GB1118517A - Oligomerisation of cyclo olefins - Google Patents

Oligomerisation of cyclo olefins

Info

Publication number
GB1118517A
GB1118517A GB2465167A GB2465167A GB1118517A GB 1118517 A GB1118517 A GB 1118517A GB 2465167 A GB2465167 A GB 2465167A GB 2465167 A GB2465167 A GB 2465167A GB 1118517 A GB1118517 A GB 1118517A
Authority
GB
United Kingdom
Prior art keywords
compounds
amount
metals
catalyst
oligomerized
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2465167A
Inventor
Henk Johan Alkema
Robert Van Helden
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Priority to GB2465167A priority Critical patent/GB1118517A/en
Publication of GB1118517A publication Critical patent/GB1118517A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • C07C6/06—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond at a cyclic carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Cycloolefins are oligomerized using a supported catalyst comprising one or more compounds of Mo, W or Re. The metals may be present as oxides in amount 0.5-30% calculated as metals by weight of the support. The catalyst may also comprise compounds of Co, Ni, Fe or Cr, particularly cobalt oxide, in amount 0.05 to 15% calculated as metal by weight of the support, and compounds of the alkali metals in amount 0.2 to 8% w. The starting materials may be monocylic or poly-cyclic mono- or poly-olefins which may be homo-oligomerized or co-oligomerized with other cycloolefins to form dimers, trimers, tetramers or mixtures thereof with higher oligomers. The oligomerization may be carried out at 50-250 DEG C. and 0.5 to 150 atm. absolute in the gaseous or liquid phase with fixed, slurried or fluidized catalyst optionally with gaseous or liquid inert diluents. The oligomers produced may be hydrogenated in situ to form completely saturated cycloalkanes by effecting the oligomerization in the presence of H2. The catalyst may additionally comprise metallic Pd, Pt, Co, Mn, Ni, Fe, Rh or Ru or compounds thereof in amount 0.1-15% w. calculated as metals on the support.
GB2465167A 1967-05-26 1967-05-26 Oligomerisation of cyclo olefins Expired GB1118517A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2465167A GB1118517A (en) 1967-05-26 1967-05-26 Oligomerisation of cyclo olefins

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2465167A GB1118517A (en) 1967-05-26 1967-05-26 Oligomerisation of cyclo olefins

Publications (1)

Publication Number Publication Date
GB1118517A true GB1118517A (en) 1968-07-03

Family

ID=10215088

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2465167A Expired GB1118517A (en) 1967-05-26 1967-05-26 Oligomerisation of cyclo olefins

Country Status (1)

Country Link
GB (1) GB1118517A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0182333A1 (en) * 1984-11-20 1986-05-28 Consortium für elektrochemische Industrie GmbH Process for preparing cycloalcadienes
US6329562B1 (en) 1999-07-08 2001-12-11 Haarmann & Reimer Gmbh Separation process for separating cycloalkenes having at least 2 double bonds from a reaction mixture
EP1288180A2 (en) * 2001-08-28 2003-03-05 Haarmann & Reimer GmbH Process to prepare cycloalkadienes via a metathesis reaction

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0182333A1 (en) * 1984-11-20 1986-05-28 Consortium für elektrochemische Industrie GmbH Process for preparing cycloalcadienes
US6329562B1 (en) 1999-07-08 2001-12-11 Haarmann & Reimer Gmbh Separation process for separating cycloalkenes having at least 2 double bonds from a reaction mixture
EP1288180A2 (en) * 2001-08-28 2003-03-05 Haarmann & Reimer GmbH Process to prepare cycloalkadienes via a metathesis reaction
EP1288180A3 (en) * 2001-08-28 2003-09-10 Haarmann & Reimer GmbH Process to prepare cycloalkadienes via a metathesis reaction

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