANSMISSION BELTS
US8227522B2 (en) * 2006-07-19 2012-07-24 Mitsuba Corporation Surface-modified blade rubber, wiper unit, and blade rubber surface modifying method
EP2664627A1 (en) * 2012-05-16 2013-11-20 Sumitomo Rubber Industries, Ltd. Surface modification method and surface-modified elastic body
EP2752436A1 (en) * 2013-01-07 2014-07-09 Sumitomo Rubber Industries, Ltd. Surface modification method and surface-modified elastic body
US9321872B2 (en) 2012-02-02 2016-04-26 Sumitomo Rubber Industries, Ltd. Surface modification method and surface-modified elastic body
US9469736B2 (en) 2011-06-03 2016-10-18 Sumitomo Rubber Industries, Ltd. Surface-modifying method and elastic body with modified surface
DE102016200292A1 (en) * 2016-01-13 2017-07-13 Robert Bosch Gmbh Process for the preparation of a coated rubber article and rubber article
US9738744B2 (en) 2013-06-11 2017-08-22 Sumitomo Rubber Industries, Ltd. Surface modification method for three-dimensional object and syringe gasket
US9752003B2 (en) 2012-11-30 2017-09-05 Sumitomo Rubber Industries, Ltd. Surface-modified elastic body
US9758605B2 (en) 2012-11-20 2017-09-12 Sumitomo Rubber Industries, Ltd. Surface modification method and surface-modified elastic body
US9963565B2 (en) 2014-10-02 2018-05-08 Sumitomo Rubber Industries, Ltd. Surface modification method and surface-modified elastic body
US10189944B2 (en) 2013-04-25 2019-01-29 Sumitomo Rubber Industries, Ltd. Surface modification method and surface-modified elastic body
US10214608B2 (en) 2015-08-03 2019-02-26 Sumitomo Rubber Industries, Ltd. Surface modification method and surface-modified body
US10280274B2 (en) 2014-01-06 2019-05-07 Sumitomo Rubber Industries, Ltd. Method for modifying surface and surface modified elastic body
US10344109B2 (en) 2012-09-10 2019-07-09 Sumitomo Rubber Industries, Ltd. Surface modification method and surface-modified elastic body
US10647829B2 (en) 2013-06-20 2020-05-12 Sumitomo Rubber Industries, Ltd. Surface modification method and surface modification body
US10759918B2 (en) 2015-08-03 2020-09-01 Sumitomo Rubber Industries, Ltd. Surface modification method and surface-modified elastic body

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6063167B2 (en) * 2012-08-02 2017-01-18 住友ゴム工業株式会社 Surface modification method and surface modified elastic body

Cited By (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2465527A1 (en) * 1979-09-25 1981-03-27 Dukhovskoi Evgeny METHOD FOR MODIFYING THE SURFACE OF RUBBER INDUSTRIAL OBJECTS AND DEVICE FOR IMPLEMENTING SAID METHOD
FR2722202A1 (en) * 1994-07-07 1996-01-12 Gkn Automotive Inc PROCESS FOR COATING A SUBSTRATE AND PROTECTING A JOINT BELLOWS
EP0890601A1 (en) * 1997-01-10 1999-01-13 Nippon Valqua Industries, Ltd. Process for producing surface-modified rubber, surface-modified rubber, and sealing material
EP0890601A4 (en) * 1997-01-10 2000-12-20 Nihon Valqua Kogyo Kk Process for producing surface-modified rubber, surface-modified rubber, and sealing material
KR100525065B1 (en) * 1997-01-10 2006-04-14 닛폰 바루카 고교 가부시키가이샤 Manufacturing Method of Surface Modified Rubber, Surface Modified Rubber and Sealing Material
EP0872512A2 (en) * 1997-04-14 1998-10-21 Hüls Aktiengesellschaft Process for modifying the surface of polymeric substrates by graft polymerisation
EP0872512A3 (en) * 1997-04-14 1999-12-08 Degussa-Hüls Aktiengesellschaft Process for modifying the surface of polymeric substrates by graft polymerisation
ES2245871A1 (en) * 2004-02-26 2006-01-16 Lodosa Auxiliar De Calzado, S.L. Washing technique for rubber products comprises ultrasonic treatment combined with detergent based water cleaning
US8227522B2 (en) * 2006-07-19 2012-07-24 Mitsuba Corporation Surface-modified blade rubber, wiper unit, and blade rubber surface modifying method
US20080271277A1 (en) * 2007-04-27 2008-11-06 Mitsuba Corporation Rubber product for wiping, rubber for wiper blade, method for producing rubber for wiper blade, and wiper unit
ITTO20090238A1 (en) * 2009-03-27 2010-09-28 Dayco Europe Srl ELASTOMERIC COMPOSITIONS INCLUDING FLUORURED ADDITIVES AND ITS USE FOR THE MANUFACTURE OF TRANSMISSION BELTS
WO2010109321A3 (en) * 2009-03-27 2011-03-24 Dayco Europe S.R.L. Elastomeric compositions comprising fluorinated additives and use thereof for manufacturing power transmission belts
CN102449007A (en) * 2009-03-27 2012-05-09 戴科欧洲有限公司 Elastomeric compositions comprising fluorinated additives and use thereof for manufacturing power transmission belts
US9096740B2 (en) 2009-03-27 2015-08-04 Dayco Europe S.R.L. Elastomeric compositions comprising fluorinated additives and use thereof for the manufacture of drive belts
US9469736B2 (en) 2011-06-03 2016-10-18 Sumitomo Rubber Industries, Ltd. Surface-modifying method and elastic body with modified surface
US9321872B2 (en) 2012-02-02 2016-04-26 Sumitomo Rubber Industries, Ltd. Surface modification method and surface-modified elastic body
US9339845B2 (en) 2012-05-16 2016-05-17 Sumitomo Rubber Industries, Ltd. Surface modification method and surface-modified elastic body
EP2664627A1 (en) * 2012-05-16 2013-11-20 Sumitomo Rubber Industries, Ltd. Surface modification method and surface-modified elastic body
US10344109B2 (en) 2012-09-10 2019-07-09 Sumitomo Rubber Industries, Ltd. Surface modification method and surface-modified elastic body
US9758605B2 (en) 2012-11-20 2017-09-12 Sumitomo Rubber Industries, Ltd. Surface modification method and surface-modified elastic body
US9752003B2 (en) 2012-11-30 2017-09-05 Sumitomo Rubber Industries, Ltd. Surface-modified elastic body
CN103910900A (en) * 2013-01-07 2014-07-09 住友橡胶工业株式会社 Surface modification method and surface-modified elastic body
EP2752436A1 (en) * 2013-01-07 2014-07-09 Sumitomo Rubber Industries, Ltd. Surface modification method and surface-modified elastic body
US9540493B2 (en) 2013-01-07 2017-01-10 Sumitomo Rubber Industries, Ltd. Surface modification method and surface-modified elastic body
US10189944B2 (en) 2013-04-25 2019-01-29 Sumitomo Rubber Industries, Ltd. Surface modification method and surface-modified elastic body
US9738744B2 (en) 2013-06-11 2017-08-22 Sumitomo Rubber Industries, Ltd. Surface modification method for three-dimensional object and syringe gasket
US10647829B2 (en) 2013-06-20 2020-05-12 Sumitomo Rubber Industries, Ltd. Surface modification method and surface modification body
US10280274B2 (en) 2014-01-06 2019-05-07 Sumitomo Rubber Industries, Ltd. Method for modifying surface and surface modified elastic body
US9963565B2 (en) 2014-10-02 2018-05-08 Sumitomo Rubber Industries, Ltd. Surface modification method and surface-modified elastic body
US10214608B2 (en) 2015-08-03 2019-02-26 Sumitomo Rubber Industries, Ltd. Surface modification method and surface-modified body
US10759918B2 (en) 2015-08-03 2020-09-01 Sumitomo Rubber Industries, Ltd. Surface modification method and surface-modified elastic body
CN106967227A (en) * 2016-01-13 2017-07-21 罗伯特·博世有限公司 Method and rubber for manufacturing the rubber coated
US20170198163A1 (en) * 2016-01-13 2017-07-13 Robert Bosch Gmbh Process for the production of a coated rubber item and rubber item
DE102016200292A1 (en) * 2016-01-13 2017-07-13 Robert Bosch Gmbh Process for the preparation of a coated rubber article and rubber article
CN106967227B (en) * 2016-01-13 2021-04-02 罗伯特·博世有限公司 Method for producing a coated rubber article and rubber article
US11208572B2 (en) * 2016-01-13 2021-12-28 Robert Bosch Gmbh Process for the production of a coated rubber item and rubber item

Also Published As

Publication number Publication date
GB1120804A (en) 1968-07-24

Similar Documents

Publication Publication Date Title
GB1120803A (en) Method of reducing the coefficient of friction of elastomer surfaces
GB1034753A (en) A process for the production of polymers of conjugated dienes
GB961411A (en) Method of copolymerizing
GB841127A (en) Inverse emulsion polymerisation of water-soluble monomers
GB1039764A (en) Coplymerisation processes
GB957965A (en) Hardener liquid for the curing of polymerisable organic compositions
GB849048A (en) Improvements in or relating to the polymerisation of unsaturated organic compounds
ES419440A1 (en) Curable compositions based on elastomeric vinylidene fluoride copolymers, process for curing the compositions, and the cured compositions
GB1113697A (en) Photographic material for the silver dyestuff bleaching process and process for its manufacture
GB1015334A (en) Process for making polymeric materials derived from vinyl chloride and other monomers
SE7601585L (en) WAY TO AVOID POLLYMERIZATION REACTIONS IN POLYMERIZATION
GB972078A (en)
GB1074636A (en) Sulfur and peroxide curable acrylate interpolymers and vulcanizates therefrom
GB942969A (en) Resinous composition
BR7408565D0 (en) CURING FLUOR-ELASTOMER COMPOSITION AND PROCESS FOR AN ELASTOMERIC COPOLYMER OF VINYLIDENE FLUORIDE AND ETHYLENICALLY Unsaturated FLUORINATED COMONOMER
GB885470A (en) Cross-linked alpha-olefin polymers and process for preparing them
GB1056447A (en) Process for the production of impact-resistant vinyl chloride graft copolymers
GB980258A (en) Production of modified rubbers
GB1099991A (en) Improvements in and relating to process for the manufacture of graft copolymers
FR78256E (en) Accelerated concrete hardening process and heated formwork used for this purpose
CU34693A (en) METHOD TO ELIMINATE MONOMERS THAT HAVE NOT REACTED FROM AN AQUEOUS DISPERSION OF VINYL CHLORIDE IN POLYMERIZATION AND THE APPARATUS TO PERFORM SUCH METHOD
IT1093454B (en) PROCESS FOR THE POLYMERIZATION IN WATER DISPERSION OF HALOGENATED VINYL MONOMERS
FR1352678A (en) Vulcanizable composition and vulcanization process
IT1079325B (en) Self-emulsifiable anaerobic sealing or adhesive compsns. - contg. acrylate monomer, peroxy initiator and anionic and/or nonionic surfactant
GB970448A (en) Copolymers of p-isopropenyl phenyl esters